• Title/Summary/Keyword: Dense

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Mineralogical Changes of Oyster Shells by Calcination: A Comparative Study with Limestone (소성에 따른 굴패각의 광물학적 특성변화: 석회석과의 비교 연구)

  • Lee, Jin Won;Choi, Seung-Hyun;Kim, Seok-Hwi;Cha, Wang Seog;Kim, Kangjoo;Moon, Bo-Kyung
    • Economic and Environmental Geology
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    • v.51 no.6
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    • pp.485-492
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    • 2018
  • About 300 thousand tones of oyster shells are produced annually and, thus, their massive recycling methods are required. Recently, a method, utilizing them as wet desulfurization materials after removal of organic matters and changing $CaCO_3$ phase into CaO through calcination, is under consideration. This study investigates the mineralogical changes (specific surface area, phase changes, surface state, etc.) of oyster shells by calcination and their characteristics were compared with those of limestone. Uncalcined oyster shells showed the higher specific surface area than limestone because the former are composed of platy and columnar structures. In contrast, investigated limestone showed a dense structure. The phase change of oyster shells occurred at lower temperature than that of limestone. The specific surface area of oyster shell decreased significantly after calcination while limestone depicted a drastic increase. Small amount of Na contained in oyster shell was suggested as the cause of this phenomenon; in that, it acted as a flux causing melting and sintering of oyster materials at lower temperature. Because of this, an additional phenomenon was observed that a part of shell materials remained untransformed even at higher calcination temperature and after longer treatment period due to the sintered surface, which covers the rest parts. Further studies investigating the effect of this phenomena from the perspective of desulfurization is required.

A Study on the Improvement Method for Efficient Service of E-GEN AED using Time and Spatial Data (시·공간 데이터를 활용한 E-GEN AED의 효율적 서비스를 위한 개선방안)

  • Beak, Seong Ryul;Kim, Jun Hyun
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.37 no.4
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    • pp.253-265
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    • 2019
  • In this study were analyzed the errors on the registration of details information, location of E-GEN (Emergency medical-GEN) AED (Automated External Defibrillator) installation site and the adequacy of spatial arrangement, which suggests an improvement methods of constructing an app or web based on time and space data for efficient operation of considering accessibility and usability. As a result of this study, first, it was not equal to each other for locations of each installation point of AED, that confirmed some area were dense or requiring additional installation. Second, it confirmed the inaccuracies in inputting and registering information about the installed location, such as the actual installation location information and the attribute information of the AED. Third, the main access node and the main address node were connected to a straight line that was found not be connected to the back door, the straight line, the stairs. Also, the opening times of AED installation sites varied according to the week and the season, the entrance was managed by the apartment management office in a separate place, it needs to be established on this information. In conclusion, it proposed a method to improve spatial equity and accessibility, a method to provide accurate distance and time according to actual movement routes in case of emergency, and a possibility of using each facility considering day and time.

Preparation of calcium phosphates by hydrothermal synthesis route (수열합성법에 의한 calcium phosphates 분말합성)

  • Moon, Sung Wook;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.203-207
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    • 2019
  • Calcium phosphates such as hydroxyapatite (HAp), tricalcium phosphate (${\beta}$-TCP), and biphasic calcium phosphate (BCP, HAp/${\beta}$-TCP) have been prepared via hydrothermal treatment. The synthesis was conducted by reacting ($Ca(OH)_2$) aqueous solution with phosphoric acid ($H_3PO_4$) under different hydrothermal synthesis conditions (temperatures up to $150^{\circ}C$ and pH lower than 12). The effects of initial precursor Ca/P ratio (1.30, 1.50 and 1.67) and post heat treatment on the phase evolution behavior of the powders and sintered ceramics were investigated. The phases of resulting powders and sintered ceramics were controllable by adjusting the initial Ca/P ratio. A single HAp phase without any noticeable second phase was obtained for the initial Ca/P ratio of 1.67 in the overall heat treatment range. Pure ${\beta}$-TCP and biphasic calcium phosphate (HAp/${\beta}$-TCP) were synthesized from precursor solutions having Ca/P molar ratios of 1.30 and 1.50, respectively, after having been heat treated at $900^{\circ}C$ or higher. Dense ceramics with translucency were obtained at considerably lower sintering temperatures.

