• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.153-153
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• 2010

p-i-n 형 비정질 실리콘 박막 태양전지에서 p층은 창물질(window material)로서 전기 전도도가 크고, 빛 흡수가 적어야한다. p층의 두께가 얇으면 p층 전체가 depletion layer가 되고 충분한 diffusion potential을 얻을 수 없어 open-circuit voltage ($V_{oc}$)가 작아진다. 반대로 p층 두께가 두꺼워지면 빛 흡수가 증가하고, 표면 재결합이 문제가 되어 변환효율이 감소한다. 밴드갭이 큰 물질로 창층을 제작하게 되면 보다 짧은 파장의 입사광이 직접 i층을 비추므로 Short-circuit current ($I_{sc}$) 와 fill factor를 증가시킬 수 있다. 하여 본 연구에서는 기존의 창층으로 사용되는 Boron을 doping한 p-type a-Si:H 대신에 $N_2O$를 첨가한 p-type a-$SiO_x$:H의 $N_2O$ flow rate에 따른 밴드갭의 변화에 관한 연구를 수행하였다. p-type a-$SiO_x$:H Layer는 $SiH_4$, $H_2$, $N_2O$, $B_2H_6$ 가스를 혼합하여 증착하게 되는데 $SiH_4$, 가스와 $H_2$ 가스의 혼합비는 1:20, $B_2H_6$ 농도는 0.5%로 고정 하였으며 $N_2O$의 flow rate을 가변하며 증착하였다. $N_2O$의 가변조건은 5에서 50sccm으로 가변하여 증착하며 일반적으로 사용되는 RF-PECVD (13.56MHz)를 이용하였고 증착 온도는 175도, 전극간의 거리는 40mm, 파워와 압력은 30W, 700mTorr로 고정하여 진행하였다. 전기적 특성을 알아보기 위해 eagle 2000 Glass를 사용하였고 구조적 특성은 p-type wafer를 사용하여 각각 대략 200nm의 두께로 증착하였다. 증착 두께는 Ellipsometry를 이용하였으며 전기 전도도는 Agilent사의 4156c를 구조적특성은 FT-IR을 사용하여 측정하였다. Conductivity(${\sigma}_d$)는 $N_2O$가 증가함에 따라 $8.73\;{\times}\;10^{-6}$에서 $5.06\;{\times}\;10^{-7}$으로 감소하였고 optical bandgap ($E_{opt}$)은 1.71eV에서 2.0eV로 증가함을 알 수 있었다. 또한 reflective index(n)의 경우는 4.32에서 3.52로 감소함을 나타내었다. 기존의 p-type a-Si:H에 비해 상당한 $E_{opt}$을 가지므로 빛 흡수에 의한 손실을 줄임으로서 $V_oc$를 향상 시킬 수 있으며 동시에 짧은 파장에서의 입사광이 직접 i층을 비추므로 $I_{sc}$와 FF를 향상 시킬 수 있으리라 예상된다. 다소 낮은 전도도만 개선한다면 고효율의 박막 태양전지를 제작 할 수 있을 것으로 기대된다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.298-298
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• 2013

Finding renewable and clean energy resources is essential research to solve global warming and depletion of fossil fuels in modern society. Recently, complex harvesting of energy from multiple sources is available in our living environments using a single device has become highly desirable, representing a new trend in energy technologies. We report that when simultaneously driving the fusion and composite cells of two or more types, it is possible to make an affect the other cells to obtain a greater synergistic effect. To understand the coupling effect of photovoltaic and piezoelectric device, we fabricate the serially integrated hybrid cell (s-HC) based on organic solar cell (OSC) and piezoelectric nanogenerator (PNG). The size of increased voltage peaks when OSC and PNG are working on is larger than the case when only PNG is working. This voltage difference is the Voc change of OSC, not the voltage change of PNG and current density difference between these two cases is manifested more clearly. When the OSC and PNG are working in s-HC at the same time, piezoelectric potential (VPNG) is generated in ZnO and theoretical total voltage is sum of voltage of an OSC (VOSC) and VPNG. However, electrons from OSC are influenced by piezoelectric potential in ZnO and current loss of OSC in whole circuit decreases. As a result, VOSC increases temporarily. Current shows the similar behavior. PNG acts a resistance in the whole circuit and current loss occurs when the electrons from OSC pass through the PNG. But piezoelectric potential recover current loss and decrease the resistance of PNG. Our PNG can maintain piezoelectric potential when the strain is held owing to the LDH layer while general PNG cannot maintain piezoelectric potential. During the section that strain is held, voltage enhancement effect is maintained and same effect appeared even turn off the light. Actually at this time, electrons in ZnO nanosheets move to LDH and trapped by the positive charges in this layer. After this strain is held, piezoelectric potential of ZnO nanosheets is disappeared but potential difference which is developed by negative charge dominant LDH layer is remained. This potential acts similar role like piezoelectric potential in ZnO. Electrons from the OSC also are influenced by this potential and the more current flows.

