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http://dx.doi.org/10.5855/ENERGY.2017.26.3.097

Energy Recovery via Pyrolysis of Waste Tire Rubber : Desulfurization Effect of Pyrolysis Oil by Adding Waste Polypropylene  

Jeong, Jaeyong (Thermochemical Energy System R&D Group, Korea Institute of Industrial Technology(KITECH))
Lee, Uendo (Thermochemical Energy System R&D Group, Korea Institute of Industrial Technology(KITECH))
Chang, Wonseok (Frontier Research & Training Institute, Korea District Heating Corporation(KDHC))
Oh, Munsei (Frontier Research & Training Institute, Korea District Heating Corporation(KDHC))
Jeong, Soohwa (Frontier Research & Training Institute, Korea District Heating Corporation(KDHC))
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Abstract
In this study, waste tire rubbers were pyrolyzed in a lab-scale pyrolysis plant equipped with a fluidized bed reactor in a temperature ranges of $450-650^{\circ}C$. The main object of this work is to investigate the properties of pyrolysis oil with reaction temperatures and the behavior of sulfur in the products when waste polypropylene was added for co-pyrolysis. The maximum yield of oil was about 52wt.% at the reaction temperature of $456^{\circ}C$. From GC-MS analysis, the pyrolysis oils consisted mainly of limonene, toluene, xylene, styrene, trimethylbenzene, methylnaphthalenes and some heteroatom(sulfur and nitrogen)-containing compounds. The addition of waste polypropylene resulted in decrease in sulfur contents of the pyrolysis oils.
Keywords
Waste tire rubber; Fast pyrolysis; Pyrolysis oil; Waste polypropylene; Desulfurization;
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