• Title/Summary/Keyword: Differential reaction

Search Result 666, Processing Time 0.032 seconds

Study of Heating Temperature and Quantification Conditions of Standard Water for Evaluating Hair Water Content (모발 수분 함량 평가를 위한 가열 온도와 기준 수분 정량 조건 연구)

  • Sang-Hun Song;Jangho Joo;Hyun Sub Park;Seong Kil Son;Nae-Gyu Kang
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.50 no.1
    • /
    • pp.11-18
    • /
    • 2024
  • Recently, there have been attempts to claim the hair moisturizing effect for a hair care product, however there has not yet been an official evaluation method because heating temperature for hair has not been established. This study was conducted to establish a quantitative evaluation for hair water content. In order to observe the behavior of water inside hair, heat was applied to hair with various temperatures using thermogravimetric dry residue. As the heating temperature increased, the amount of moisture released from the hair increased. As a result of evaluating hair using a differential scanning calorimeter (DSC), a unique phenomenon in which a rapid endothermic reaction occurs around 75 ℃ was observed. This phenomenon was also observed in different ethnic hair. In hair that damaged the hair cuticle barrier with oxidation and heat, this rapidly rising endothermic reaction temperature occurred at 77 ℃, which was slightly higher, and 73 ℃ was observed when this hair was applied with polar oil, conditioning polymer, or keratin protein. To determine how this reaction affects the hair surface, friction test was performed using an atomic force microscope. When heated above 75 ℃, cuticle friction increased, however when heated above 90 ℃, there was no change in hair cuticle friction. Finally, it was confirmed that around 75 ℃ is the critical temperature at which desorption of water bound to the hair occurs. It is suggested that a heating temperature of 75 ℃ is the optimal temperature for detecting and quantifying the moisture content of hair, and that approximately 10% detected at 75 ℃ can be a standard value for hair moisture content.

Study of Hydrodynamics and Reaction Characteristics of K-based Solid Sorbents for CO2 Capture in a Continuous System Composed of Two Bubbling Fluidized-bed Reactors (두 개의 기포유동층으로 구성된 연속장치에서 CO2 회수를 위한 K-계열 고체흡수제의 수력학적 특성 및 반응특성)

  • Kim, Ki-Chan;Kim, Kwang-Yul;Park, Young Cheol;Jo, Sung-Ho;Ryu, Ho-Jung;Yi, Chang-Keun
    • Korean Chemical Engineering Research
    • /
    • v.48 no.4
    • /
    • pp.499-505
    • /
    • 2010
  • In this study, hydrodynamics and reaction characteristic of K-based solid sorbents for $CO_2$ capture were investigated using a continuous system composed of two bubbling fluidized-bed reactors(1.2 m tall bed with 0.11 m i.d.). Potassium-based dry sorbents manufactured by the Korea Electric Power Research Institute were used, which were composed of $K_2CO_3$ of 35% for $CO_2$ absorption and supporters of 65% for mechanical strength. The continuous system consists of two bubbling fluidized-bed reactors, solid injection nozzle, riser, chiller, analyzer and heater for regeneration reaction. The minimum fluidizing velocity of the continuous system was 0.0088 m/s and the solid circulation rate measured was $10.3kg/m^2{\cdot}s$ at 1.05 m/s velocity of the solid injection nozzle. The $CO_2$ concentration of the simulated gas was about 10 vol% in dry basis. Reaction temperature in carbonator and regenerator were maintained about $70^{\circ}C$ and $200^{\circ}C$, respectively. Differential pressures, which were maintained in carbonator and regenerator, were about $415mmH_2O$ and $350mmH_2O$, respectively. In order to find out reaction characteristics of dry sorbents, several experiments were performed according to various experimental conditions such as $H_2O$ content(7.28~19.66%) in feed gas, velocity (0.053~0.103 m/s) of simulated gas, temperature($60{\sim}80^{\circ}C$) of a carbonator, temperature($150{\sim}200^{\circ}C$) of a regenerator and solid circulation rate($7.0{\sim}10.3kg/m^2{\cdot}s$). The respective data of operating variables were saved and analyzed after maintaining one hour in a stable manner. As a result of continuous operation, $CO_2$ removal tended to increase by increasing $H_2O$ content in feed gas, temperature of a regenerator and solid circulation rate and to decrease by increasing temperature of a carbonator and gas velocity in a carbonator.

