• Title/Summary/Keyword: Deposit Growth

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Room Temperature Preparation of Electrolytic Silicon Thin Film as an Anode in Rechargeable Lithium Battery (실리콘 상온 전해 도금 박막 제조 및 전기화학적 특성 평가)

  • Kim, Eun-Ji;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.8-15
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    • 2012
  • Silicon-based thin film was prepared at room temperature by an electrochemical deposition method and a feasibility study was conducted for its use as an anode material in a rechargeable lithium battery. The growth of the electrodeposits was mainly concentrated on the surface defects of the Cu substrate while that growth was trivial on the defect-free surface region. Intentional formation of random defects on the substrate by chemical etching led to uniform formation of deposits throughout the surface. The morphology of the electrodeposits reflected first the roughened surface of the substrate, but it became flattened as the deposition time increased, due primarily to the concentration of reduction current on the convex region of the deposits. The electrodeposits proved to be amorphous and to contain chlorine and carbon, together with silicon, indicating that the electrolyte is captured in the deposits during the fabrication process. The silicon in the deposits readily reacted with lithium, but thick deposits resulted in significant reaction overvoltage. The charge efficiency of oxidation (lithiation) to reduction (delithiation) was higher in the relatively thick deposit. This abnormal behavior needs to clarified in view of the thickness dependence of the internal residual stress and the relaxation tendency of the reaction-induced stress due to the porous structure of the deposits and the deposit components other than silicon.

Surface Microtopography of Pyrophyllite Crystals from Gussi Deposit, Korea (전남 구시광산에서 산출하는 엽납석 결정의 표면 미세형태)

  • Mayumi Jige;Ryuji Kitagawa;Hwang, Jin-Yeon
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.115-121
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    • 2004
  • The surface microtopography of pyrophyllite collected from the Gussi deposit, Korea was observed by mean of transmission electron microscopy (TEM) with the gold decoration technique. As results, closed step patterns with malformed circular islands were characteristically observed on the (001) surface of pyrophyllite, contrasting with spiral step patterns common in illite and kaolinite. Gussi pyrophyllite was likely crystallized from hydrothermal solution of higher temperature and/or higher supersaturation than those of other clay minerals. Comparing with micro-topographies of pyrophyllite from the Shokozan and the Uku deposits, southwest Japan, growth mechanism of Gussi pyrophyllite is almost equivalent to those from the Shokozan and the Uku deposits.

The Study of Sputtered SiGe Thin Film Growth for Photo-detector Application (광검출기 응용을 위하여 스퍼터된 미세결정 SiGe 박막성장 연구)

  • Kim, Do-Young;Kim, Sun-Jo;Kim, Hyung-Jun;Han, Sang-Youn;Song, Jun-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.6
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    • pp.439-444
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    • 2012
  • For the application of photo-detector as active layer, we have studied how to deposit SiGe thin film using an independent Si target and Ge target, respectively. Both targets were synthesized by purity of 99.999%. Plasma generators were generated by radio frequency (rf, 13.56 MHz) and direct current (dc) power. When Ge and Si targets were sputtered by dc and rf power, respectively, we could observe the growth of highly crystalline Ge thin film at the temperature of $400^{\circ}C$ from the result of raman spectroscopy and X-ray diffraction method. However, SiGe thin film did not deposit above method. Inversely, we changed target position like that Ge and Si targets were sputtered by rf and dc power, respectively. Although Ge crystalline growth without Si target sputtering deteriorated considerably, the growth of SiGe thin film was observed with increase of Si dc power. SiGe thin film was evaluated as microcrystalline phase which included (111) and (220) plane by X-ray diffraction method.

