• Journal of Soil and Groundwater Environment
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• v.15 no.1
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• pp.66-72
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• 2010

The partitioning tracer method is to estimate the residual saturation of nonaqueous phase liquid (NAPL) in soils by analyzing tracer's retardation induced by the reversible partitioning of tracer with NAPL. This study is to estimate the residual diesel saturation in soils using the partitioning tracer method. Two-dimensional soil box was used to represent the 2-dimensional flows of groundwater and tracer solution in the saturated aquifer, and the soil box was filled with soil and then saturated with water. The residual diesel saturation was induced in saturated soil, and the partitioning tracer method was applied. The results from batch-partitioning experiment indicated that the diesel-water partitioning was linear with respect to tracer's concentration, and the partition coefficient of tracer between diesel and water was measured by their linearities. The groundwater flow in the saturated aquifer was simulated in the 2-dimensional soil box, and the residual diesel contamination was visually identified. The results from the partitioning tracer method with or without diesel in soils confirmed that 4-methyl-2-pentanol, 2-ethyl-1-butanol and 1-hexanol, can be used as a detecting method for diesel contamination. By the accuracies of estimations for diesel contamination using the partitioning tracer method, 2-ethyl-1- butanol showed the highest accuracy with 83%.

• Tribology and Lubricants
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• v.36 no.6
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• pp.385-390
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• 2020

It rains heavily, such as long rain and typhoons, during a typical rainy season in Korea. In this season, several fuel contamination accidents by water and vehicular problems caused by water contaminated fuel occur. Many research groups have studied the effects of water contaminated fuel on vehicles and environment. However the characteristics of water contaminated fuel have not been studied. In this study, we prepared diesel samples with a constant ratio of water (0~30 volume %) using an emulsifier. Then, we analyzed these diesel samples for their representative fuel properties. In the analytical results, diesel with 30% water showed an increase in fuel properties such as density (823→883 kg/㎥), kinematic viscosity (2.601→6.345 ㎟/s), flash point (47→56℃), pour point (-22→2℃), CFPP (cold filter plugging point) (-17→20℃) and copper corrosion number (1a→2a). The low temperature characteristics, such as low pour point and CFPP, blocks the fuel filter in the cold season. In addition, water contaminated diesel decreases lubricity (190→410 ㎛) under high frequency reciprocating rig (HFRR) and derived cetane number (54.81→34.25). The low lubricity of fuel causes vehicle problem such as pump and injector damage owing to severe friction. In addition, the low cetane diesel fuel increases exhaust gases such as NOx and particulate matters (PM) owing to incomplete combustion. This study can be used to identify the problems caused by water contamination to vehicle and fuel facilities.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.401-406
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• 2000

Spilling of petroleum hydrocarbons such as gasoline, motor oils, and diesel fuel from underground storage tanks (USTs) is a major source of contamination to ground water and soils. In response to the need of developing an effective and economical cleanup technique, this study investigates the effectiveness of using sonication to enhance the soil flushing method. The study involves laboratory testing, and the testing was conducted using a specially designed and fabricated device to determine the effect of sonication on contaminant removal. The sonication was applied at 20 kHz frequency under different power levels. Test soil was Joomoonjin Sand, and diesel fuel was used as a contaminant of soil flushing test. The results of the investigation show that sonication enhanced the contaminant removal from soils significantly, and the degree of enhancement varied with power levels of sonication. Based on the results of the study, it is concluded that the flushing method with sonication has a great potential to become an effective method for removing petroleum hydrocarbons from the contaminated ground.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.21-22
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• 2005

A study on the wear characteristics of the white metal(Sn-base alloy) bearing as a function of particle contamination level was conducted in order to establish control criteria of the lubricant in the 2-stroke marine diesel engine. Particle contamination level of the lubricants ranged from NAS 10 to 12 for the experiments. Bar-on-plate type wear test was performed using reciprocating wear tester. Based on this study it was found that there was no noticeable difference in weight loss of the white metal for NAS10 and NAS11(particle contamination level). Surface roughness of the white metal bearing after the wear test of 8hrs for the highly contaminated lubricant(NAS12 level) was up to $6{\mu}m$ in Rmax whilst that of the less contaminated lubricants(NAS10 & 11) was less than $1.5{\mu}m$ in Rmax.

