• 제목/요약/키워드: Detection process

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Accurate Analysis of Trace Phthalates and Method Validation in Cosmetics using Gas Chromatography with Mass Spectrometric Detection (화장품에 함유된 미량의 프탈레이트 함량을 정확히 분석하기 위한 가스크로마토그래피-질량분석 시험법 및 그 시험법의 유효성)

  • Kim, Min-Kee;Jeong, Hye-Jin;Cho, Jun-Cheol
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.1
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    • pp.33-41
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    • 2012
  • An effective, environmentally friendly analytic methods using gas chromatography with mass spectrometric detector (GC-MSD) have been developed for the quantitative analysis of trace phthalate levels in cosmetics such as nail lacquer and hair spray. Since such cosmetics are largely comprised of organic solvents, conventional clean-up methods that have been widely used for phthalate analyses are in adequate. In addition, analysis of trace phthalate levels is notorious for its sensitivity to contamination, which causes high analytical values. A direct sample dilution method using an organic solvent was adopted to the sample preparation process to determine the exact amounts of phthalates and simultaneously avoid the high risk of secondary contamination. The method has many advantages including high accuracy, sensitivity, and simplicity in sample preparation. Dibutyl phthalate (DBP) and di (2-ethylhexyl) phthalate (DEHP) were selected for analysis because they have been frequently detected in cosmetics and consistently reported as endocrine disruptors in humans and animals. Internal standard method using two deuterium substitutes (DBP-$d_4$, DEHP-$d_4$) as the internal standard was also used. The results of 'Method validation' showed the capabilities of this method for the routine analysis of phthalates at the ppm level. The recovery ranges were between 95 % and 106.1 %, and relative standards deviations (RSD) were less than 3.9 % in fortified nail lacquer and hair spray samples at the concentration of $25{\mu}g/g$.

A Study on the Threats of Wiretapping and Effective Security Management Strategies (도청보안의 취약성 및 개선방안에 관한 연구)

  • Lee, Young Ho;Choi, Kyung Cheol;Woo, Sang Yeob
    • Korean Security Journal
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    • no.62
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    • pp.347-367
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    • 2020
  • Rapid advancement of technology in today's society has allowed for easy access and use of data, promoting the process of informationization. Along with the merits of such development, unintended consequences of security risks involving wiretapping have been increasing as well. The security threats posed by wiretapping technology must be addressed by every organization and individual, as it could be used to leak confidential information about the nation's security, military and diplomatic strategies, industrial technologies, and personal information. Despite increasing threats stemming from the surrounding nations using advanced wiretapping technology, there is a lack of awareness at the government level, and the existing security measures for detecting and counteracting the wiretapping equipment are ineffective. In this research, the authors offered technical suggestions for improving the security strategies against the threats of wiretapping and information leakage by conducting a content analysis. The authors suggested the units of an agency be assigned a security grade based on its importance, and that adequate security equipment should be operated according to the grade. For instance, around-the-clock surveillance is recommended for grade-1 facilities, and portable wiretapping equipment detectors should be used to protect conference rooms and other key sites.

Biological stability in the ozone and peroxone pretreatment systems in river water (하천수 내 생물학적 안정성에 따른 유기물 특성변화와 오존산화기반 전처리 연구)

  • Park, Se-Hee;Noh, Jin-Hyung;Park, Ji-Won;Maeng, Sung-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.2
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    • pp.159-168
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    • 2018
  • Climate change is believed to increase the amount of dissolved organic matter in surface water, as a result of the release of bulk organic matter, which make difficult to achieve a high quality of drinking water via conventional water treatment techniques. Therefore, the natural water treatment techniques, such as managed aquifer recharge (MAR), can be proposed as a alternative method to improve water quality greatly. Removal of bulk organic matter using managed aquifer recharge system is mainly achieved by biodegradation. Biodegradable dissolved organic carbon (BDOC) and assimilable organic carbon (AOC) can be used as water quality indicators for biological stability of drinking water. In this study, we compared the change of BDOC and AOC with respect to pretreatment methods (i.e., ozone or peroxone). The oxidative pretreatment can transform the recalcitrant organic matter into readily biodegradable one (i.e., BDOC and AOC). We also investigated the differences of organic matter characteristics between BDOC and AOC. We observed the decreases in dissolved organic carbon (DOC) and the tryptophan-like fluorescence intensities. Liquid chromatographic - organic carbon detection (LC-OCD) analysis also showed the reduction of the low molecular weight (LMW) fraction (15% removed, less than 500 Da), which is known to be easily biodegradable, and the biopolymers, high molecular weight fractions (66%). Therefore, BDOC consists of a broad range of organic matter characteristics with respect to molecular weight. In AOC, low molecular weight organic matter and biopolymers fraction was reduced by 11 and 6%, respectively. It confirmed that biodegradation by microorganisms as the main removal mechanism in AOC, while BDOC has biodegradation by microorganism as well as the sorption effects from the sand. $O_3$ and $O_3+H_2O_2$ were compared with respect to biological stability and dissolved organic matter characteristics. BDOC and AOC were determined to be about 1.9 times for $O_3$ and about 1.4 times for $O_3+H_2O_2$. It was confirmed that $O_3$ enhanced the biodegradability by increasing LMW dissolved organic matter.