Load Fidelity Improvement of Piecewise Integrated Composite Beam by Irregular Arrangement of Reference Points (참조점의 불규칙적 배치를 통한 PIC보의 하중 충실도 향상에 관한 연구)

  • Ham, Seok Woo;Cho, Jae Ung;Cheon, Seong S.
    • Composites Research
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    • v.32 no.5
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    • pp.216-221
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    • 2019
  • Piecewise integrated composite (PIC) beam has different stacking sequences for several regions with respect to their superior load-resisting capabilities. On the interest of current research is to improve bending characteristics of PIC beam, with assigning specific stacking sequence to a specific region with the help of machine learning techniques. 240 elements of from the FE model were chosen to be reference points. Preliminary FE analysis revealed triaxialities at those regularly distributed reference points to obtain learning data creation of machine learning. Triaxiality values catagorise the type of loading i.e. tension, compression or shear. Machine learning model was formulated by learning data as well as hyperparameters and proper load fidelity was suggested by tuned values of hyperparameters, however, comparatively higher nonlinearity intensive region, such as side face of the beam showed poor load fidelity. Therefore, irregular distribution of reference points, i.e., dense reference points were distributed in the severe changes of loading, on the contrary, coarse distribution for rare changes of loading, was prepared for machine learning model. FE model with irregularly distributed reference points showed better load fidelity compared to the results from the model with regular distribution of reference points.

Observation on the Seabed around Simheungteak Seamount near Dokdo and using Mini-ROV (소형 ROV를 활용한 독도 및 심흥택해산 해저면 탐사)

  • MIN, WON-GI;RHO, HYUN SOO;KIM, CHANG HWAN;PARK, CHAN HONG;KIM, DONGSUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.1
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    • pp.18-29
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    • 2019
  • ROV surveys were conducted using 500 meter mini class ROV with HD video camera, 2 LED lights, a simple manipulator and 8 thrusters near the Dokdo and Simheungtaek seamount. Total six dives have been conducted using the ROV "V8 SII" from Sweden and ROV's support ship, "KOSAL V" at 4 stations between 45 and 370 meters with diving time ranged from 30 to 120 minutes. Dense communities of sea anemone (Actinostolidae sp.) and ophiuroids (Ophiuridae sp.) on the surface of rocky bottom and snow crab on the soft bottom with muddy-sand were observed at northwestern part of Simheungtaek seamount. We obtained the following results 1) habitats information for snow crab, one of the major fisheries resources, and deep-sea fauna, 2) observation on the specific topography and sediment conditions, 3) observation of the seabed surface covered with the discarded fishing gears. This study represents the first report of in situ visual observation of deep-sea organisms and their habitats near the Dokdo slopes and flat top of the Simheungtaek seamount in the East Sea. These results indicated that immediate oceanographic survey using the mini class ROV is available in the East Sea.

Urban Street Planting Scenarios Simulation for Micro-scale Urban Heat Island Effect Mitigation in Seoul (미시적 열섬현상 저감을 위한 도시 가로수 식재 시나리오별 분석 - 서울시를 대상으로 -)

  • Kwon, You Jin;Lee, Dong Kun;Ahn, Saekyul
    • Journal of Environmental Impact Assessment
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    • v.28 no.1
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    • pp.23-34
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    • 2019
  • Global warming becomes a serious issue that poses subsidiary issues like a sea level rise or a capricious climate over the world. Because of severe heat-wave of the summer in Korea in 2016, a big attention has been focused on urban heat island since then. Not just about heat-wave itself, many researches have been concentrated on how to adapt in this trendy warming climate and weather in a small scope. A big part of existing studies is mitigating "Urban Heat Island effect" and that is because of huge impervious surface in urban area where highly populated areas do diverse activities. It is a serious problem that this thermal context has a high possibility causing mortality by heat vulnerability. However, there have been many articles of a green infrastructures' cooling impact in summer. This research pays attention to measure cooling effect of a street planting considering urban canyon and type of green infrastructures in neighborhood scale. This quantitative approach was proceeded by ENVI-met simulation with a spatial scope of a commercial block in Seoul, Korea. We found the dense double-row planting is more sensitive to change in temperature than that of the single-row. Among the double-row planting scenarios, shrubs which have narrow space between the plant and the land surface were found to store heat inside during the daytime and prevent emitting heat so as to have a higher temperature at night. The quantifying an amount of vegetated spaces' cooling effect research is expected to contribute to a study of the cost and benefit for the planting scenarios' assessment in the future.

