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PHOTOCHEMICAL REACTIONS OF PSEUDOSACCHARIN 3-ALLYL ETHER (PROBENAZOLE) AND ITS ALKYL ETHER

  • Yoon, Ung-Chan
    • Journal of Photoscience
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    • v.2 no.2
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    • pp.77-81
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    • 1995
  • Photoreactions of pseudosaccharin ethers have been investigated. Pseudosaccharin 3-allyl ether undergoes a facile photoreaction via reaction pathways involving homolysis of bond between pseudosaccharyl oxygen and 3-allyl carbon, and excited nucleophilic substitution of allyloxy group by solvent which are not quenched by oxygen present in the reaction. Product yield demonstrates that the homolysis pathway predominates over the nucleophilic substitution in ca. 7:1 ratio. In contrast, pseudosaccharin alkyl ethers follow different reaction routes to produce two products, solvent-substituted pseudosaccharin alkyl ethers and reduction products, 3-alkoxy-1, 2-benzisothiazoles. The formations of reduction products, 3-alkoxy-1, 2-benzisothiazoles are completely quenched by oxygen.

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Quality Attributes of Winning Products in the Korean Market

  • Son Eun-Il;Park Young-Taek
    • Proceedings of the Korean Society for Quality Management Conference
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    • 1998.11a
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    • pp.31-36
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    • 1998
  • 250 winning products from 1985 to 1997 in the Korean market were examined in order to find that what kind of product attributes have been major determinants of commercial success in the market. The major determinants are different with product categories. For example, function has been the most important determinant in electric home appliances, while portability has been the most important in telecommunication products. The results will be a cue to the future direction of new product development.

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On Sums of Products of Horadam Numbers

  • Cerin, Zvonko
    • Kyungpook Mathematical Journal
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    • v.49 no.3
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    • pp.483-492
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    • 2009
  • In this paper we give formulae for sums of products of two Horadam type generalized Fibonacci numbers with the same recurrence equation and with possibly different initial conditions. Analogous improved alternating sums are also studied as well as various derived sums when terms are multiplied either by binomial coefficients or by members of the sequence of natural numbers. These formulae are related to the recent work of Belbachir and Bencherif, $\v{C}$erin and $\v{C}$erin and Gianella.

Photochemistry of $\alpha$, $\alpha$-Dihalovalerophenones

  • Cho, Sungsu;Park, Bong Ser
    • Journal of Photoscience
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    • v.11 no.32
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    • pp.75-76
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    • 2004
  • ${\alpha}$,${\alpha}$-Dibromovalerophenone and ${\alpha}$,${\alpha}$-dichlorovalerophenone were prepared and their photochemical behaviors were investigated. The former gives C-Br cleavage products and the latter gives mainly the Yang photocyclization products upon irradiation. The reactivity of the chlorine substituted ketone turned out to be quite different from that of ${\alpha}$,${\alpha}$-difluorovalerophenone which gives both the cyclization and elimination products from the 1,4-biradical intermediate.

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Development of 3-dimensional strip rolling analysis

  • Jiang, Zheng-Lian;Park, Hae-Doo;Chung, Jin-Hwan
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.03a
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    • pp.253-256
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    • 1997
  • Through right deduction of theoretical equations and some disposal technique, a 3-dimensional strip rolling coupled analysis software has been successfully developed in this paper, which considers strip plastic deformation and roll elastic deformation simultaneously. The calculated examples with different kinds of rolling conditions all conform to the reality, and results show that the developed 3-dimensional program is applicable to the wide strip.

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A Multiobjective Model for Locating Drop-off Boxes for Collecting Used Products

  • Tanaka, Ken-Ichi;Kobayashi, Hirokazu;Yura, Kenji
    • Industrial Engineering and Management Systems
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    • v.12 no.4
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    • pp.351-358
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    • 2013
  • This paper proposes a multiobjective model describing the trade-offs involved in selecting the locations of drop-off boxes for collecting used products and transporting these products to designated locations. We assume the following reverse flow of used products. Owners of used products (cellular phones, digital cameras, ink cartridges, etc.) take them to the nearest drop-off box when the distance is reasonably short. We also assume that owners living closer to drop-off boxes dispose of more used products than do owners living farther from drop-off boxes. Different types of used products are collected, with each type requiring its own drop-off box. A transportation destination for each product is specified. Three objectives are considered: maximizing the volume of used products collected at drop-off boxes; minimizing the cost of transporting collected products to designated locations; and minimizing the cost of allocating space for drop-off boxes. We formulate the above model as a multiobjective integer programming problem and generate the corresponding set of Pareto optimal solutions. We apply the model to an area using population data for Chofu City, Tokyo, Japan, and analyze the trade-offs between the objectives.