A COMPARATIVE STUDY ON AUDITORY ATTENTION AND PHONEME DIFFERENTIAL ABILITY AMONG CHILDREN WITH READING DISABILITY AND WITH ATTENTION DEFICIT/HYPERACTIVITY (읽기 장애와 주의력 결핍/과잉 운동 장애아동의 주의력 과제와 음소 변별 과제 수행 비교 - 청각 과제를 중심으로 -)

  • Lee, Kyung-Hee;Shin, Min-Sup;Kim, Boong-Nyun;Cho, Soo-Churl
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
    • /
    • v.14 no.2
    • /
    • pp.197-208
    • /
    • 2003
  • Objective:In this study, we hypothesized that deficit in processing rapid linguistic stimuli is at the heart of Reading Disability(RD) and deficit in response inhibition is at the heart of Attention Deficit/Hyperactivity(ADHD). We conducted experiments to identify the core cognitive characteristics of children either with RD or with ADHD or with both, using attentional tasks and phoneme differential tests. Method:In the study 1, 28 children with ADHD, 16 children with RD+ADHD were individually administered visual/auditory performance tests. Then, the differences of performance on attentional tasks between two groups were compared while IQs of two groups were controlled. In the study 2, 13 children with RD+ADHD/RD, 13 children with ADHD, and 13 normal children were administered computerized phoneme differential tests. Result:Visual attentional tasks did not distinguish an ADHD group from a RD+ADHD group. With auditory attentional tasks, however, the comorbid group showed significantly more difficulties, causing a large variance in reaction time. RD, RD+ADHD, and ADHD groups showed more errors in phoneme differential tests than a normal control group, and each group showed distinctive performance patterns. Discussion:An ADHD group had difficulty in response inhibition and sustained attention, and children who also had RD along with ADHD magnified the auditory attentional difficulties. Even though children with RD had more trouble with responding correctly to target stimuli, their responses were not significantly different from those of children with ADHD.

  • PDF

Addition Polymerization of 5-Norbornene-2-carboxylic Acid Esters Using Palladium Catalyst System: Synthesis of Monomers, Effect of Their Stereochemistry on Polymerization Behavior (Palladium 촉매를 이용한 5-Norbornene-2-carboxylic Acid Esters의 부가 중합: 단량체의 합성, 단량체의 Stereochemistry(Endo-, Exo-이성질체)가 고분자의 중합 거동에 미치는 영향)

  • Chung, Hae-Kang;Shim, Hyoug-Sub;Jeon, Seung-Ho;Kim, Ji-Heung;Nam, Sung Woo;Jeon, Boong Soo;Kim, Young Jun
    • Polymer(Korea)
    • /
    • v.39 no.3
    • /
    • pp.487-492
    • /
    • 2015
  • The effects of chemical structure of alkyl groups of norbornene carboxylic alkyl esters(methyl, octyl, 4-chlorobenzyl) and endo/exo ratios of norbornene monomers on activity of palladium catalyst and polymerization behavior were investigated. Norbornene ester monomers were synthesized from the reaction of 5-norborene-2-carboxylic acid and various alcohols. Polymerization catalyst, di-${\mu}$-chloro-bis(-methoxybicyclo[2,2,1]-hept-2-ene)palladium(II) (DCBMP), was synthesized according to the literature procedure and silver hexafluoroantimonate ($AgSbF_6$) was used as a conjugate anion source. Gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) were the principal techniques for polymer characterization and $^1H$ NMR spectroscopy was used for chemical structures determination of monomers and polymers. For all of the norbonene alkyl esters GPC data showed that when the amounts of endo isomers exceeded those of exo isomers decreased molecular weight polymers were obtained probably due to the decreased catalyst activity. Polymerizations were conducted by varying the monomer/catalyst mole ratios (100:1, 200:1, 300:1). When 300:1 monomer/catalyst ratio was employed it was possible to synthesize high molecular weight ($M_n=27500g/mol$), film forming polymer from exo-norbornene carboxylic acid octyl ester.

Operating Characteristics of a 0.25 MW Methanation Pilot Plant with Isothermal Reactor and Adiabatic Reactor (등온반응기와 단열반응기 조합으로 구성된 0.25 MW급 메탄합성 파일롯 공정 운전특성)

  • Kim, Suhyun;Yoo, Youngdon;Kang, Sukhwan;Ryu, Jaehong;Kim, Jinho;Kim, Munhyun;Koh, Dongjun;Lee, Hyunjung;Kim, Gwangjun;Kim, Hyungtaek
    • Clean Technology
    • /
    • v.19 no.2
    • /
    • pp.156-164
    • /
    • 2013
  • In this study, we analyzed the operational characteristics of a 0.25 MW methanation pilot plant. Isothermal reactor controled the heat released from methanation reaction by saturated water in shell side. Methanation process consisting of isothermal reactor and adiabatic reactor had advantages with no recycle compressor and more less reactors compared with methanation process with only adiabatic reactors. In case that $H_2$/CO ratio of syngas was under 3, carbon deposition occurred on catalyst in tube side of isothermal reactor and the pressure of reactors increased. In case that $H_2$/CO ratio was maintained around 3, no carbon deposition on catalyst in tube side of isothermal reactor was found by monitoring the differential pressure of reactors and by measuring the differential pressure of several of tubes filled with catalyst before and after operating. It was shown that CO conversion and $CH_4$selectivity were over 99, 97%, respectively, and the maximum $CH_4$productivity was $695ml/h{\cdot}g-cat$.