• Journal of Soil and Groundwater Environment
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• v.22 no.1
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• pp.13-17
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• 2017

Over 30% of domestic soil contamination has occurred via petroleum products and complex oil. Moreover, contamination by complex oil is more intense than it is by a single petroleum product species. In this study, we analyzed sectional TPH (total petroleum hydrocarbon) pattern and sectional ratio of current domestically distributed petroleum products, such as kerosene, diesel, bunker C, and lubricant and complex oils, to determine pollution characteristics of the soil. In the TPH pattern, kerosene, which is a light distillate, had an early retention time, and lubricant oil, which is a heavy distillate, had a late retention time in the gas chromatogram. In addition, we obtained a complexly contaminated soil via diesel and lubricant oil from the Navy and inspected it for its ratio of complex oil species. The inspection results showed that this soil was contaminated with 85% diesel and 15% lubricant oil. The method developed in this study could be used to determine complex petroleum sources and ratios at sites with accidentally contaminated soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.347-350
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• 2002

The petrochemical products can cause soil and groundwater contamination during their transportation and the use of the products, and while being contained in underground storage tanks(USTs) throughout the leakage. To treat the contaminated soil, the bioventing method is suitable for the remediation of semi-volatile compounds, such as diesel and kerosene. Biofiltration is one of possible method to treat the off-gas produced in the process of the bioventing. This study is related to the usage, effectiveness of treatment, and feasibility of two types of biofilter system made of ceramic-compost and polymer respectively to treat diesel VOCs at constant retention time of 20 sec. Compost biofilter showed the average removal efficiency of 73 % when the inlet concentration increased to 20 ppmv. Increased the inlet concentration decreased the microbial activities as well as the removal efficiency. On the contrary, the removal efficiency of the polyurethane biofilter was maintained at 88 % at the inlet concentration of 13 ppmv during ten days and was obtained to 80 % at the inlet concentration of 30 ppmv in spite of the drop of the efficiency in the sudden increase of the inlet concentration. At the beginning of the experiment it showed low removal efficiency at low inlet concentration due to the low microbial activity, however, as experiments proceed the removal efficiency could be obtained more than 80% at high inlet concentration.

• KSBB Journal
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• v.26 no.1
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• pp.1-6
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• 2011

Contamination of soils, groundwater, air and marine environment with hazardous and toxic chemicals is major side effect by the industrialization. Bioremediation, the application of microorganism or microbial processes to degrade environmental contaminant, is one of the new environmental technologies. Because of low water solubility and volatility of diesel, bioremediation is more efficient than physical and chemical methods. The purpose of this study is biodegradation of diesel in sand by using Rhodococcus fascians, a microorganism isolated from petroleum contaminated soil. This study was performed in the column containing sand obtained from sea sides. Changes in biodegradability of diesel with various flow rates, inoculum sizes, diesel concentrations, and pH were investigated in sand column. The optimal condition for biodegradation of diesel by R. fascians in sand column system was initial pH 8 and air flow rate of 30 mL/min. Higher diesel degradation was achieved at larger inoculum size and the diesel degradation by R. fascians was not inhibited by diesel concentration up to 5%.

• Journal of the Korean Geotechnical Society
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• v.22 no.7
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• pp.45-54
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• 2006

Resistivity cone penetrometer test (RCPT) can be employed at a relatively low cost for in-situ delineation of subsurface contamination. While the resistivity measurement has a potential to investigate the subsurface contamination, resistivity measurements alone will lead to some degree of ambiguity in the results. In this study, capacitance measurement was incorporated into the RCPT to overcome the ambiguity inherent in electrical resistivity measurements. This study is focused on verifying the applicability of resistivity and capacitance measurements of CPT module to provide information on subsurface contaminated by heavy metal and petroleum hydrocarbon. Laboratory model tests were performed to evaluate the sensitivity of the measured resistivity and relative capacitance on the water content and different types of contaminants. Test results show that simultaneous measurement of electrical resistivity and capacitance can give more reliable information on subsurface contamination. Electrical measurements of the CPT module showed high applicability to be used in detecting saturated soils contaminated by heavy metal and diesel plume floating above the groundwater table.

• Tribology and Lubricants
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• v.24 no.3
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• pp.111-121
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• 2008

An integrated in-line oil monitoring detector assigned for continuous in situ monitoring multiple parameters of oil performance for predicting economically optimal oil change intervals and equipment condition control is presented in this study. The detector estimates oil deterioration based on the information about chemical degradation, total contamination, water content of oil and oil temperature. The oil oxidation is estimated by "chromatic ratio", total contamination is measured by the changes in optical intensity of oil in three optical wavebands ("Red", "Green" and "Blue") and water content is evaluated as Relative Saturation of oil by water. The detector is able to monitor oils with low light absorption (hydraulic, transformer, turbine, compressor and etc. oils) as well as oils with rather high light absorption in visible waveband (diesel and etc. oils). In a case study that the detector is applied to a diesel engine oil, it is found that the detector provides good results on oil chemical degradation as well as soot concentration.

• Tribology and Lubricants
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• v.19 no.5
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• pp.251-258
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• 2003

New method and device for the on-line measurement of soot concentration in a diesel engine oil are proposed, where the measurement principle is based mainly on attenuated internal total reflection. The detector were evaluated in various ranges of contaminated oils by carbon black particles. It was found that the proposed detector could be well used to monitor the oil deterioration due to soot contamination. Operational range of the detector was found from 0 to 5 mass percentage of soot content. Test results with water and fuel dilution showed that these effects were not remarkable. However, adsorption of carbon black particles onto the measurement surface was considered to be a critical problem of the detector. Effects of particle deposition on the interface was experimentally evaluated with the oil temperature and flow turbulence and discussed throughout this work.