• Analytical Science and Technology
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• v.37 no.1
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• pp.12-24
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• 2024

In this study, laser-induced breakdown spectroscopy (LIBS) was used to estimate the degree of rice polishing. As-threshed rice seeds were dehusked and polished for different times, and the resulting grains were analyzed using LIBS. Various atomic, ionic, and molecular emissions were identified in the LIBS spectra. Their correlation with the amount of polished-off matter was investigated. Na I and Rb I emission line intensities showed linear sensitivity in the widest range of polished-off-matter amount. Thus, univariate models based on those lines were developed to predict the weight percent of polished-off matter and showed 3-5 % accuracy performances. Partial least squares-regression (PLS-R) was also applied to develop a multivariate model using Si I, Mg I, Ca I, Na I, K I, and Rb I emission lines. It outperformed the univariate models in prediction accuracy (2 %). Our results suggest that LIBS can be a reliable tool for authenticating the degree of rice polishing, which is closed related to nutrition, shelf life, appearance, and commercial value of rice products.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.19 no.1
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• pp.88-98
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• 2014

Despite of emerging and increasing concerns to microplastics, no standard methodology has not been proposed for determination of microplastics. This study aims to develop the analysis method for microplastics in seawater by overviewing methodologies proposed by previous studies and by assessing some processes in those methodologies which possibly cause uncertainties in microplastic determination. Furthermore, we present preliminary results of distribution characteristics of microplastics in seawater of Incheon/Kyeonggi coastal region which is based on our new methodology. Microplastics in surface microlayer (SML) and subsurface water (SSW) were collected using mesh screen and planktonic nets (trawl net with $330{\mu}m$ mesh size and hand net with $20{\mu}m$ mesh size), respectively. Microplastics with < $300{\mu}m$ was predominant, indicating hand net as the better collection tool for SSW. As for SML, FT-IR based microplastic concentration was well matched with naked-eye based concentration which has been used in most of previous studies. However, a poor relationship was observed for SSW, indicating that concentration data of previous SSW studies should be corrected. Incheon/Kyeonggi bay seawater contained the similar concentration range with those in coastal region of the Nakdong River. Our methodology can be used as a basic tool for further microplatic studies.

• Journal of Korea Water Resources Association
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• v.51 no.9
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• pp.803-812
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• 2018

The purpose of this study is to develop Particle Swarm Optimization (PSO) automatic calibration algorithm with multi-objective functions by Python, and to evaluate the applicability by applying the algorithm to the Soil and Water Assessment Tool (SWAT) watershed modeling. The study area is the upstream watershed of Gongdo observation station of Anseongcheon watershed ($364.8km^2$) and the daily observed streamflow data from 2000 to 2015 were used. The PSO automatic algorithm calibrated SWAT streamflow by coefficient of determination ($R^2$), root mean square error (RMSE), Nash-Sutcliffe efficiency ($NSE_Q$), and especially including $NSE_{INQ}$ (Inverse Q) for lateral, base flow calibration. The results between automatic and manual calibration showed $R^2$ of 0.64 and 0.55, RMSE of 0.59 and 0.58, $NSE_Q$ of 0.78 and 0.75, and $NSE_{INQ}$ of 0.45 and 0.09, respectively. The PSO automatic calibration algorithm showed an improvement especially the streamflow recession phase and remedied the limitation of manual calibration by including new parameter (RCHRG_DP) and considering parameters range.