Effect of Vinylene Carbonate as an Electrolyte Additive on the Electrochemical Properties of Micro-Patterned Lithium Metal Anode (미세 패턴화된 리튬금속 전극의 Vinylene Carbonate 첨가제 도입에 따른 전기화학 특성에 관한 연구)

  • Jin, Dahee;Park, Joonam;Dzakpasu, Cyril Bubu;Yoon, Byeolhee;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.22 no.2
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    • pp.69-78
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    • 2019
  • Lithium metal anode with the highest theoretical capacity to replace graphite anodes are being reviewed. However, the dendrite growth during repeated oxidation/reduction reaction on lithium metal surface, which results in poor cycle performance and safety issue has hindered its successful implementation. In our previous work, we solved this problem by using surface modification technique whereby a surface pattern on lithium metal anode is introduced. Although the micro-patterned Lithium metal electrode is beneficial to control Li metal deposition efficiently, it is difficult to control the mossy-like Li granulation at high current density ($>2.0mA\;cm^{-2}$). In this study, we introduce vinylene carbonate (VC) electrolyte additive on micro patterned lithium metal anode to suppress the lithium dendrite growth. Owing to the synergetic effect of micro-patterned lithium metal anode and VC electrolyte additive, lithium dendrite at a high current density is dense. As a result, we confirmed that the cycle performance was further improved about 6 times as compared with the reference electrode.

Facilitated Oxygen Transport through a Polyethersulfone Membrane Containing Cobalt Tetraphenylporphyrin-Benzylimidazole (Cobalt Tetraphenylporphyrin-benzylimidazole을 포함한 산소 촉진수송막)

  • Lee, Seung Hwan;Park, Se Hyung;Park, Jung Hoon
    • Membrane Journal
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    • v.28 no.6
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    • pp.424-431
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    • 2018
  • The gas separation performance of a mixed membrane structure based on a mixture of polyethersulfone (PES) and cobalt tetraphenylporphyrin-benzylimidazole (CoTpp-BIm) as an oxygen carrier was investigated. The CoTpp-BIm mixed PES membrane had an asymmetric structure with a mixture of finger structure and sponge-like structure, and the upper surface was dense. The gas separation performance test was carried out using $94%\;N_2$ gas and $6%\;O_2$ mixed gas. Oxygen and nitrogen permeability coefficients were measured at ${\Delta}P$ ranging from 15 to 228 cmHg and the permeate side of the PES membrane was maintained at vacuum level. The oxygen permeability coefficient of CoTpp-BIm mixed PES membranes increased as supplied pressure was decreased. When the supply pressure was 15 cmHg, the gas permeability ($P_{O_2}$) was 6676 Barrer, the $O_2/N_2$ selectivity (${\alpha}$) was 6.1, and the promoting factor (F) was 2.39. Based on these results, it was confirmed that the addition of CoTpp-BIm to the PES film improved the oxygen separation characteristics.

Analysis of the Individual Tree Growth for Urban Forest using Multi-temporal airborne LiDAR dataset (다중시기 항공 LiDAR를 활용한 도시림 개체목 수고생장분석)