A Study on the Effects of Functional Reusable Packing Containers for Marine Products on Logistics Rationalization (수산물의 기능성 재사용 포장용기 사용을 통한 물류합리화에 관한 연구)

  • Kim, Byeongchan;Yang, Daeyong
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.11 no.3
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    • pp.145-158
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    • 2015
  • Disposable marine product packaging materials such as wooden, Styrofoam, and corrugated cardboard boxes have a very low reuse rate, thus causing the logistics costs to rise and making it difficult to establish a unit load system for marine products. Disposable packing containers to be discarded are accompanied by resource and environmental issues home and abroad. Transportation vehicles for marine products have to return empty without loading different kinds of products after delivery due to the smell and properties of marine products, thus posing as an obstacle to logistics rationalization. In an effort to overcome those limitations, this study examined the stages of transportation including "producer-wholesale market in the producing area-commission merchant-wholesale market in the consumption area-commission merchant-quasi-wholesale market-consumer" and also analyzed the utilization and distribution of disposable packaging materials currently used in the circulation of marine products including wooden, Styrofoam, and corrugated cardboard boxes. Based on the analysis results, the investigator developed a logistics rationalization model capable of promoting semi-permanent reuse and lowering empty vehicle rate on return routes as an alternative to address environmental issues caused by disposable packaging materials, which have been an obstacle to the logistics rationalization of marine products, packaging costs in the process of repeating packing and unpacking at each stage of marine products circulation, and empty vehicle rates on return routes after marine products delivery.

The Effect of Adolescents′ Consumption Values on the Clothing Products Evaluation (청소년 소비가치가 의류 제품 정가에 미치는 영향)

  • 백선영;이선재
    • Journal of the Korean Society of Costume
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    • v.50 no.6
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    • pp.59-72
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    • 2000
  • The Purpose of this study is to determine the effect of new generation adolescents' clothing consumption values on their evaluation of clothing products. In the positive analysis, a questionnaire survey was conducted. Particularly, based on Sheth's (1991) theory, a focus group Interview was performed to develop the questionnaire on adolescents' clothing consumption values. The results of this study can be summarized as follows: First, young consumers have different values and clothing purchasing behavior from adults. To be specific, adolescents tended to appreciate fashionable and sensual values among clothing consumption values. Second, it was found that adolescents'personal values and their group-wise clothing consumption values affected their evaluation of clothing products. Such a finding may explain the relationship between value system and purchasing decisions. Namely, adolescents' evaluation of clothing products is affected by their value system. This finding supports the consumer value system suggested by the "expectation-value" theory. Thus, values and clothing products evaluation are neither separated from each other nor unrelated, but they affect each other in an abstract hierarchial structure. After all, through the route model, personal values affect clothing consumption values, which in turn affect clothing products evaluation. Besides, the clothing consumption values are affected by gender directly or indirectly. All in all, some specific indices regarding the abstract and hierarchial consumption values could be offered by analyzing the effects of adolescents' consumption values on their evaluation of clothing products in reference to the external clues of price and trademark manipulated, and thereby, the effects of consumption values on the positive clothing products evaluation could be determined in general.n general.

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Defective Medicine according to Product Liability Law (제조물책임법상 제조물로서 의약품의 결함)

  • Jeon, Byong-Nam
    • The Korean Society of Law and Medicine
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    • v.8 no.1
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    • pp.235-277
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    • 2007
  • In Product Liability law, the 'defection' of the manufactured products is its key concept, defined in detail. The concept had been already developed through the precedents and theories for the past years even before the PL law was enacted and the concept was listed. Especially, the medicine products need the different approach, because they might directly harm to the human life and body due to their being injected or taken, unlikely other manufactured articles. Since the medical products have the double contradictory functions such as effects and side effects, the defection decisions become so difficult. However, because there are high concerns that wrong medical products will directly harm the human life and body, the decision standards should be more strengthened. The decision standards should include the risk-effect standard as the considered components and make the customer-expecting standard as the final standard. The decision time for defection should be made considering the science technology level when the medical products were provided, not when the accident occurred. It is the most important for the manufacturers to prevent the damages by making and selling the non-defective medicine products for themselves, rather than by taking the legal remedy means afterwards. Therefore, the non-defective guidelines for the medicine manufacturers will help increase the effects and minimize the side-effects.

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Determinants of purchase intention for vegan fashion products - Application of the modified planned behavior model - (비건 패션제품 구매의도 결정요인 - 수정된 계획행동모델의 적용 -)

  • Yoh, Eunah
    • The Research Journal of the Costume Culture
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    • v.26 no.2
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    • pp.125-139
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    • 2018
  • This study explores determinants of purchase intentions for vegan fashion products based on the modified planned behavior model. Survey data from 434 university students were subjected to an analysis using descriptive statistics, factor analysis, and structural equation modeling. The results showed that almost half of the consumers surveyed recognized vegan fashion products and a little more than a half of consumers surveyed had purchase experience for vegan fashion products. Clothing, bags, and shoes are the most frequently purchased vegan fashion product categories. From the results of the model test, purchase intentions on vegan fashion products were determined by attitude, subjective norms, ethical responsibility, and ethical identity of the consumers. When consumers have a more positive attitude, have higher subjective norms, stronger ethical responsibility, and stronger ethical identity regarding the purchase of vegan fashion products, they are likely to have a greater intention to purchase vegan fashion products. The findings contribute to the literature by adding test results for vegan fashion products among the ethical product categories, highlighting the importance of the consideration of product category, which can give somewhat different results when exploring ethical consumption. Based on these findings, marketers need to use special tags or signage highlighting the ethical values and meanings of vegan fashion products to better communicate with target consumers with a high level of ethical responsibility and to help increase consumers' control over purchase behaviors through reducing barriers generated by insufficient product information.