• Corrosion Science and Technology
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• v.12 no.2
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• pp.102-112
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• 2013

A very high-temperature gas reactor (VHTR) is one of the next generation nuclear reactors owing to its safety, high energy efficiency, and proliferation-resistance. Heat is transferred from the primary helium loop to the secondary helium loop through an intermediate heat exchanger (IHX). Under VHTR environment Alloy 617 is being considered a candidate Ni-based superalloy for the IHX of a VHTR, owing to its good creep resistance, phase stability and corrosion resistance at high temperature. In this study, high-temperature corrosion tests were carried out at 850 - $950^{\circ}C$ in air and impure helium environments. Alloy 617 specimens showed a parabolic oxidation behavior for all temperatures and environments. The activation energy for oxidation was 154 kJ/mol in helium environment, and 261 kJ/mol in an air environment. The scanning electron microscope (SEM) and energy-dispersive x-ray spectroscopy (EDS) results revealed that there were a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbide after corrosion test. The thickness and depths of degraded layers also showed a parabolic relationship with the time. A corrosion rate of $950^{\circ}C$ in impure helium was higher than that in an air environment, caused by difference in the outer oxide morphology.

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.1
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• pp.115-123
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• 2005

In this study, life cycle assessment(LCA) technique was employed to evaluate the environmental impact of material recycling of polyethylene terephthalate(PET) bottle. Life cycle inventory was established based on the data collected from recycling companies in Korea. Simapro 5.0 LCA software and Eco-indicator 95 index were used for the analysis. The biggest impact by the material recycling of PET bottle on the environmental category was the global warming. It is because melting and production of the recycled PET product consume a significant amount of electricity and energy. In the environmental pollution discharge, $CO_2$ emission was the highest, followed by NOx. This is probably due to the use of diesel and gasoline in the consumption of electricity and transportation. All the environmental impact showed (-) value except the ozone layer depletion, which means that the material recycling of PET bottle is environmentally fair. The use of recycled PET product greatly reduced the environmental impact.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.755-767
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• 2014

Chlorine is one of the most produced and most used non-flammable chemical substances in the world even though its toxicity and high reactivity cause the ozone layer depletion. However, in modern life, it is impossible to live a good life without using Chlorine and its derivatives since they are being used as an typical ingredient in more than 40 percent of the manufactured goods including medicines, detergents, deodorant, fungicides, herbicides, insecticides, and plastic, etc. Even if Chlorine has been handled and distributed in various business (small and medium-sized businesses, water purification plants, distribution company, etc.), there have been few researches about its possible health hazard and transportation risks. Accordingly, the purpose of this paper is to make a detailed assessment of Chlorine-related risks and to model an index of chemicals transportation risks that is adequate for domestic circumstances. The assessment of possible health hazard and transportation risks was made on 13 kinds of hazardous chemicals, including liquid chlorine. This research may be contributed to standardizing the risk assessment of Chlorine and other hazardous chemicals by using an index of transportation risks.