  • Kim, Seoung-Yeal;Kim, Whee-Moon;Song, Won-Kyong;Choi, Young-Eun;Choi, Jae-Yong;Moon, Guen-Soo
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.22 no.5
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    • pp.1-12
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    • 2019
  • It is important to measure the height of trees as an essential element for assessing the forest health in urban areas. Therefore, an automated method that can measure the height of individual tree as a three-dimensional forest information is needed in an extensive and dense forest. Since airborne LiDAR dataset is easy to analyze the tree height(z-coordinate) of forests, studies on individual tree height measurement could be performed as an assessment forest health. Especially in urban forests, that adversely affected by habitat fragmentation and isolation. So this study was analyzed to measure the height of individual trees for assessing the urban forests health, Furthermore to identify environmental factors that affect forest growth. The survey was conducted in the Mt. Bongseo located in Seobuk-gu. Cheonan-si(Middle Chungcheong Province). We segment the individual trees on coniferous by automatic method using the airborne LiDAR dataset of the two periods (year of 2016 and 2017) and to find out individual tree growth. Segmentation of individual trees was performed by using the watershed algorithm and the local maximum, and the tree growth was determined by the difference of the tree height according to the two periods. After we clarify the relationship between the environmental factors affecting the tree growth. The tree growth of Mt. Bongseo was about 20cm for a year, and it was analyzed to be lower than 23.9cm/year of the growth of the dominant species, Pinus rigida. This may have an adverse effect on the growth of isolated urban forests. It also determined different trees growth according to age, diameter and density class in the stock map, effective soil depth and drainage grade in the soil map. There was a statistically significant positive correlation between the distance to the road and the solar radiation as an environmental factor affecting the tree growth. Since there is less correlation, it is necessary to determine other influencing factors affecting tree growth in urban forests besides anthropogenic influences. This study is the first data for the analysis of segmentation and the growth of the individual tree, and it can be used as a scientific data of the urban forest health assessment and management.

Secondary Metabolites and Morphological Diversity in the Leaves of Perilla Landrace from Korea

  • Assefa, Awraris Derbie;Sung, Jung-Sook;Jeong, Yi-Jin;Lee, Ho-Sun;Rhee, Ju-Hee;Hur, On-Sook;Noh, Jae-Jong;Ro, Na-Young;Hwang, Ae-Jin;Lee, Jae-Eun
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2019.10a
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    • pp.64-64
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    • 2019
  • Screening and identification of genetic resources based on their phytoconstituents and morphological characters potentially provide baseline data for researchers, breeders, and nutraceutical companies who wish to formulate a nutrient-dense diet and health beneficial supplement. Thus, we evaluated the amount of total phenolic content and major phenolic compounds; examined if phenolic compounds could be used as distinguishing factors for perilla genetic resources; and investigated the relation between some quantitative and qualitative morphological characters with the contents of phenolic compounds in 360 accessions obtained from National Agrobiodiversity Center gene bank, Jeonju, Korea. Total phenolic content (TPC) was estimated using Folin-Ciocalteu colorimetric assay. Individual phenolic compounds were determined using an Ultra-High Performance Liquid Chromatography system equipped with Photodiode Array detector. Considerable variations were observed in TPC (7.99 to 117.47 mg GAE/g DE), rosmarinic acid (RA) (ND to 19.19 mg/g DE), caffeic acid (CA) (ND to 0.72 mg/g DE), apigenin-7-O-diglucuronide (ADG) (ND to 1.24 mg luteolin equivalent (LUE)/g DE), scutellarein-7-O-glucuronide (SG) (ND to 4.32 mg LUE/g DE), and apigenin-7-O-glucuronide (AG) (ND to 1.60 mg LUE/g DE). RA was the most dominant phenolic compound in most accessions (95.3%) followed by SG. The adaxial leaf color was light green, green and dark green in 13.8%, 65.0%, and 21.1 % of the accessions, respectively. 78.8% of the accessions had light green color at the abaxial side with the remaining being described as green. Most of the accessions (96.9%) were cordate shape, the remaining being eclipse. Intensities of green pigment at abaxial and adaxial leaf surfaces were correlated with contents of individual phenolic compounds and TPC whereas leaf length and width had no correlation with TPC, CA and RA, and negatively correlated with ADG, AG, and SG. Leaf shape was not related with content of phenolic compounds, color of leaves, or the length or width of leaves. Accessions IT57426, IT157434, IT267710, and IT267712 which contained relatively high contents of TPC and major phenolic compounds (RA and SG) could be used for further research in breeding and bioassay test. Our study result showed the contents of total phenolics and individual phenolic compounds along with the morphological characters could be useful distinguishing factors for perilla genetic resources.

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