• Journal of Energy Engineering
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• v.26 no.3
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• pp.97-104
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• 2017

In this study, waste tire rubbers were pyrolyzed in a lab-scale pyrolysis plant equipped with a fluidized bed reactor in a temperature ranges of $450-650^{\circ}C$. The main object of this work is to investigate the properties of pyrolysis oil with reaction temperatures and the behavior of sulfur in the products when waste polypropylene was added for co-pyrolysis. The maximum yield of oil was about 52wt.% at the reaction temperature of $456^{\circ}C$. From GC-MS analysis, the pyrolysis oils consisted mainly of limonene, toluene, xylene, styrene, trimethylbenzene, methylnaphthalenes and some heteroatom(sulfur and nitrogen)-containing compounds. The addition of waste polypropylene resulted in decrease in sulfur contents of the pyrolysis oils.

• Elastomers and Composites
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• v.53 no.3
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• pp.124-130
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• 2018

Recently, microwaves have been used for desulfurization because they can selectively dissociate C-S and S-S bonds present in vulcanized rubber. In this study, we investigated the changes in structural and physical properties of EPDM (Ethylene propylene diene monomer) rubber by irradiating it with microwaves for different durations. The surface chemical composition of the irradiated EPDM rubber was analyzed by FT-IR, XPS, and EDS analyses. It was confirmed by XPS that C-S and S-S S2p peak heights greatly decreased when microwave irradiation was performed for more than 5 min. In the EPDM sample irradiated with microwaves for 10 min, the number of S-O bonds significantly increased owing to oxidation. As the microwave irradiation time was increased, SEM images showed cracks and voids on the EPDM surface. The 20% decomposition temperature of the EPDM rubber sample was investigated by TGA, and it was found to be about $435.23^{\circ}C$ for the EPDM rubber irradiated for 10 min. The crosslinking density of the EPDM rubber was determined by measuring the degree of swelling, and the highest value was observed for the E5 sample irradiated for 5 min. The degree of swelling of the E10 sample irradiated for 10 min was lower than that of the E5 sample. These results indicate that when irradiated with microwaves for more than a certain time, desulfurization occurs and the side chain of the EPDM rubber dissociates and forms additional crosslinking bonds.

• Clean Technology
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• v.9 no.4
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• pp.189-196
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• 2003

ZnO-CuO mixed sorbents for desulfurization in hot gas cleaning process Were prepared and investigation on their characteristics was performed in this study. The rate of sulfidation increased as the amount of copper oxide in the composite sorbent was raised. TPO experiments were carried out to investigate the characteristics of the regeneration of the sorbents with severa1 different ratios of Zno to CuO. Copper sulfate was formed at temperatures above $400^{\circ}C$, while it was decomposed by pyrolysis above $700^{\circ}C$. $SO_2$ slippage due to $CuSO_4$ was observed in the sorbent regenerated at temperatures above $600^{\circ}C$. However, it was not observed when regenerated above $700^{\circ}C$. It was confirmed in the ZnO-CuO mixed sorbent system that CuO suppressed the vaporization of ZnO on the one hand and Zno minimized the $SO_2$ slippage due to CuO on the other hand.

• Korean Chemical Engineering Research
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• v.55 no.4
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• pp.567-573
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• 2017

In this work, tungsten oxide ($WO_x$) supported on SBA-15 (mesoporous silica) were prepared and applied for oxidative desulfurization of sulfur compounds in marine diesel containing about 230 ppmw of sulfur concentration. Prepared catalysts were examined by two steps; at first step, oxidation reaction carried out with hydrogen peroxide as oxidant and then the oxidized sulfur compounds were extracted by acetonitrile as solvent. Catalysts were characterized by using X-ray diffraction, X-ray fluorescence, X-ray photoelectron spectroscopy and $N_2$ adsorption-desorption isotherms. Tungsten oxide exists as monoclinic crystal system on SBA-15 and over about 10 wt% of the $WO_x$ loading took the form of multi-layers on SBA-15. The 13 wt% $WO_x$/SBA-15 catalyst exhibite highest activity, achieving about 76.3% sulfur removal in the reaction conditions, such as catalyst amount of 0.1 g, reaction temperature at $90^{\circ}C$, reaction time for 3 h and O/S molar ratio of 10. One time oxidation reaction is enough oxidize the sulfur compounds in marine diesel completely. The repetition experiment of extraction process indicated that sulfur removal could reach 94.4% after 5 times.

• Clean Technology
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• v.12 no.4
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• pp.232-237
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• 2006

The zinc-based desulfurization sorbents for a fluidized-bed system were prepared by a spray drying method and the effects of the pH and viscosity of the slurry on the attrition resistance of the prepared sorbents were investigated in this work. In order to improve the attrition resistance, alumina sol was used for an inorganic binder and pH of the slurry was changed for its better dispersion in slurry. The attrition resistance of the prepared sorbents decreased due to the phase transition of alumina sol to gel as the slurry pH increased to its basicity. The optimum pH condition for the good attrition resistance of the sorbents was about 6.0 in this study. It was confirmed that the attrition property of the sorbents were varied with the viscosity of the slurry. The attrition resistance of the sorbents prepared by the spray drying method increased as their bulk density increased, while it decreased as the surface area and porosity of the sorbents. The optimum viscosity for the high attrition was in the range 400-500 cP.