Effects of CsCl on the Early Root Growth of Maize (Zea mays) (옥수수(Zea mays) 뿌리의 초기 생장에 미치는 CsCl의 영향)

  • Park, Woong-June
    • Journal of Life Science
    • /
    • v.20 no.2
    • /
    • pp.298-303
    • /
    • 2010
  • In this work, the effects of $Cs^+$ on root growth of 2-day-old maize seedlings were scrutinized. CsCl (5 mM - 30 mM) decreased the fresh weight of the primary root and of the shoot above the coleoptilar node. The elongation growth of the primary root was also inhibited by CsCl. The CsCl-inhibited growth was partially restored by 60 mM KCl. Lineweaver-Burk plot of the reaction in the presence and absence of 60 mM KCl displayed competitive interaction of CsCl (at higher than 10 mM). However, the Reversal of the inhibition by 60 mM KCl did not follow the competitive relationship with 5 mM CsCl, indicating the presence of differential mechanisms of $K^+$ influence depending on the concentration of CsCl. The differential effects of CsCl dependent on the concentrations were also observed in the CsCl-evoked radial expansion of the subapical region of the root. In spite of the decrease in length of the root, shrinkage of the root apical meristem was not observed. CsCl above 10 mM induced the expression of ZmKUP1, indicating functional deficiency of $K^+$ due to competition with Cs. However, the expression of ZmKUP1 by 5 mM CsCl was unclear. Conclusively, exogenously applied $Cs^+$ decreased root elongation and fresh weight and caused radial expansion of the subapical region of the primary root in 2-day-old maize seedlings by complex mechanisms including competitive and noncompetitive interactions with $K^+$. Because the shrinkage of the root apical meristem was not observed, it is concluded that the effects of CsCl on maize root growth was mainly related to cell expansion.

Wettability Evaluation of Sn-0.3Ag-0.7Cu Solder Alloy with Different Flux Activity and Indium Addition (플럭스 활성도 및 In 첨가에 따른 Sn-0.3Ag-0.7Cu 솔더 조성의 젖음 특성 변화)

  • Yu, A-Mi;Kim, Jun-Ki;Kim, Mok-Soon;Hyun, Chang-Yong;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.15 no.4
    • /
    • pp.51-57
    • /
    • 2008
  • In this paper, wetting and interfacial reaction properties for low Ag containing Sn-Ag-Cu Pb-free solder alloy, i.e., Sn-0.3Ag-0.7Cu were investigated and compared with those of Sn-1.0Ag-0.5Cu and Sn-3.0Ag-0.5Cu. Melting behavior and stress-strain curves of some Sn-xAg-xCu alloys were also measured using a differential scanning calorimeter(DSC) and a tensile test machine, respectively. In order to enhance insufficient wetting properties of Sn-0.3Ag-0.7Cu alloy, the improvement of wetting properties were analyzed by applying fluxes containing higher content of halide or indium adding of 0.2wt.% into the solder alloy. It was concluded that the small addition of indium is more effective for the improvement of wettability in low temperature range of $230{\sim}240^{\circ}C$ than applying flux containing higher content of halide.

  • PDF

Resistance to Phytophthora Blight of Commercial Pepper Cultivars in Korea (국내 시판 고추 품종의 역병 저항성)

