• Title/Summary/Keyword: Detailed Chemistry

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Mechanisms of Formation of Manganese Oxide Minerals in the Manganese Deposits of the Taebaeg Mt. Region, Korea (太白山地區 망간鑛床에 있어서 酸化망간鑛物의 生成機構)

  • Kim, Soo-Jin;Cho, Hyen-Goo;Choi, Hun-Soo
    • Journal of the Mineralogical Society of Korea
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    • v.5 no.1
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    • pp.1-5
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    • 1992
  • The manganese oxide ores in the Taebaeg Mt. region have been formed by supergene weathering of the primary hydrothermal or sedimentary manganese ores. The supergenesis is controlled by the physical chemistry of the descending groundwater in the supergene zone. It includes the fundamental geological processes, such as dissolution, oxidation, transportation, precipitation, and crystallization and recrystallization. However, the fundamental mechanisms for the formation of various manganese oxide minerals are 1) replacement, 2) precipitation from solution, and 3) solid state crystallization and recrystallization. Various textures and structures of ores have been formed by these processes. Detailed paragenetic sequence of manganese oxide minerals in each ore deposit is summerized.

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Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4-Air$ Diffusion Flame (화염편 모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석)

  • Kim Gunhong;Kim Hoojoong;Kim Yongmo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.1
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    • pp.68-75
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    • 2005
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

Effects of Addition of Hydrogen and Water Vapor on Flame Structure and NOx Emission In $CH_4$-Air Diffusion Flame (메탄-공기 확산화염에서 수소와 수증기 첨가가 화염구조와 NOx 배출에 미치는 효과)

  • Park, Jeong;Keel, Sang-In;Yun, Jin-Han
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.171-181
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    • 2007
  • Blending effects of hydrogen and water vapor on flame structure and NOx emission behavior are numerically studied with detailed chemistry in methane-air counterflow diffusion flames. The composition of fuel is systematically changed from pure methane and pure hydrogen to the blending fuels of methane-hydrogen-water vapor through the molar addition of $H_2O$. Flame structure is changed considerably for hydrogen-blending methane flames and hydrogen-blending methane flames diluted with water vapor in comparison to pure methane flame. These complicated changes of flame structures also affect NOx emission behavior considerably. The changes of thermal NO and Fenimore NO are analyzed for various combinations of the fuel composition. Importantly contributing reaction steps to thermal NO and Fenimore NO are addressed in pure methane, hydrogen-blending methane flames, and hydrogen-blending methane flames diluted with water vapor.

The High School Common Science Textbook and Classes by the Point of Science Teacher's View (교사들에 의한 공통과학 교과서 평가와 수업내용 현황)

  • Kim, Sung-Won;Jin, Yoo-Jung
    • Journal of The Korean Association For Science Education
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    • v.17 no.4
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    • pp.405-413
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    • 1997
  • High school common science is introduced by the sixth national curriculum. It consists of physics, chemistry, biology and earth science like the secondary school science. In this paper, textbooks are analyzed by the science teachers and the status of the present teaching and learning methods is reported. The detailed results are as follows; 1. Almost high school teachers choose textbook that included little the STS material. More than two teachers are teaching the high school common science and when they are chosen, they are independent with their major. 2. According to the national curriculum, they evaluated the textbooks as it is below the middle level. This evaluations are not dependent on teachers' comparement and textbook's class except the several matters based on STS (science-technology-society). 3. The teacher teaching the high school common science thought that teaching the textbook in school is worse than analysizing it. they must have emphasised on learning of inquire method than system of knowledge, introduction to material connected with real life and STS in the high school common science.

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High Performance Polyimides for Applications in Microelectronics and Flat Panel Displays

  • Ree Moonhor
    • Macromolecular Research
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    • v.14 no.1
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    • pp.1-33
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    • 2006
  • Polyimides (PIs) exhibit excellent thermal stability, mechanical, dielectric, and chemical resistance properties due to their heterocyclic imide rings and aromatic rings on the backbone. Due to these advantageous properties, PIs have found diverse applications in industry. Most PIs are insoluble because of the nature of the high chemical resistance. Thus, they are generally used as a soluble precursor polymer, which forms complexes with solvent molecules, and then finally converts to the corresponding polyimides via imidization reaction. This complexation with solvent has caused severe difficulty in the characterization of the precursor polymers. However, significant progress has recently been made on the detailed characterization of PI precursors and their imidization reaction. On the other hand, much research effort has been exerted to reduce the dielectric constant of PIs, as demanded in the microelectronics industry, through chemical modifications, as well as to develop high performance, light-emitting PIs and liquid crystal (LC) alignment layer PIs with both rubbing and rubbing-free processibility, which are desired in the flat-panel display industry. This article reviews this recent research progresses in characterizing PIs and their precursors and in developing low dielectric constant, light-emitting, and LC alignment layer PIs.

