• Journal of the Korean Chemical Society
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• v.54 no.1
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• pp.43-48
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• 2010

Polyamide derived from azo compound of o-amino phenol coupled with acetyl acetone, maleic anhydride acid and p-phenylene diamine were prepared. The prepared polyamide (PA) was refluxed with metal salts of transition metal ions include, $Co^{+2},\;Cr^{+2},\;Ni^{+2},\;Cu^{+2},\;Zn^{+2},\;Cd^{+2}$ and $Fe^{+3}$ in dimethyl formamide (DMF) in different molar ratios. These complexes were characterized and identified by elemental and thermal analysis, IR, 1H NMR spectra. The data showed that PA ligand coordinates with metal ions in abidentate manner through donating N=N and O-H groups. The metal ions are surrounded by coordinated water molecules and anions to establish the geometrical structure of the complexes. The thermal analysis degradation at different temperatures explained the weight loss of hydrated water and the decompositions of complexes until a constant weight loss of metal oxides is obtained.

• Journal of Welding and Joining
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• v.29 no.1
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• pp.74-79
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• 2011

Three different welding wires were used to study the effects of Al content on weld metal toughness and porosity formation in self-shielded arc welding. Weld metal microstructure showed that while wire with 1.3% Al content contains coarse $\delta$-ferrite, wires with less than 0.5% Al content showed no such phase. In addition to the microstructural differences, cleanliness in weld metal was also different among wires. It showed that weld metal toughness was influenced by the $\delta$-ferrite formation, cleanliness and Ni addition. Even though wires with less than 0.5% Al content showed higher weld metal toughness, they showed relatively poor workability, forming porosities in weld bead in lower arc voltages.

• The korean journal of orthodontics
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• v.44 no.3
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• pp.105-112
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• 2014

Objective: The purpose of this study was to evaluate the effects of three different surface conditioning methods on the shear bond strength (SBS) of metal brackets bonded directly to gold alloy with chemically cured resin. Methods: Two hundred ten type III gold alloy specimens were randomly divided into six groups according to the combination of three different surface conditioning methods (aluminum oxide sandblasting only, application of a metal primer after aluminum oxide sandblasting, silica coating and silanation) and thermocycling (with thermocycling, without thermocycling). After performing surface conditioning of specimens in accordance with each experimental condition, metal brackets were bonded to all specimens using a chemically cured resin. The SBS was measured at the moment of bracket debonding, and the resin remnants on the specimen surface were evaluated using the adhesive remnant index. Results: Application of metal primer after aluminum oxide sandblasting yielded a higher bond strength than that with aluminum oxide sandblasting alone (p < 0.001), and silica coating and silanation yielded a higher bond strength than that with metal primer after aluminum oxide sandblasting (p < 0.001). There was no significant change in SBS after thermocycling in all groups. Conclusions: With silica coating and silanation, clinically satisfactory bond strength can be attained when metal brackets are directly bonded to gold alloys using a chemically cured resin.

• Laser Solutions
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• v.9 no.2
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• pp.1-9
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• 2006

In this paper, we investigated the characteristics of fatigue fracture on TB(Tailored Blank) weldment by comparing the fatigue crack propagation characteristics of base metal with those of TB welded sheet used for vehicle body panels. We also investigated the influence of center crack on the fatigue characteristic of laser weld sheet of same thickness. We conducted an experiment on fatigue crack propagation on the base metal specimen of 1.2mm thickness of cold-rolled metal sheet(SPCSD) and 2.0mm thickness of hot-rolled metal sheet(SAPH440) and 1.2+2.0mm TB specimen. We also made an experiment on fatigue crack propagation on 2.0+2.0mm and 1.2+1.2mm thickness TB specimen which had center crack. The characteristics of fatigue crack growth on the base metal were different from those on 1.2+2.0mm thickness TB specimen. The fatigue crack growth rate of the TB welded specimens is slower in low stress intensity factor range $({\Delta}K)$ region and faster in high${\Delta}K$ region than that of the base metal specimens. The slant crack angle slightly influenced the crack propagation of the TB specimen of 2.0+2.0mm thinkness.

• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.625-628
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• 2012

We investigated the interaction between polyynes (linear carbon chains) and various metal nanoparticles (Ag, Au, and Cu) to provide insight into the optical properties of metal-polyynes systems prepared by different experimental techniques. Polyynes were produced by laser ablation in deionized water, metal nanoparticles solutions, and copper chloride solution. Metal nanoparticles complexes with polyynes were analyzed by Raman, surface-enhanced Raman scattering, and UV-vis spectroscopy.

• Proceedings of the KWS Conference
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• 2007.11a
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• pp.310-312
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• 2007

Two metal cored composite wires were manufactured to satisfy AWS F7A4-EC-G specification. They were used to weld EH36 grade steels with three different fluxes. Variation of carbon, manganese, silicon, titanium, and boron contents which affect the weld metal strength in weld metal was investigated.

