• Analytical Science and Technology
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• v.28 no.5
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• pp.347-352
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• 2015

Chemical properties such as heat of formation and density of methylnitroimidazole derivatives were predicted and analyzed by using density functional theory (DFT). Successive addition of energetic nitro groups into an imidazole ring increases both the heat of formation and the density. Using the chemical property values computed by DFT, explosive performance was analyzed with the Cheetah program, and compared with those of TNT, RDX, and HMX, which are currently used widely in military systems. When both C-J pressure and detonation velocity were used as explosive performance, methyldinitroimidazole derivatives show better performance than TNT, while methyltrinitroimidzole is almost close to RDX. Since methylnitroimidazole derivatives have a good merit, i.e. low melting point for melt loading, they are forecasted to be used widely in various military and civilian application.

• Explosives and Blasting
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• v.38 no.2
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• pp.13-21
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• 2020

The shaped charge was used in explosive demolition of a steel frame structure, but it was often not used because it was limited to use and impossible to supply at domestic and overseas. Existing linear shaped charge did not have sufficient cutting performance to cut steel frame structures with a huge scale and thick steel plate. To solve these problems, we produced a device that could generate metal jets using industrial explosives of high detonation velocity and pressure. In this study, we made a charging container of three types which applicable to explosive demolition of steel frame structures. The experiment of cutting performances was carried out to evaluate the effect of cutting of charging containers on the various thicknesses of the H-beam and steel plate. As a result of the experiment, sufficient cutting performance was confirmed.

• Explosives and Blasting
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• v.40 no.2
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• pp.1-14
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• 2022

Numerical simulation is the most widely used methods for evaluating blasting performance. This study, conducted the numerical analysis of shock chamber model to evaluate the pressure confine effect of the stemming material and plug device. The stemming effect was compared and evaluated with that of the STF-based stemming material currently under development and sand, which is a commonly used blast stemming material. Furthermore, to verify of enhancement the confine effect inside blast hole pressure, three types of stemming plugs were adopted for the numerical analysis. The numerical simulation results revealed that the STF-based stemming materials were superior to the general stemming material. Also, It is evaluated that the STF-based stemming and Plug system can not only prevent detonation gas from overflowing the borehole prematurely, but also prolong the action time and scope of detonation gas in the borehole effective.

• Explosives and Blasting
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• v.25 no.1
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• pp.45-52
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• 2007

When emulsion explosives(1kg/cartridge) are loaded into a long vertical borehole at open blasting site, they undergo an Impact corresponding to 117.6J of shock energy. After shocking. the crystallization of emulsion nay happen immediately. Furthermore, it nay cause a desensitization, arising from increase in the density of emulsion explosive by the breakage of sensitizer. In this paper, some experimental work was performed using PVC pipe equipment(50mm diameter and 12m lengths) to investigate the effects of loading impart of emulsion explosive. It is shown that detonation energy decreases up to 26% of the normal state value and this effect is less than 3% of the total performance of emulsion explosives in borehole blasting.

• Journal of the korean Society of Automotive Engineers
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• v.14 no.5
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• pp.30-40
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• 1992

Spark knock obstructs any improvement in the efficiency and performance of an engine. As the knock mechanism of spark ignition engine, the detonation and the autoignition theory have been offered. In this paper, the knock model was established, which was able to predict the onset of knock and knock timing of spark ignition engine by the basis of autoignition theory. This model was a function of engine speed and equivalent air-fuel ratio. When this established knock model was tested from 1000rpm to 3000rpm of engine speed data, maximum error was crank angle 2 degrees between measured and predicted knock time. And the main results were as follows by the experimental analysis of spark knock in spark ignition engine. 1) Knock frequency was increased as engine speed increased. 2) Knock amplitude was increased as mass of end gas increased. 3) Knock frequency was occured above minimum 18% mass fraction of end gas.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.922-925
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• 2011

Smoothed Particle Hydrodynamics (SPH) is a Lagrangian method widely used for the modeling fluid flows. Simulations of explosions require, besides the hydrodynamic equations, a realistic equation of state, an energy source term, and a set of chemical kinetic equations to follow the composition changes of the gas during the explosion. The performance of the hydrodynamic equations is investigated in the framework of the Sedov-Taylor blast-wave. The implementation of chemical kinetic equations and equation of state is studied with 1D detonation of TNT slab. Our results are compared to those from analytical and experimental studies.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.363-366
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• 2012

Detonative combustion is considered as a promising combustion mechanism for improving thermodynamic efficiency of power generation systems as a PGC, as well as high-speed propulsion systems. Among the various types of detonative combustion, RDE is fascinated by many researchers because of the simplicity and continuos operation characteristics. Present paper is an introduction to the physical and operational concept of RDE with a brief history of RDE researches and recent development activities. Additional discussions will devoted to the relevance to the tangential mode instabilities in liquid rocket engines and improvement of liquid rocket performance.

• Journal of the Korea Institute of Military Science and Technology
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• v.12 no.3
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• pp.378-387
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• 2009

The shaped charge consists of the cast or pressed explosive and the metal liner. The pressure formed in detonation wave is so high that the liner is collapsed and the jet of high temperature, pressure and velocity is produced. The jet penetrates the target. In this paper, the simulation for optimization of flexible linear shaped charge(FLSC) was carried out by AUTODYNE program. Based on the results of simulation, we made a prototype of FLSC and evaluated penetration performance, flexibility and its application. The test result of prototype was compared with that of simulation.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.2
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• pp.112-119
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• 2016

Many studies have been conducted on the performance of a passive autocatalytic recombiner (PAR), but not many have focused on the locations where the PAR is installed. During a severe accident in a nuclear reactor containment, a large amount of hydrogen gas can be produced and released into the containment, leading to hydrogen deflagration or a detonation. A PAR is a hydrogen mitigation method that is widely implemented in current and advanced light water reactors. Therefore, for this study, a PAR was installed at different locations in order to investigate the difference in hydrogen reduction rate. The results indicate that the hydrogen reduction rate of a PAR is proportional to the distance between the hydrogen induction location and the bottom wall.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2003.11a
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• pp.72-77
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• 2003

Nano-diamonds were added to Ultra-high molecular weight polyethylene (UHMWPE) to improve the tribological properties of UHMWPE. Nano-diamonds which have a diameter of about 5-10nm were produced by detonation. UHMWPE/nano-diamonds composites were fabricated by hot pressing method. It is shown that friction coefficient was increased and wear resistance was improved as nano-diamonds were added to UHMWPE because of excellent mechanical properties of nano-diamonds located on UHMWPE surface.