• Title/Summary/Keyword: Density

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Synthesis and Characterization of La0.75Sr0.25FeO3 Used as Cathode Materials for Solid Oxide Fuel Cell by GNP Method (GNP법을 이용한 고체산화물 연료전지의 공기극용 La0.75Sr0.25FeO3의 제조 및 특성)

  • Park, Ju-Hyun;Son, Hui-Jeong;Lim, Tak-Hyoung;Lee, Seung-Bok;Yun, Ki-Seok;Yoon, Soon-Gil;Shin, Dong-Ryul;Song, Rak-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.7-13
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    • 2007
  • We synthesized and investigated $La_{0.75}Sr_{0.25}FeO_3$ by Glycine Nitrate Process(GNP) method used as cathode materials for SOFC(solid oxide fuel cell). Optimized amount of glycine is 3.17 mol. ICP elemental composition analysis indicated that the stoichiometry of the synthesized powders have nearly nominal values. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The sample powders were isostatically pressed to form a pellet. The green body was sintered at $1200^{\circ}C$ and the relative density of the sintered specimens were measured by Archimedes mettled. We measured electrochemical performance of LSF by AC impedance spectroscopy. Resistance of LSF shows lower value than that of LSM throughout all temperature region. The anode-supported solid oxide fuel cell showed a performance of $342mW/cm^2(0.7V,\;488mA/cm^2)$ at $750^{\circ}C$. The electrochemical characteristics of the single cell were examined by at impedance method.

Influence of Precursor on the Electrochemical Properties of Li(Ni0.5Co0.2Mn0.3)O2 Cathode for the Lithium Secondary Battery (전구체의 물성에 따른 리튬 2차전지용 Li(Ni0.5Co0.2Mn0.3)O2의 전기화학적 특성 변화)

  • Kang, Donghyun;Arailym, Nurpeissova;Chae, Jeong Eun;Kim, Sung-Soo
    • Journal of the Korean Electrochemical Society
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    • v.16 no.4
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    • pp.191-197
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    • 2013
  • The one of the cathode material, $Li(Ni_{0.5}Co_{0.2}Mn_{0.3})O_2$, was synthesized by the precursor, $Ni_{0.5}Co_{0.2}Mn_{0.3}(OH)_2$, from the co-precipitation method and the morphologies of the primary particle of precursors were flake and needle-shape by controlling the precipitation parameters. Identical powder properties, such as particle size, tap density, chemical composition, were obtained by same process of lithiation and heat-treatment. The relation between electrochemical performances of $Li(Ni_{0.5}Co_{0.2}Mn_{0.3})O_2$ and the primary particle morphology of precursors was analyzed by SEM, XRD and EELS. In the $Li(Ni_{0.5}Co_{0.2}Mn_{0.3})O_2$ cathode from the needle-shape precursor, the primary particle size was smaller than that from flake-shape precursor and high Li concentration at grain edge comparing grain center. The cycle and rate performances of the cathode from needle-shape precursor shows superior to those from flake-shape precursor, which might be attributed to low charge-transfer resistance by impedance measurement.

Analysis on Adhesion Properties of Composite Electrodes for Lithium Secondary Batteries using SAICAS (SAICAS를 이용한 리튬이차전지용 복합전극 결착특성 분석)

  • Byun, Seoungwoo;Roh, Youngjoon;Jin, Dahee;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.21 no.2
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    • pp.28-38
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    • 2018
  • Although the adhesion properties of composite electrodes are important for securing long-term reliability and realizing high energy density of lithium secondary batteries, related research has not been carried out extensively due to the limitation of measurement technology. However, surface and interfacial cutting analysis system(SAICAS), which can measure the adhesion properties while cutting and peeling a coating layer of $1{\sim}1000{\mu}m$ thickness, has been developed and applied for analyzing the adhesion properties of composite electrodes for lithium secondary batteries. Thus, this review presents not only the principle and measurement method of SAICAS but also comparison results between SAICAS and conventional peel test. In addition, application examples of SAICAS are introduced in the study of electrode design optimization, new binder derivation study, and binder distribution in composite electrode. This suggests that SAICAS is an analytical method that can be easily applied to investigate the adhesion properties of composite electrodes for lithium secondary batteries.

An Advanced MCL Method for a Sharing Analysis of Mobile Communication Systems beyond 3G (차세대 이동통신 시스템의 주파수 공유분석을 위한 개선된 MCL 방법)

  • Chung Woo-Ghee;Yoon Hyun-Goo;Jo Han-Shin;Lim Jae-Woo;Yook Jong-Gwan;Park Han-Kyu
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.3 s.106
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    • pp.307-316
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    • 2006
  • In this paper the analytical method, namely advanced minimum coupling loss(A-MCL), was proposed in order to analyze the coexistence of OFDM-based systems beyond 3G(B3G) with point-to point(PP) fixed service(FS) microwave systems. Our proposed method is based on a power spectral density(PSD) analysis. So it can be easily applicable to analyze the coexistence of OFDM-based systems B3G using flexible spectrum usage(FSU) with other systems, where the conventional MCL method cannot allocate transmit power partially to some subcarriers which overlap the band of a victim system. By applying the conventional MCL method and the A-MCL method, interfering power levels at the receiver of a interfered system are respectively calculated. A-MCL can calculate interference power more accurately than MCL by the maximum value of 4.5 dB. Therefore it can be concluded that our prosed method, namely A-MCL, is applicable to a sharing analysis of OFDM-based systems B3G.

