• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1479-1484
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• 2014

Based on the full optimized molecular geometric structures at B3LYP/cc-pvtz method, a new designed compound, 4,6,8-trinitro-4,5,7,8-tetrahydro-6H-furazano[3,4-f ]-1,3,5-triazepine was investigated in order to look for high energy density compounds (HEDCs). The analysis of the molecular structure indicates that the seven-membered ring adopts chair conformation and there exist intramolecular hydrogen bond interactions. IR spectrum and heat of formation (HOF) were predicted. The detonation velocity and pressure were evaluated by using Kamlet-Jacobs equations based on the theoretical density and condensed HOF. The bond dissociation energies and bond orders for the weakest bonds were analyzed to investigate the thermal stability of the title compound. The results show that $N_1-N_6$ bond is the trigger bond. The crystal structure obtained by molecular mechanics belongs to $Pna2_1$ space group, with lattice parameters Z = 4, a = 15.3023 ${\AA}$, b = 5.7882 ${\AA}$, c = 11.0471 ${\AA}$, ${\rho}=2.06gcm^{-3}$. In addition, the analysis of frontier molecular orbital shows the title compound has good stability and high chemical hardness.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.97-107
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• 2017

Fluid dynamic constant volume combustion technology detonation has been paid attention as a "game-changing" technology to overcome the efficiency and performance limitation of the present constant pressure combustion systems. For the past several years, a number of experimental and CFD-based theoretical studies have been conducted for the basic operation tests of RDE's. Present paper include a comprehensive survey on the research activities on RDE and its core technologies comprehensively to provide a direction for the future RDE researches, yet unfamiliar domestically.

• Explosives and Blasting
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• v.41 no.1
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• pp.19-31
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• 2023

There are various types of explosives, and each explosive has different characteristics such as water resistance, energy required for detonation, and crushing power, so understanding the characteristics of explosives is important for safe use and performance improvement. Computer simulation is used indirectly along with various experiments to understand the characteristics of explosives, and a state equation is used to express the explosive detonation process through computer simulation. In this study, the explanation of JWL EOS, which is mainly used among the state equations of explosives, and the cylinder expansion experiment to calculate the coefficient of JWL EOS were implemented as ANSYS AUTODYN and compared and analyzed with the actual experimental results. As a result, an error rate of around 20% occurred, and it was found that the overall change pattern of pressure and energy was consistent with the previously published experimental results.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.2118-2119
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• 2008

The paper introduces a new Distribution Class ground lead disconnector design that not only extends the claimable detonation range well below the 20 amps specified in industry standards, but is very durable when exposed to severe arrester durability tests. Finally, this paper shows how this next generation disconnector interacts with the connected arrester to improve the overvoltage withstand capability of the arrester assembly.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.5
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• pp.440-448
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• 2015

Kinetic energy(KE) rod warhead system is a new interceptor which combines advantages of existing ones. This system is less dependant on a precision guidance than direct hit type warhead and gives high penetration rates than blast fragmentation type warhead. In this paper, isotropic KE rod warhead system is introduced with detonation/deployment model. A penetration effects of the deployed rods are calculated using TATE penetration equation. Also, an engagement performance analysis method is suggested. Finally, an optimal detonation time and engagement geometry is derived by Monte-Carlo simulation in various engagement situation using the performance analysis factor.

• Explosives and Blasting
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• v.40 no.4
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• pp.1-14
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• 2022

To review the appropriateness of current regulations on the simple explosive storage facility, the effects of internal explosion on the structural stability of the standard storage facility were analyzed by means of both FEM analyses and field experiments. As a result, it was found that the explosion-proof performance of the existing storage structure was not sufficient for 15 kg of emulsion-type explosive. Thus, an alternative method of splitting explosives was tested by conducting sympathetic detonation experiments. This method worked properly as expected, and the proper amount of splitted explosive was determined according to the test results. In addition, a storage structure with open ceiling was found to be very effective because explosion pressure was released so rapidly that the damage of the facility could be reduced significantly. Hence, such a structural pattern was proposed as a new design scheme for simple explosive storage facility.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.519-524
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• 2008

A numerical study is conducted to investigate propulsion performance enhancement based on S225 experiment case of ISL(French-German Research Institute of Saint-Louis)'s superdetonative ram accelerator. For govern equation, multi-species Navier-Stokes equation coupled with Baldwin-Lomax turbulence modeling is used. Govern equation is discretized by Roe's FDS and integrated by LU-SGS time integration. Detailed chemical reaction about $H_2/O_2/CO_2$ for high pressure is considered. $2H_2+O_2+2.5CO_2$ mixture was used for propellant gas. For the same over-driven factor, the launching speed of computation was faster than one of S225. Another configuration and condition of S225 was applied. A flame structure is very different from S225. For strong mixture case, it shows ignition by viscous effect. Acceleration and speed increment is higher than S225 computation and experiment. By using more strong mixture, propulsion performance was enhanced.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.2
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• pp.131-138
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• 2015

Energetic monomers with new design concept were synthesized for energetic prepolymers. Novel energetic monomers consisted of ring-opening polymerizable oxirane and a molecular explosive moiety instead of small explosophores as energetic functional groups. According to the design concept, glycidyl dinitroazetidine (GDNAZ) and glycidyl nitroazetidinol(GNAZO) energetic monomers were synthesized, respectively, and characterized by NMR, EA and GC MS. Heat of formation and detonation performance were calculated by theoretical method to evaluate energy performance of these novel energetic monomers. The result revealed that GDANZ and GNAZO possessed high potential as new energetic monomers for synthesizing energetic prepolymers and binders in PBXs.

• Explosives and Blasting
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• v.19 no.1
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• pp.101-110
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• 2001

Depleted uranium (DU) outperforms tungsten heavy alloys (WHA) by about 10%. Because of environmental and hence, political concerns, there is a need to improve WHA performance, in order to replace the DU penetrators. A technique of metal powder compaction by the detonation of an explosive has been applied to tungsten-titanium(W-Ti) powder materials that otherwise may be difficult to fabricate conventionally or have dissimilar, nonequilibrium, or unique me1astab1e substructures. However, the engineering properties of compacted materials are not widely reported and are little known especially for the "unique" composition of W-Ti alloy. To develop high-performance tungsten composites with superior ballistic attributes, it is necessary to understand, carefully document controlled experimental results, and develop basic computational models for potential composites with controlled microstructures. A detailed understanding and engineering application of W-Ti alloy can lead to the development of new structural design for engineering components and materials.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.11a
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• pp.172-175
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• 2005

Since, similar to other commercial launch vehicles, various kinds of pyrotechnique devices are used in the KSLV-I(Korea Space Launch Vehicle), the electronic equipment on the vehicle equipment bay is exposed to the sever pyroshock environment during Pyrotechnique device detonation. In order to confirm the survivability of electrical instruments from these pyroshock conditions, shock tests are performed by using a pyroshock simulation during development and qualification phase. In this paper, the pyroshock simulator installed in KARI(Korea Aerospace Research Institute) are briefly introduced, and its performance of pyroshock generating is compared with the measured shock response spectrums from small scaled fairing jettisoning tests. The results show that the pyroshock simulator is still proper to generate severe pyroshocks similar to real pyrotechique detonating conditions, but the redesign on the test jigs is necessary to improve its test performance.