• The Journal of Korean Academy of Prosthodontics
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• v.38 no.1
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• pp.1-11
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• 2000

Relining and rebasing are essential for long-term success and oral health in removable prosthodontics. Major features of failures between metal base and relining resins are adhesive failure due to lack of chemical bonding. The purpose of this study was to find a better metal primer and metal surface treatment method that enhance the bonding strength with relining resin materials. The surfaces of ticonium alloys were treated with $25{\mu}m$ sandblasting (Group A), stone wheel(Group B), stone wheel and EZ oxisor(Group C), $75{\mu}m$ sandblasting(Group D) and EZ oxisor application after $75{\mu}m$ sandblasting(Group E). They were subdivided into no primer application (Group I), MR bond application(Group II) and Metafast bonding liner (Group III). Then specimens were completed though being bonded with relining resins. The specimens were stored in $38^{\circ}C$ water for 48 hours and tensile strength was measured using the universal testing machine. The results were as follows, 1. Primer application groups showed higher bond strength than no primer application group(p<0.05). 2. In comparison with primer application groups, MR bond group showed higher bond strength than Meta fast bonding liner application group(p<0.05). 3. In comparison with surface treatment methods, Bond strengths of group A and B were significantly different with group C, D, and E, and group C were significantly different with group D, and E in no primer application group()(0.05). In primer application groups, group A, B, C were significantly different with group D and E(p<0.05). According to results of this study, Metal primer application and metal surface roughening were considered to be advantageous for relining of metal base dentures.

• Asian Journal of Turfgrass Science
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• v.11 no.3
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• pp.205-210
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• 1997

The metal spikes evaluated in this study significantly affected more negative on the turf wear and ball speed of putting green than alternative plastic spikes. 1.The metal spikes caused the most amount of wear compared with plastic spikes, athletic shoes and mountain-climbing shoes. On the other hand, athletic shoes caused the least amount of wear. Plastic spikes caused wear more than athletic shoes, hut apparently wear less than metal spikes. The wear from metal spike repaired later than any other tread types. 2.The wear from all kinds of shoe treads in wetcondition green were higher than in dry-condition green and the wear from metal spikes was more severe compared with plastic spikes in both green condition. 3. Ball speed of heavy compaction area by metal spike was reduced about 9% compared with that of light compaction area, hecause metal spikes made many holes in the putting green surface. On the other hand, plastic spikes did not affect hall speed of heavy and light compaction area in the putting green. Key words: Metal spike, Plastic spike, Wear, Ball speed.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2002.05a
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• pp.113-199
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• 2002

In this study, the toughness was evaluated by using the instrumented Charpy impact testing procedures for A15083-O aluminum alloy used in the LNG carrying and storing tank. The specimens were GMAW welded with four different mixing shield gas ratios (Ar100%+He0%, Ar67%+He33%, Ar50%+He50%, and Ar33%+He67%), and tested at four different temperatures(+25, -30, -85, and -196$^{\circ}C$ ) in order to investigate the influence of the mixing shield gas ratio and the low temperature. The specimens were divided into base metal, weld metal, fusion line, and HAZ specimen according to the worked notch position. From experiment, the maximum load increased a little up to -85$^{\circ}C$, and the maximum load and maximum displacement were shown the highest and the lowest at -196$^{\circ}C$ than the other test temperatures. The absorption energy of weld metal notched specimens was not nearly depends on test temperature and mixing shield gas ratio because the casting structure was formed in weld metal zone. In the other hand, the others specimens was shown that the lower temperature, the higher absorption energy slightly up to -85$^{\circ}C$ but the energy was decreased so mush at -196$^{\circ}C$

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.3
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• pp.120-126
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• 2006

In this paper, we investigated the characteristics of fatigue fracture on TB(Tailored Blank) weldment by comparing the fatigue crack propagation characteristics of base metal with those of TB welded sheet used for vehicle body panels. We also investigated the influence of center crack on the fatigue characteristic of laser weld sheet of same thickness. We conducted an experiment on fatigue crack propagation on the base metal specimen of 1.2mm thickness of cold-rolled metal sheet(SPCSD) and 2.0mm thickness of hot-rolled metal sheet(SAPH440) and 1.2+2.0mm TB specimen. We also made an experiment on fatigue crack propagation on 2.0+2.0mm and 1.2+1.2mm thickness TB specimen which had center crack. The characteristics of fatigue crack growth on the base metal were different from those on 1.2+2.0mm thickness TB specimen. The fatigue crack growth rate of the TB welded specimens is slower in low stress intensity factor range$({\Delta}K)$ region and faster in high ${\Delta}K$ region than that of the base metal specimens.