Analysis of Electromagnetic Scattering by a Resistive Strip Grating with Tapered Resistivity on Dielectric Multilayers (다층 유전체위의 변하는 저항율을 가진 저항띠 격자구조에 의한 전자파 산란 해석)

  • Uei-Joong Yoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.8 no.5
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    • pp.495-503
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    • 1997
  • In this paper, the E-polarized electromagnetic scattering problems by a resistive strip grating with tapered resistivity on 3 dielectric layers are analyzed to find out the effects for the tapered resistivity of resistive strip and the relative permittivity and thickness of 3 die- lectric layers by applying the Fourier-Galerkin moment methods. The induced surface current density is expanded in a series of Jacobi-polynomial ${P^{(\chi,\beta)}}_p$(.) of the order $\alpha$= 0 and $\beta$=1 as a kind of orthogonal polyomians, and the tapered resistivity assumes to vary linearly from 0 at one edge to finite resistivity at the other edge. The normalized reflected and transmitted powers are obtained by varying the tapered resistivity and the relative permittivity and thickness of dielectric layers. The sharp variation points are observed when the higher order modes are transferred between propagating and evanescent modes, and in general the local minimum positions occur at less grating period for the more relative permittivity of dielectric layers. It should be noted that the patterns of the normalized reflected and transmitted powers for the tapered resistivity are very much different from those of the uniform resistivity and perfectly conducting cases. The proposed method of this paper cna solve the scattering problems for the tapered resistive, uniform resistive, and PEC strip cases.

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0.25 μm AlGaN/GaN HEMT Devices and 9 GHz Power Amplifier (0.25 μm AlGaN/GaN HEMT 소자 및 9 GHz 대역 전력증폭기)

  • Kang, Dong-Min;Min, Byoung-Gue;Lee, Jong-Min;Yoon, Hyung-Sup;Kim, Sung-Il;Ahn, Ho-Kyun;Kim, Dong-Young;Kim, Hae-Cheon;Lim, Jong-Won;Nam, Eun-Soo
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.1
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    • pp.76-79
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    • 2016
  • This paper describes the successful development and the performance of X-band 50 W pulsed power amplifier using a 50 W GaN-on-SiC high electron mobility transistor. The GaN HEMT with a gate length of $0.25{\mu}m$ and a total gate width of 12 mm were fabricated. The X-band pulsed power amplifier exhibited an output power of 50 W with a power gain of 6 dB in a frequency range of 9.2~9.5 GHz. It also shows a maximum output power density of 4.16 W/mm. This 50 W GaN HEMT and X-band 50 W pulsed power amplifier are suitable for the radar systems and related applications in X-band.

A Study on DM-RS Structure for LTE V2V Communications (LTE 차량 간 통신을 위한 DM-RS 구조 연구)

  • Baek, Jung-Yeon;Park, Ji-Hye;Hong, Een-Kee
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.42 no.1
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    • pp.279-285
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    • 2017
  • The study on 'support for V2V(Vehicle to Vehicle) services based on LTE sidelink' has been carried out in 3GPP RAN working group. The conventional LTE sidelink technology is not adequate for high speed V2V communications because the conventional DM-RS(Demodulation Reference signal) structure is developed for pedestrian environment. While the typical speed of pedestrian environment is 3km/h, that of V2V communications is 120 km/h and the information on channel estimation is not sufficient with legacy DM-RS structure. In this paper, improved DM-RS structures for V2V communications that have rapid channel variation are introduced and the performance of channel estimation accuracy is analyzed. Simulation results show that the performance improvement of channel estimation can be achieved based on extended sub-carrier spacing structure resulted from reduced inter-carrier interference. However, the extended sub-carrier spacing requires the longer cyclic prefix and higher overhead. As a results of considerations on DM-RS modification, the sub-carrier spacing is maintained and the high density of DM-RS is applied for V2V communications.

Effect of diets with different energy and lipase levels on performance, digestibility and carcass trait in broilers