Characteristics of Volatile Organic Compounds and Aldehydes Emission from Yellow poplar (Liriodendron tulipifera L.) (백합나무 판재의 VOCs 및 Aldehydes 방출특성)

  • Lee, Min;Park, Sang-Bum;Lee, Sang-Min;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.4
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    • pp.357-366
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    • 2014
  • Based on fundamental properties and machining characteristics of Yellow poplar (Liriodendron tulipifera L.), it has well performance on machinability or workability, drying, and fine surface. Additionally, yellow poplar is light weight and has bright color with high performance of bending processing, so it could be used for furniture or artworks materials and wood-based panel materials. Recently, public attention has been focused on indoor air quality, and Ministry of environment drift more tight regulation on indoor air quality for an apartment house and public facility with the times. Construction materials has been assessed emission of volatile organic compounds (VOCs) and formaldehyde according to law (No.10789), so yellow poplar is also needed to assess these emission characteristics. Emission of VOC and aldehyde compounds from dry and green wood condition of yellow poplar were investigated with KS M 1998:2009. Based on results, more than 30 compounds were detected from yellow poplar, and lower NVOC (natural VOC) were emitted than AVOC (Anthropogenic VOC) and OVOC (other VOC). Formaldehyde emission was lower than $5{\mu}g/m^3$ and acetaldehyde, ketone, and propionaldehyde were detected from yellow poplar. From dry yellow poplar, m-Tolualdehyde ($33.6{\mu}g/m^3$) was additionally detected while no detection of propionaldehyde. After drying process, amount of ketone emission increased significantly. The unique smell of yellow poplar may not only come from emission of acetaldehyde and propionaldehyde.

CLINICAL STUDY OF POSITRON EMISSION TOMOGRAPHY WITH $[^{18}F]$-FLUORODEOXYGLUCOSE IN MAXILLOFACIAL TUMOR DIAGNOSIS (구강 악안면 영역의 암종 진단에 있어서 $[^{18}F]$-Fluorodeoxyglucose를 이용한 양전자방출 단층촬영의 임상적 연구)

  • Kim, Jae-Hwan;Kim, Kyung-Wook;Kim, Yong-Kack
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.5
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    • pp.462-469
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    • 2000
  • Positron Emission Tomography(PET) is a new diagnostic method that can create functional images of the distribution of positron emitting radionuclides, which when administered intravenously in the body, makes possible anatomical and functional analysis by quantity of biochemical and physiological process. After genetic and biochemical changes in initial stage, malignant tumor undergoes functional changes before undergoing anatomical changes. So, early diagnosis of malignant tumors by functional analysis with PET can be achieved, replacing traditional anatomical analysis, such as computed tomography(CT) and magnetic resonance image(MRI), etc. Similarly, PET can identify malignant tumor without confusion with scar and fibrosis in follow up check. In the Korea Cancer Center Hospital(KCCH) from October 1997 to September 1999, clinical study was performed in 79 cases that underwent 89 times PET evaluation with [18F]-Fluorodeoxyglucose for diagnosis of oral and maxillofacial tumors, and the data was analysed by Bayesian $2{\times}2$ Classification Table. The results were as follows : Evaluation for initial diagnosis with FDG-PET (P<0.005) 1. Agreement rate or accuracy rate is 88.9%. 2. Sensitivity is 95.2%, and specificity 66.7%. 3. Positive predictive rate is 90.9%, and negative predictive rate 80.0%. 4. In consideration of tumor stage, diagnostic rate in less than stage II was 90% and in greater than stage III 100%. 5. In consideration of tumor size, diagnostic rate in less than T2 was 92.3% and in greater than T3 100%. After primary treatment, evaluation for follow up check with FDG-PET (P < 0.001) 1. Agreement rate or accuracy rate is 85.4%. 2. Sensitivity is 87.5%, and specificity 82.4%. 3. Positive predictive rate is 87.5%, and negative predictive rate 82.4%. 4. In 24 recurred cases, 6 had distant metastasis, and 5 of them were diagnosed with FDG-PET, resulting in diagnostic rate of FDG-PET of 83.3%. From the above results, Positron Emission Tomography with [18F]- Fluorodeoxyglucose appears to be more sensitive and accurate for detecting the presence of oral and maxillofacial tumors, and has various clinical applications such as early diagnosis of tumor in initial and follow up check and detection of distant metastasis.