  • Kim, Byung-Soo;Kwon, Tae-Ryong;Hwang, Ji-Eun;Lee, Jae-Moo;Park, Dong-Guen;Ahn, Joon-Hyung;Kim, Hye-Yeon
    • Research in Plant Disease
    • /
    • v.16 no.2
    • /
    • pp.141-147
    • /
    • 2010
  • Resistance to Phytophthora blight (Phytophthora capsici Leonian) of commercial cultivars of Capsicum pepper in Korea were evaluated from 2008 to 2010. In 2008 and 2009, the cultivars were tested for resistance to the Pc003 isolate collected in Youngyang, Gyeongbuk province. In 2010, the selected cultivars in the previous years were tested by inoculating with 3 isolates obtained from the pepper plants in Miryang in Gyeongnam province, Youngyang in Gyeongbuk province, and Goesan in Chungbuk province. A continuous variation in resistance from highly resistant to susceptible was observed among the commercial pepper cultivars. It was also noted that some cultivars, although their names were initiating with 'Yeokgang' or 'PR' meaning Phytophthora resistance, were very low in resistance or susceptible. When the resistant cultivars selected in 2008 and 2009 experiment were inoculated with the 3 isolates, all the commercial cultivars except a rootstock, 'Tantan', succumbed to the exceptionally virulent Pc005 (Miryang) isolate. Pc002 (Goesan) was a little more virulent than Pc003 (Youngyang). A few cultivars resistant to Pc003 (Youngyang) were severely infected by Pc002 (Goesan). Significant interaction in analysis of variance suggested the differential interactions between cultivars and pathogen isolates. Strategies to breed cultivars having high level of resistance to the highly variable pathogenic fungus, Phytophthora capsici, were discussed.

Distribution and differential expression of microRNAs in the intestinal mucosal layer of necrotic enteritis induced Fayoumi chickens

  • Rengaraj, Deivendran;Truong, Anh Duc;Ban, Jihye;Lillehoj, Hyun S.;Hong, Yeong Ho
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.30 no.7
    • /
    • pp.1037-1047
    • /
    • 2017
  • Objective: Despite an increasing number of investigations into the pathophysiology of necrotic enteritis (NE) disease, etiology of NE-associated diseases, and gene expression profiling of NE-affected tissues, the microRNA (miRNA) profiles of NE-affected poultry have been poorly studied. The aim of this study was to induce NE disease in the genetically disparate Fayoumi chicken lines, and to perform non-coding RNA sequencing in the intestinal mucosal layer. Methods: NE disease was induced in the Fayoumi chicken lines (M5.1 and M15.2), and non-coding RNA sequencing was performed in the intestinal mucosal layer of both NE-affected and uninfected chickens to examine the differential expression of miRNAs. Next, quantitative real-time polymerase chain reaction (real-time qPCR) was performed to further examine four miRNAs that showed the highest fold differences. Finally, bioinformatics analyses were performed to examine the four miRNAs target genes involvement in the signaling pathways, and to examine their interaction. Results: According to non-coding RNA sequencing, total 50 upregulated miRNAs and 26 downregulated miRNAs were detected in the NE-induced M5.1 chickens. While 32 upregulated miRNAs and 11 downregulated miRNAs were detected in the NE-induced M15.2 chickens. Results of real-time qPCR analysis on the four miRNAs (gga-miR-9-5p, gga-miR-20b-5p, ggamiR-196-5p, and gga-let-7d) were mostly correlated with the results of RNAseq. Overall, ggamiR-20b-5p was significantly downregulated in the NE-induced M5.1 chickens and this was associated with the upregulation of its top-ranking target gene, mitogen-activated protein kinase, kinase 2. Further bioinformatics analyses revealed that 45 of the gene targets of gga-miR-20b-5p were involved in signal transduction and immune system-related pathways, and 35 of these targets were predicted to interact with each other. Conclusion: Our study is a novel report of miRNA expression in Fayoumi chickens, and could be very useful in understanding the role of differentially expressed miRNAs in a NE disease model.

Synthesis and characterization of three-dimensional monodispersed NiO/NiCo2O4 via Ni3[Co(CN)6]2 PBA nanocubes (Ni3[Co(CN)6]2 PBA 나노큐브를 통한 단분산된 3차원 구조의 NiO/NiCo2O4 제조 및 특성 평가)

  • Kwag, Sung Hoon;Lee, Young Hun;Kim, Min Seob;Lee, Chul Woo;Kang, Bong Kyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.27 no.3
    • /
    • pp.110-114
    • /
    • 2017
  • $NiO/NiCo_2O_4$ nanocubes were successfully synthesized via the calcination process of $Ni_3[Co(CN)_6]_2$ PBAs. The prepared monodispersed $Ni_3[Co(CN)_6]_2$ PBAs were aggregated by 'self-assembly' of the nuclei generated during the synthesis reaction. The self-assembly rate of the particles is affected by the temperature and the amount of surfactant SDBS (sodium dodecylbenzenesulfonate). FESEM analysis shows that monodispersed 200 nm PBA nanocubes are obtained at 0.25 g SDBS and $60^{\circ}C$ temperature. Thermal behavior was confirmed by thermogravimetric-differential thermal analysis (TG-DTA) to determine optimal calcination conditions. Then, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analyzes were performed to investigate the morphology and crystallinity of the particles precursors and $NiO/NiCo_2O_4$ nanocubes.