  • Hu, Y.D.;Lan, D.;Zhu, Y.;Pang, H.Z.;Mu, X.P.;Hu, X.F.
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.8
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    • pp.1275-1284
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    • 2018
  • Objective: A 28-d trial was conducted to evaluate the effect of diets with different energy and lipase levels on performance, nutrient digestibility, serum profiles, gut health, and carcass quality in broilers. Methods: A total of 720 one-day-old male Ross 308 broilers ($45.4{\pm}0.5g$) were randomly assigned to one of the following four treatments: i) RET, reduced energy treatment (metabolizable energy = 2,950 and 3,100 kcal/kg for starter and finisher diet), ii) BDT, basal diet treatment (metabolizable energy = 3,050 and 3,200 kcal/kg for starter and finisher diet, iii) RET015, RET+0.15 g/kg lipase, and iv) RET03, RET+0.3 g/kg lipase. There were 10 replications (cages) per treatment with 18 birds per cage. Results: During d 1 to 14, broilers fed BDT, RET015, and RET03 diets had higher (p<0.05) body weight gain than those fed RET diet. During d 1 to 14, 15 to 28 and the overall experiment, feed conversion ratio in RET03 treatment was lower (p<0.05) compared with RET treatment. On d 14, the apparent total tract digestibility (ATTD) of dry matter (DM), ether extract (EE), and gross energy in RET03 treatment was higher (p<0.05) than those in RET treatment, while the ATTD of N was increased (p<0.05) by RET03 treatment. On d 28, broilers fed RET03 diet had higher (p<0.05) ATTD of DM than those fed RET and RET015 diets, while the ATTD of EE in BDT and RET03 treatments was increased (p<0.05) compared with RET and RET015 treatments. Broilers fed RET03 diet had higher villus height (VH) and VH:crypt depth (CD) ratio than those fed RET and BDT diets. The activity of pancreatic lipase in BDT and RET03 treatments was higher (p<0.05) than that in RET treatment. Conclusion: Taken together, lipase supplementation (3,000 U/kg feed) increased growth performance, nutrient digestibility, VH, VH:CD ratio and lipase activity, but decreased triglyceride, low-density lipoprotein cholesterol and the abdominal fat percentage in broilers fed reduced energy diet.

Comparison of Behaviour of Straight and Curved Mechanically Stabilized Earth Walls from Numerical Analysis Results (수치해석을 통한 보강토옹벽 직선부와 곡선부의 거동 특성)

  • Jung, Hyuk-Sang
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.83-92
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    • 2017
  • This paper deals with numerical analysis of behavior of curved mechanically stabilized earth(MSE) walls with geosynthetics reinforcement. Unlike typical concrete retaining walls, MSE wall enables securing stability of higher walls without being constrained by backfill height and is currently and widely used to create spaces for industrial and residential complexes. The design of MSE walls is carried out by checking external stability, similarly to the external checks of conventional retaining wall. In addition, internal stability check is mandatory. Typical stability check based on numerical analysis is done assuming 2-dimensional condition (plane strain condition). However, according to the former studies of 3-dimensional MSE wall, the most weakest part of a curved geosynthetic MSE wall is reported as the convex location, which is also identified from the studies of the laboratory model tests and field monitoring. In order to understand the behaviour of the convex location of the MSE wall, 2-dimensional analysis clearly reveals its limitation. Furthermore, laboratory model tests and field monitoring also have restriction in recognizing their behaviour and failure mechanism. In this study, 3-dimensional numerical analysis was performed to figure out the behaviour of the curved part of the geosynthetic reinforced wall, and the results of the straight-line and curved part in the numerical analysis were compared and analysed. In addition, the behaviour characteristics at each condition were compared by considering the overburden load and relative density of backfill.

Effect of rapeseed meal supplementation to gestation diet on reproductive performance, blood profiles and milk composition of sows

  • Choi, H.B.;Hong, J.S.;Jin, S.S.;Jung, S.W.;Jang, J.C.;Jeong, J.H.;Kim, Y.Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.3
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    • pp.386-394
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    • 2018
  • Objective: This experiment evaluated the effect of dietary supplementation levels of rapeseed meal (RSM) in gestation diets on reproductive performance, blood profiles, milk composition of sows, and growth of their progeny. Methods: A total of 55 mixed-parity sows ($Yorkshire{\times}Landrace$; average parity = 3.82) with an initial body weight (BW) of 193.0 kg were used in this experiment. Sows were allotted to one of 5 treatments at breeding based on BW and backfat thickness in a completely randomized design. Treatments consisted of dietary RSM supplementation levels (0%, 3%, 6%, 9%, and 12%) in gestation diets. During lactation all sows were fed a common lactation diet with no RSM supplementation. Results: Body weight, backfat thickness, litter size, lactation feed intake, and milk composition of sows, and growth of their progeny were not different among dietary treatments. In blood profiles, a quadratic increase (Quadratic, p<0.05) in serum triiodothyronine (T3) concentration and a linear increase (Linear, p<0.01) in serum thyroxine (T4) concentration were observed at d 110 of gestation as dietary RSM supplementation levels increased. However, serum T3 and T4 concentrations in lactating sows and their piglets were not affected by RSM supplementation of gestation diets. Concentrations of serum total cholesterol and low density lipoprotein cholesterol in sows were not influenced by dietary treatments, whereas serum glucose level in sows decreased linearly at d 110 of gestation (Linear, p<0.05) by increasing dietary RSM supplementation in gestation diets. Conclusion: The RSM could be supplemented to gestation diets up to 12% with no detrimental effects on reproductive performance and growth of their progeny. However, increasing supplementation levels of RSM in gestation diets may increase serum T3 and T4 concentrations and decrease serum glucose concentration of sows in late gestation.