• Plant Journal
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• v.15 no.4
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• pp.30-35
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• 2019

To meet both increasing social demand for reduction of fine dust and the strengthened air pollutant emission standards, this paper indicated performance enhancement of FGD with structural constraints in 500 MW coal fired thermal power plant's. Through modifying internal facilities for flue gases to make swirl in the absorption tower, it made turbulence and increased the efficiency of material transfer, the reaction area and time with the limestone slurry. Therefore, it could reduce dust and enhance the performance of collecting the SO₂. As a result, desulfurization efficiency was improved from 91.61% to 98.43% and dust removal efficiency was improved from 77.4% to 87.08%. Emission density is 7.85 ppm of SO₂ and 4.67 mg/㎥ of dust. This is a level that satisfies emission limit of 25 ppm of SO₂ and 5 mg/㎥ of dust which are the air pollutant emission standards of 2023. The performance enhancement method of this study is expected to be effectively applied to other coal-fired power plants with similar constraints.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.331-343
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• 2005

Development of hydrogen station system is an important technology to commercialize fuel cells and fuel cell powered vehicles. Generally, hydrogen station consists of hydrogen production process including desulfurizer, reformer, water gas shift (WGS) reactor and pressure swing adsorption (PSA) apparatus, and post-treatment process including compressor, storage and distributer. In this review, we investigate the R&D trends and prospects of hydrogen station in domestic and foreign countries for opening the hydrogen economy society. Indeed, the reforming of fossil fuels for hydrogen production will be essential technology until the ultimate process that may be water hydrolysis using renewable energy source such as solar energy, wind force etc, will be commercialized in the future. Hence, we also review the research trends on unit technologies such as the desulfurization, reforming reaction of fossil fuels, water gas shift reaction and hydrogen separation for hydrogen station applications.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.116.2-116
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• 2001

Korea Institute of Energy Research(KIER) has designed the 3MW pilot scale wet FGD process based on the experimental results of the bench scale FGD system which can treat 150 m3/hr of flue gases. The effects of process chemistry, packing material, and operating variables including L/G ratio, pH, scrubber pressure drop were investigated. In cooperation with Kyunggi Chemicals, the 3MW pilot scale plant was established on the industrial site at Onsan, Korea. This system has been operating since October 1999. This paper introduces an outline of the design features of the pilot plant and discusses its operational results.

• Journal of Energy Engineering
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• v.9 no.1
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• pp.10-18
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• 2000

기존 화력발전소에 탈황설비가 추가되고, 이로 인하여 새로운 계통의 통풍저항을 상쇄시키기위하여 기존의 유인통풍기와 탈황설비 사이에 승압통풍기가 설치되고 있다 통풍저항의 증가와 새로운 통풍기의 추가는 기존 통풍특성의 변화를 나타낼것이고 , 빈번한 발저소 정지를 가져오는 심한 노내 압력변동을 보이게 될 것이다. 따라서 , 발전소를 안전하게 운전하기 위해서는 설계된 통풍계통을 기반으로 한 교정된 운전모드에 관한 지식이 요구된다. 본 논문에서는 MMS (Modular Modeling System) 소프트웨어를 사용하여 우회 댐퍼의 개방을 수반하는 유인 및 승압통풍기의 비상정지의 사례에 따른 화력발전소 노내 압력, 통풍기의 압력과 유량, 댐퍼의 개도등과 같은 해석결과를 제시하고 논의하고 있다.

• Corrosion Science and Technology
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• v.4 no.6
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• pp.242-249
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• 2005

A lot of parts in FGD (Flue Gas Desulfurization) systems of fossil-fuel power plants show the environments in which are highly changeable and extremely acidic corrosive medium according to time and locations, e.g. in duct works, coolers and re-heaters etc. These conditions are formed when system materials are immersed in fluid that flows on them or when exhausted gas is condensed into thin layered acidic medium to contact materials of the system walls and roofs. These environments make troublesome corrosion and air pollution problems that are occurred from the leakage of the condensed solution. To cathodically protect the metallic structures in extremely acidic fluid, the properties of the protective coatings on the metal surface were very important, and epoxy Novolac coating was applied in this work. On the base of acid immersion tests, hot sulfuric acid decreased the hardness of the coatings and reduced greatly the content of $Na_2O$, $Al_2O_3$, and $SiO_2$ among the main components of the coating. A special kind of CP(Cathodic Protection) system has been developed and tested in a real scale of the FGD facility. Applied coating for this CP system was peeled off and cracked in some parts of the facility. However, the exposed metal surface to extremely acidic fluid by the failure of the coatings was successfully protected by the new CP system.