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Regional Distribution of Isotropy Magnetic Property of Dual-type Giant Magnetoresistance-Spin Valve Multilayer (이중구조 거대자기저항-스핀밸브 박막의 자기등방성 영역분포에 관한 연구)

  • Khajidmaa, Purevdorj;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.23 no.6
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    • pp.193-199
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    • 2013
  • The regional distribution of magnetic isotropy depending on the post annealing condition for the dual-type structure GMR-SV (giant magnetoresistance-spin valve) of NiFe/Cu/NiFe/IrMn/NiFe/Cu/NiFe multilayer was investigated. The rotation of in-plane ferromagnetic layer induced by controlment of the post annealing temperature inside of the vacuum chamber. The magnetoresistive curves of a dual-type IrMn based GMR-SV depending on the direction of the magnetization easy axis of the free layer and the pinned layer are measured by between $0^{\circ}$ and $360^{\circ}$ angles for the applied fields. The optimum annealing temperature having a steady and isotropy magnetic sensitivity of 1.52 %/Oe was $107^{\circ}C$ in the rotational section of $0{\sim}90^{\circ}$. By investigating the switching process of magnetization for an arbitrary measuring direction, the in-plane orthogonal magnetization for the dual-type GMR-SV multilayer can be used by a high sensitive biosensor for detection of magnetized micro-beads.

Wavelet-Based Digital Watermarking Using Level-Adaptive Thresholding (레벨 적응적 이치화를 이용한 웨이블릿 기반의 디지털 워터마킹)

  • Kim, Jong-Ryul;Mun, Young-Shik
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.37 no.1
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    • pp.1-10
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    • 2000
  • In this paper, a new digital watermarking algorithm using wavelet transform is proposed. Wavelet transform is widely used for image processing, because of its multiresolution characteristic which conforms to the principles of the human visual system(HVS). It is also very efficient for localizing images in the spatial and frequency domain. Since wavelet coefficients can be characterized by the gaussian distribution, the proposed algorithm uses a gaussian distributed random vector as the watermark in order to achieve invisibility and robustness. After the original image is transformed using DWT(Discrete Wavelet Transform), the coefficients of all subbands including LL subband are utilized to equally embed the watermark to the whole image. To select perceptually significant coefficients for each subband, we use level-adaptive thresholding. The watermark is embedded to the selected coeffocoents, using different scale factors according to the wavelet characteristics. In the process of watermark detection, the similarity between the original watermark and the extracted watermark is calculated by using vector projection method. We analyze the performance of the proposed algorithm, compared with other transform-domain watermarking methods. The experimental results tested on various images show that the proposed watermark is less visible to human eyes and more robust to image compressions, image processings, geometric transformations and various noises, than the existing methods.