• International Journal of Air-Conditioning and Refrigeration
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• v.14 no.1
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• pp.7-13
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• 2006

Because the usage of CFC and HCFC based refrigerants are restricted due to the depletion of ozone layer, the $NH_3$ gas, in the experiment is evaluated to the performance characteristics for the superheat control to improve the energy efficiency. The experiment is carried out about the condensing pressure of refrigeration system from 1,500 kPa to 1,600 kPa through the degree of superheat from 0 to $10^{\circ}C$ at each condensing pressure. As a result, in the case of shell and tube type of heat exchanger, the COP is more efficient than other cases at the degree of superheat $1^{\circ}C$ at each condensing pressure. In the case of shell and disk type of heat exchanger, the COP is the most efficient at the degree of superheat 0.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.14 no.2
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• pp.69-74
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• 2005

Since the use of CFC and HCFC refrigerants is to be restricted due to the depletion of ozone layer, this experiment applies the $NH_{3}$ gas to study the performance characteristics from the superheat control for improving the energy efficiency. The experiments are carried out for the condensing pressure of refrigeration system from 1500kPa to 1600kPa by 50kPa and for degree of superheat from $0^{circ}$ to $1^{circ}$ by $10^{circ}$ at each condensing pressure. As a result of experiment, 1) As degree of superheat increased, evaporating pressure of the compressor decreased so equilibrium temperature decreased. And specific volume of refrigerant vapors increased so refrigerant mass flow and heat load of the evaporator decreased. 2) An influence of change of condensing pressure on heat load of the evaporator was insignificant. 3) With the identical degree of superheat, change of compressed temperature was insignificant according to each condensing pressure, so there was little change in enthalpy.4) when the degree of superheat is $0^{circ}$C at each condensing pressure, the refrigeration system has the hi띤est performance.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.31 no.2
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• pp.143-150
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• 2013

Recently, environmental issues such as climate warming, ozone layer depletion, reduction of tropical forests and desertification are emerging as global environmental problems beyond national problems. And international attention and effort have been carried out in many ways to solve these problems. In this study, the growth of green was calculated quantitatively using the technique of remote sensing and temperature change was figured out through temperature extraction in the city. The land-cover changes and thermal changes for research areas were analyzed using Landsat TM images on May 2002 and May 2009. Surface temperature distribution was calculated using spectral degree of brightness of Band 6 that was Landsat TM thermal infrared sensor to extract the ground surface temperature in the city. As a result of research, the area of urban green belt was increased by $2.87km^2$ and the ground surface temperature decreased by $0.6^{\circ}C{\sim}0.8^{\circ}C$ before and after tree planting projects. Henceforth, if the additional study about temperature of downtown is performed based on remote sensing and measurement data, it will contribute to solve the problems about the urban environment.

• Journal of the Korean Society of Safety
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• v.29 no.6
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• pp.9-14
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• 2014

Recently many efforts and researches have been done to cope with industrial facilities that require a low energy machines due to the gradual depletion of the natural resources. The fiber-reinforced composite materials in general have good properties and have the proper mechanical properties according to the change of the ply sequences and fiber distribution types. However, in the fiber-reinforced composite material, there are several problems, including fiber breaking, peeling, layer lamination, fiber cracking that can not be seen from the metallic material. Particularly, the fracture and delamination are likely to be affected by the thickness of the stacking laminates when the bi-material laminated structure is subjected to a load of the mixed mode. In this study, we investigated the effect of the thickness ratio of the difference in the CFRP/GFRP bi-material laminate composites by measuring the cracking behavior and the AE characteristics in a mixed mode loading, which may be generated in the actual structure. The results show that the thickness of the CFRP becomes more thick, the mode I energy release rate becomes a larger, and also the influence of mode I is greater than that of mode II. In addition, AE amplitude which shows the level of the damage in the structure was obtained the more damage in the CFRP with the thin thickness.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.14 no.7
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• pp.1647-1652
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• 2010

A CdS film has been used as a window layer in CdTe and Cu(In,Ga)$Se_2$ thin films solar cell. Partial substitution of Zn for Cd increases the photocurrent and the open-circuit voltage by providing a match in the electron affinities of the two materials and the higher band gap. In this paper, CdZnS/CdTe and CdS/CdTe heterojunctions were fabricated and the electrical characteristics were investigated. Current-voltage-temperature measurements showed that the current transport for CdS/CdTe heterojunction was controlled by both tunneling and interface recombination. However, CdZnS/CdTe heterojunction displayed different current transport mechanism with the operating temperature. For above room temperature, the current transport of device was generation/recombination in the depletion region and was the leakage current and/or tunneling in the range below room temperature.