• Journal of Environmental Science International
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• v.24 no.5
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• pp.623-631
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• 2015

Microarray technology provides a unique tool for the determination of gene expression at the level of messenger RNA (mRNA). This study, the mRNA expression profiles provide insight into the mechanism of action of cadmium in Fleshy shrimp (Fenneropenaeus chinensis). The ability of genomic technologies was contributed decisively to development of new molecular biomarkers and to the determination of new possible gene targets. Also, it can be approach for monitoring of trace metal using oligo-chip microarray-based in potential model marine user level organisms. 15K oligo-chip for F. chinensis that include mostly unique sets of genes from cDNA sequences was developed. A total of 13,971 spots (1,181 mRNAs up- regulated and 996 down regulated) were identified to be significantly expressed on microarray by hierarchical clustering of genes after exposure to cadmium for different conditions (Cd24-5000 and Cd48-1000). Most of the changes of mRNA expression were observed at the long time and low concentration exposure of Cd48-1000. But, gene ontology analysis (GO annotation) were no significant different between experiments groups. It was observed that mRNA expression of main genes involved in metabolism, cell component, molecular binding and catalytic function. It was suggested that cadmium inhibited metabolism and growth of F. chinensis.

• Journal of the Korean GEO-environmental Society
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• v.11 no.7
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• pp.45-49
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• 2010

We have developed and demonstrated the use of a new kinetic method as an analytical tool for the measurement of $HO_2{\cdot}/O_2{\cdot}^-$. This new method is based on the reduction of $Fe^{3+}$-Ethylene Diamine Tetra Acetate, EDTA) into $Fe^{2+}$-EDTA by $HO_2{\cdot}/O_2{\cdot}^-$ and the well-known Fenton-like reaction of $H_2O_2$ and $Fe^{2+}$-EDTA to yield the hydroxyl radicals ($OH{\cdot}$). Since this method for $HO_2{\cdot}/O_2{\cdot}^-$ shows high sensitivity and allows a simple calibration system, it can contribute significantly to understanding the basic functions of $HO_2{\cdot}/O_2{\cdot}^-$ in advanced oxidation processes for water treatment. Moreover, the present technique has the advantage of using inexpensive and easily available nonenzymatic reagents and of being insensitive to the moderate concentration of possible interferences often found in aqueous phase.

• Analytical Science and Technology
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• v.14 no.2
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• pp.95-102
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• 2001

A comprehensive analytical method of endocrine disruptors[i.e., nonylphenol(NP), octylphenol(OP), bis(2-ethylhexyl) phthalate(BEHP)] in meat or pork samples was developed. The method employed closed culture tube extraction with dichloromethane and solvent exchange to iso-hexane and SPE(2g) aminopropyl column, followed by determination on gas chromatography linked to mass spectrometry(GC/MS) operated in the single ion monitering(SIM) mode. For the multipoint recovery of nonylphenol, octylphenol and bis(2-ethlhexyl) phthalate OP, NP were showen good recoveries in $0.125-1.25{\mu}g/g$ range of concentration, and BEHP more good recoveries in $0.0125-12.5{\mu}g/g$ wide range of concentration. The present method was applied to beef or pork samples of mart and butcher in Cheonju city and near Cheonju. The range of concentrations was respectively, $0.06-0.24{\mu}g/g$ in nonylphenol(NP) and $0.36-2.35{\mu}g/g$ in bis(2-ethylhexyl) phthalate(BEHP), but octylphenol(OP) was not dected in any samples. This method provides a powerful analytical tool to investigate a wide range of endocrine disruptors in biological samples of limited quantity.

• Knowledge Management Research
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• v.21 no.1
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• pp.27-40
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• 2020

Response surface methodology (RSM) empirically studies the relationship between a response variable and input variables in the product or process development phase. The ultimate goal of RSM is to find an optimal condition of the input variables that optimizes (maximizes or minimizes) the response variable. RSM can be seen as a knowledge management tool in terms of creating and utilizing data, information, and knowledge about a product production and service operations. In the field of product or process development, most real-world problems often involve a simultaneous consideration of multiple response variables. This is called a multiple response surface (MRS) problem. Various approaches have been proposed for MRS optimization, which can be classified into loss function approach, priority-based approach, desirability function approach, process capability approach, and probability-based approach. In particular, the loss function approach is divided into univariate and multivariate approaches at large. This paper focuses on the univariate approach. The univariate approach first obtains the mean square error (MSE) for individual response variables. Then, it aggregates the MSE's into a single objective function. It is common to employ the weighted sum or the Tchebycheff metric for aggregation. Finally, it finds an optimal condition of the input variables that minimizes the objective function. When aggregating, the relative weights on the MSE's should be taken into account. However, there are few studies on how to determine the weights systematically. In this study, we propose an interactive procedure to determine the weights through considering a decision maker's preference. The proposed method is illustrated by the 'colloidal gas aphrons' problem, which is a typical MRS problem. We also discuss the extension of the proposed method to the weighted MSE (WMSE).