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Evaluation of Automatic Image Segmentation for 3D Volume Measurement of Liver and Spleen Based on 3D Region-growing Algorithm using Animal Phantom (간과 비장의 체적을 구하기 위한 3차원 영역 확장 기반 자동 영상 분할 알고리즘의 동물팬텀을 이용한 성능검증)

  • Kim, Jin-Sung;Cho, June-Sik;Shin, Kyung-Sook;Kim, Jin-Hwan;Jeon, Ho-Sang;Cho, Gyu-Seong
    • Progress in Medical Physics
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    • v.19 no.3
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    • pp.178-185
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    • 2008
  • Living donor liver transplantation is increasingly performed as an alternative to cadaveric transplantation. Preoperative screening of the donor candidates is very important. The quality, size, and vascular and biliary anatomy of the liver are best assessed with magnetic resonance (MR) imaging or computed tomography (CT). In particular, the volume of the potential graft must be measured to ensure sufficient liver function after surgery. Preoperative liver segmentation has proved useful for measuring the graft volume before living donor liver transplantations in previous studies. In these studies, the liver segments were manually delineated on each image section. The delineated areas were multiplied by the section thickness to obtain volumes and summed to obtain the total volume of the liver segments. This process is tedious and time consuming. To compensate for this problem, automatic segmentation techniques have been proposed with multiplanar CT images. These methods involve the use of sequences of thresholding, morphologic operations (ie, mathematic operations, such as image dilation, erosion, opening, and closing, that are based on shape), and 3D region growing methods. These techniques are complex but require a few computation times. We made a phantom for volume measurement with pig and evaluated actual volume of spleen and liver of phantom. The results represent that our semiautomatic volume measurement algorithm shows a good accuracy and repeatability with actual volume of phantom and possibility for clinical use to assist physician as a measuring tool.

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A Study on Detecting Selfish Nodes in Wireless LAN using Tsallis-Entropy Analysis (뜨살리스-엔트로피 분석을 통한 무선 랜의 이기적인 노드 탐지 기법)

  • Ryu, Byoung-Hyun;Seok, Seung-Joon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.22 no.1
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    • pp.12-21
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    • 2012
  • IEEE 802.11 MAC protocol standard, DCF(CSMA/CA), is originally designed to ensure the fair channel access between mobile nodes sharing the local wireless channel. It has been, however, revealed that some misbehavior nodes transmit more data than other nodes through artificial means in hot spot area spreaded rapidly. The misbehavior nodes may modify the internal process of their MAC protocol or interrupt the MAC procedure of normal nodes to achieve more data transmission. This problem has been referred to as a selfish node problem and almost literatures has proposed methods of analyzing the MAC procedures of all mobile nodes to detect the selfish nodes. However, these kinds of protocol analysis methods is not effective at detecting all kinds of selfish nodes enough. This paper address this problem of detecting selfish node using Tsallis-Entropy which is a kind of statistical method. Tsallis-Entropy is a criteria which can show how much is the density or deviation of a probability distribution. The proposed algorithm which operates at a AP node of wireless LAN extracts the probability distribution of data interval time for each node, then compares the one with a threshold value to detect the selfish nodes. To evaluate the performance of proposed algorithm, simulation experiments are performed in various wireless LAN environments (congestion level, how selfish node behaviors, threshold level) using ns2. The simulation results show that the proposed algorithm achieves higher successful detection rate.

Hazard Analysis of Autonomous Vehicle due to V2I Malfunction (V2I 오작동에 의한 자율주행자동차의 위험성 분석)

  • Ahn, Dae-ryong;Shin, Seong-geun;Baek, Yun-soek;Lee, Hyuck-kee
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.18 no.6
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    • pp.251-261
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    • 2019
  • The importance of autonomous driving systems that utilize V2X services such as V2V(Vehicle to Vehicle) and V2I(Vehicle to Infrastructure) for safer and more comfortable driving is increasing with the recent development of autonomous vehicles. Partly autonomous vehicles based on environmental sensors have limitations for predicting and determining areas beyond the recognition distance of the mounted sensors and in response to atypical objects that are difficult to detect. Therefore, it is important to utilize the V2X service to improve the limit of sensor detection performance and to make driving safer and more comfortable. However, there may be an accident risk of autonomous vehicles due to incorrect information provided by V2X. Thus, the application of technology to prevent this needs to be considered. In this pater, we used the ISO-26262 Part3 Process and performed HARA (Hazard Analysis and Risk Assessment) to derive the risk sources of autonomous vehicles due to V2I malfunctions by using the communication between vehicles and infrastructure among V2X. We also developed ASIL ratings based on the simulations and real vehicle tests of the malfunctions of major cases of usnig V2I.