Effects of Shock Waves on the Mixing and the Recirculation Zone of Supersonic Diffusion Flames (초음속 확산화염 내의 혼합과 재순환 영역에 대한 충격파의 영향)

  • Kim, Ji-Ho;Huh, Hwan-Il;Choi, Jeong-Yeol;Yoon, Young-Bin;Jeung, In-Seuck
    • 한국연소학회:학술대회논문집
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    • 1998.10a
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    • pp.123-129
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    • 1998
  • A numerical study has been conducted to investigate the effect of shock waves on the mixing and the recirculation zone of a hydrogen jet diffusion flame in a supersonic combustor. The general trends are compared with the experimental results obtained from the supersonic combustor at the University of Michigan. For the numerical simulation of supersonic diffusion flames, multi-species Navier-Stokes equations and detailed chemistry reaction equations of $H_2$-Air are considered. The $K-{\omega}/k-{\varepsilon}$ blended two equation turbulent model is used. Roe's FDS method and MUSCL method are used for convection fluxes in governing equations. Numerical results show that when slender wedges are mounted at the combustor wall the mixing and the combustion are enhanced and the size of recirculation zone is increased . The flame shape of supersonic flames is different in the flame-tip; it is not closed but open. The flame shape is shown to be greatly affected by shock waves.

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Modeling for gaseous methane/liquid oxygen combustion processes at supercritical pressure (초임계 압력상태의 기체메탄/액체산소 연소과정 해석)

  • Kim, Tae-Hoon;Kim, Yong-Mo;Kim, Seong-Ku
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.85-88
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    • 2010
  • This study has been mainly motivated to numerically model the supercritical mixing and combustion processes encountered in the liquid propellant rocket engines. In the present approach, turbulence is represented by the extended $k-{\varepsilon}$ turbulence model. To account for the real fluid effects, the propellant mixture properties are calculated by using SRK (Souve-Redlich-Kwong) equation of state. In order to realistically represent the turbulence-chemistry interaction in the turbulent nonpremixed flames, the flamelet approach based on the real fluid flamelet library has been adopted. Based on numerical results, the detailed discussions are made for the real fluid effects and the precise structure of gaseous methane/liquid oxygen coaxial jet flame.

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A Study on Chemical Effecta Through Preferential Diffusion of H2 and H in CH4-H2 Counterflow Diffusion Flames (메탄-수소 대향류확산화염에서 H2와 H의 선호확산을 통한 화학적 효과에 관한 연구)

  • Park, Jeong;Kwon, Oh-Boong;Lee, Eui-Ju;Yun, Jin-Han;Keel, Sang-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.12
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    • pp.1009-1016
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    • 2007
  • Numerical study on preferential diffusion effects in flame structure in $CH_4-H_2$ diffusion flames is conducted with detailed chemistry. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. Discernible differences in flame structures are displayed with three species diffusion models. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. It is seen that the modifcation of flame structure is mainly due to the preferential diffusion of H2 and thereby the nature of chemical kinetics. It is also found that the behaviors of major species with the three species diffusion models are addressed to the nature of chemical kinetics, and this is evident by examining importantly contributing reaction steps to the production and destruction of those chemical species.

Distinction of Internal Tissue of Raw Ginseng Root Using a Computed Tomography Scanner

  • Jung, In-Chan;Jeong, In-Soo;Kim, Cheon-Suk
    • Journal of Ginseng Research
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    • v.36 no.4
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    • pp.469-476
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    • 2012
  • Raw ginseng root of Panax ginseng is graded according to its shape and the quality of its internal tissue. A variety of grades are sold with prices according to grade. If an inferior raw ginseng is purchased, the consumer experience an economic loss. This research was conducted in order to explore the possibility of developing a noninvasive method for investigating raw ginseng's internal tissue. It has been determined that computed tomography (CT) scanner images agreed with actual cross-sections of raw ginseng. CT images were obtained to assess the internal portions of raw ginseng, and CT scans of raw ginseng were thoroughly measured using the Hounsfield unit (HU) system, since it allows for a more detailed analysis compared to nuclear magnetic resonance imaging. HU is a measure of attenuation used for CT images, with each pixel being assigned a value using a scale on which air is defined as -1000, water as 0 and compact bone as +1000. It takes about one second to process are slice and produce an image of the raw ginseng by a one channel CT scanner. An image good enough to discriminate the internal tissues can be obtained in 1/24 seconds with a one-channel CT scanner. Using this method, images of raw ginseng can be obtained and the characteristics of the internal tissues can be observed in a short time.

Dynamic Characteristics of Transverse Fuel Injection and Combustion Flow-Field inside a Scramjet Engine Combustor

  • Park, J-Y;V. Yang;F. Ma
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.62-68
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    • 2004
  • A comprehensive numerical analysis has been carried out for both non-reacting and reacting flows in a scramjet engine combustor with and without a cavity. The theoretical formulation treats the complete conservation equations of chemically reacting flows with finite-rate chemistry of hydrogen-air. Turbulence closure is achieved by means of a k-$\omega$ two-equation model. The governing equations are discretized using a MUSCL-type TVD scheme, and temporally integrated by a second-order accurate implicit scheme. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel/air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the .underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flow-field. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.

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