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.8
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• pp.2001-2011
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• 1993

This study deals with the machining of sculptured surfaces on 5-axis CNC milling machine with end mill cutter. The study (I) has the following contents. In 5-axis CNC milling, CL-data consist of CC-data and cutter axis direction vector at the CC-point. Thus, in machining of the sculptured surface on 5-axis CNC milling machine, determination of the direction vector of the milling cutter is very important. The direction vector is obtained by the fact that bottom plane of the milling cutter must not interfere with the free-form surface being machined. The interference is checked by the z-map method which can be applied in all geometric types of the sculptured surfaces. After generating NC part programs from 5-axis post-processing algorithms, sculptured surfaces were machined with 5-axis CNC milling machine (CINCINNATI MILACRON, 20V-80). From these machining tests, it was shown that the machining of the free-form surfaces on 5-axis CNC milling machine with the end mill has smaller cusp heights and shorter cutting time than on 3-axis CNC milling machine with the ball-end mill. Thus, 5-axis CNC end milling was effective machining method for sculptured surfaces. The study (II) deals with the prediction of cusp height and the determination of tool path interval for the 5-axis machining of sculptured surfaces on the basis of study(I).

• Journal of the Korean Geophysical Society
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• v.4 no.2
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• pp.113-120
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• 2001

The discrete wavelet transform(DWT) has potential as a tool for supplying discriminatory attributes with which to distinguish seismic events. The wavelet transform has the great advantage over the Fourier transform in being able to localize changes. In this study, a discrete wavelet transform is applied to seismic traces for identifying seismic events and picking of arrival times for first breaks and S-wave arrivals. The precise determination of arrival times can greatly improve the quality of a number of geophysical studies, such as velocity analysis, refraction seismic survey, seismic tomography, down-hole and cross-hole survey, and sonic logging, etc. provide precise determination of seismic velocities. Tests for picking of P- and S- wave arrival times with the wavelet transform method is conducted with synthetic seismic traces which have or do not have noises. The results show that this picking algorithm can be successfully applied to noisy traces. The first arrival can be precisely determined with the field data, too.

• Journal of Korean Academy of Nursing Administration
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• v.7 no.2
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• pp.205-221
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• 2001

It will become more and more popular to use the long-term care facilities and home health care services with the chronic disease increasing. It depends on how much the consumers would pay and purchase the services. They might get more benefits from that kind of services than from ordinary hospitalization. So far, the study of determining the medical service price has focused most often on the efforts from the providers' view. But it must be reasonable to include the consumers' value for the service. This study was performed to assess WTP(Willingness to Pay) for home health care service in order to apply to the determination of nursing price in a reasonable manner. In this study, respondents were asked if they would pay for the service's intangible benefits under the four different types(open-ended minimum WTP, open-ended maximum WTP, bidding WTP, referendum WTP). The contingent valuation method is a potentially useful tool in understanding how people value the benefits of the service. As a result, average open-ended minimum WTP was W16,015 per day among 65 respondents. Average open-ended maximum WTP was W29,154 per day among 65 respondents. Average bidding WTP was W26,300 per day among 65 respondents. Average referendum WTP was W22,200 per day among 70 respondents. The results of regression analyses were also consistent with theoretical prediction, e.g., increasing WTP with consumers' value for the service, state of patients, and household income. This study demonstrated that it was more reasonable to consider the consumers' value in determining the services' price. In addition, a further study is needed to test the validity of this CV method and to determine a proper nursing price based on the consumers' view.