Case Study of N Deficiency Symptom of Strawberry in the Soil Applied with Sea Deposit Compost (바다부유물질로 만든 퇴비를 시용한 토양에서 발생한 딸기의 질소결핍증 해결 사례연구)

  • Kim, Yoo-Hak;Kim, Myung-Sook;Kang, Seong-Soo;Yoon, Sung-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1023-1026
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    • 2011
  • Nitrogen content in soil is a major factor for the crop growth. Ammonium nitrogen in soils is volatilized when soil pH is high. The growth and development problem of strawberry such as color of leaves turning into purple was found when soils were treated with the compost prepared from suspended solids of high pH from the sea. From in-situ analysis it was found that soil pH was 8.33 and nitrate, phosphorous, and potassium contents were relatively low. Nitric acid was added to adjust pH of irrigating water as 1.7, 1.9, and 2.3, then $KNO_3$ $0.25g\;L^{-1}$ and $KH_2PO_4$ $0.25g\;L^{-1}$ were added. It was resulted that soils with pH 1.7 produced the most developed strawberries. Strawberry was recovered by irrigation containing the same solution. From the results, the growth and development problem of the strawberry resulted from low nitrate absorption rate. It was concluded that the growth and development of strawberries were recovered by the reduced soil pH using nitric acid.

Synthesis of diamond thin films by hot-filament C.V.D

  • 최진일
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.2
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    • pp.227-232
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    • 1998
  • Diamond crystallization and discontinuous deposit phenomena depend on the process of hydrocarbon deposition, nucleation and growth. Then, it is investigated the concentration of methane, flow rate, structure and the growth process of $CH_4-H_2$ system in hot filament assisted C.V.D. There is a limited value of temperature, pressure, flow rate and the mole fraction of methane-hydrogen gas. Diamond nucleation occurs on substrate selectively and surface diffusion of species on the substrate plays an important role in the early stages of nucleation and growth.

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Ecological Characteristics of Vibrio vulnificus in Estuary of Kum River (금강 하구에 있어서 Vibrio vulnificus의 생태학적 특성)

  • 김영만;양송주;김형선;권지영;장수현
    • Journal of Food Hygiene and Safety
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    • v.10 no.2
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    • pp.53-59
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    • 1995
  • Vibrio unlnificus, a normal inhabitant in estuaries, is of great concern because it is a potent human pathogen causing septicemia, wound infection and gastrointestinal disease in Kum river, sampling was undertaken in five station from March, 26, 1993 to February, 22, 1994. Samples of 54 and 49 were collected from seawater and bottom deposit. The total detection rate of V. unlnificus was 11.7%. The detection rates of V. unlnificus in the seawater and the bottom deposit were 9.3% and 14.3% respectively. V. unlnificus was mainly detected in estuary water when temperature was above 23$^{\circ}C$ and salinity was below 15%. We suppose that water when temperature, salinity, pH and COD affect growth of V. unlnificus.

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Development of an Expert Technique and Program to Predict the Pollution of Outdoor Insulators (옥외 절연물의 오손도 예측 기법 및 프로그램 개발)

  • Kim, Jae-Hoon;Kim, Ju-Han;Han, Sang-Ok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.28-34
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    • 2007
  • Recently, with the rapid growth of industry, environmental condition became worse. In addition to outdoor insulators in seashore are polluted due to salty wind. Also this pollution causes the flashover and failure of electric equipments. Especially the salt contaminant is one of the most representative pollutants, and known as the main source of the accident by contamination. As well known, the pollution has a close relation with meteorological factors such as wind velocity, wind direction, temperature, relative humidity, precipitation and so on. In this paper we have statistically analyzed the correlation between the pollution and the meteorological factors. The multiple regression analysis was used for the statistical analysis; daily measured equivalent salt deposit density(dependent variable) and the weather condition data(independent variable) were used. Also we have developed an expert program to predict the pollution deposit. A new prediction system using this program called SPPP(salt pollution prediction program) has been used to model accurately the relationship between ESDD with the meteorological factors.

The Short-run and Long-run Dynamics Between Liquidity and Real Output Growth: An Empirical Study in Indonesia

  • JUMONO, Sapto;SOFYAN, Joel Faruk;SUGIYANTO, Sugiyanto;MALA, Chajar Matari Fath
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.595-605
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    • 2021
  • The objectives of this research are to see if the phenomena of "demand following" and "supply leading" exist in the business cycle, as well as to look at how liquidity and output react to changes in credit risk, investment-saving gap, inflation, exchange rate, and growth rate of real national output. Employing quarterly data of Maluku and North Maluku (2008-2019), this study utilizes VAR/VECM for inferential analysis. This research found three important findings. First, liquidity and output growth influenced each other in the long run. Second, the determinants of output growth for Maluku are liquidity, investment-saving gap, and inflation, while the determinants of liquidity are output-growth, the gap of investment-saving, and inflation. Third, the determinants of output growth for North Maluku are liquidity, credit risk, investment-saving gap, inflation, exchange rate, and the national output-growth, while the determinants of liquidity are output-growth, credit risk, investment-saving gap, inflation, exchange rate, and national output-growth. The findings of this study supported the hypothesis of demand following and supply leading theory in the Maluku and North Maluku business cycles. This study concludes that economic development would improve if supported by liquidity adequacy through increased deposit growth.

Effects of Gas Flow Variables on the Crystal Growth of Diamond in Hot Filament-Assisted CVD (고온 필라멘트 다이아몬드 CVD에서 기체유동변수가 결정성장에 미치는 영향)

  • 서문규;이지화
    • Journal of the Korean Ceramic Society
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    • v.31 no.1
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    • pp.88-96
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    • 1994
  • Hot filament-assisted CVD was carried out to deposit diamond films on Si(100) substrate at 90$0^{\circ}C$ using a 1% CH4-H2 mixture gas. Deposition was made at various conditions of mass flow rate of the feed gas (30~1000 sccm), pressure (2.5~300 Torr), and filament-substrate distance (4~15 mm), and the deposited films were characterized by SEM, XRD, and Raman spectroscopy. As the flow rate increases, the growth rate also increased but the crystallinity of the film was degraded. A longer filament-substrate distance simply caused both the growth rate and the crystallinity to become poorer. On the other hand, the pressure variation resulted in a maximum growth rate of 2.6 ${\mu}{\textrm}{m}$/hr at 10 Torr and the best film quality around 50 Torr, exhibiting an optimum condition. The observed trends were interpreted in terms of the flow velocity-dependent pyrolysis reaction efficiency and mass transport through the boundary layer.

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Effect of H2 on The Diamond Film Growth Mechanism by HFCVD Method Using CH3OH/H2O (HFCVD법에 의한 H2 다이아몬드 박막 제조에 수소가 미치는 영향)

  • Lee Kwon-Jai;Shin Jae-Soo;Kwon Ki-Hong;Lee Min-Soo;Koh Jae-Gui
    • Korean Journal of Materials Research
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    • v.14 no.12
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    • pp.835-839
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    • 2004
  • The diamond thin films was deposited on Si(100) substrate by Hot Filament Chemical Vapor Deposition (HFCVD) method using supplied the $CH_{3}OH/H_{2}O$ mixtured gas with excess H_{2} gas. The role of hydrogen ion as the growth mechanism of the diamond deposit was examined and compared the $CH_{3}OH/H_{2}O$ with the $CH_4/H_2$. Pressures in the range of $1.1\sim290{\times}10^2$ Pa were applied and using $3.4\sim4.4$ kw power. It was investigated by Scanning Electron Microscopy(SEM) and Raman spectroscopy The H ion was etching the graphite and restrained from $sp^3\;to\;sp^2$. But excess $H_2$ gas was not helped diamond deposit using $CH_{3}OH/H_{2}O$ mixtured gas. It was shown that the role of hydrogen ion of deposited diamond films using $CH_{3}OH/H_{2}O$ was different from $CH_4/H_2$.