• 제목/요약/키워드: Degree of conversion

검색결과 351건 처리시간 0.028초

Degree of conversion of resin composite cured by light through a translucent fiber posts

  • Urapepon, Somchai
    • The Journal of Advanced Prosthodontics
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    • 제6권3호
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    • pp.194-199
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    • 2014
  • PURPOSE. This study evaluated the depth of cure of resin composite cured by light through a translucent fiber post. MATERIALS AND METHODS. The opaque plastic tubes in various lengths of 2, 4, 6, 8, 10, 12, 14 mm. were filled with resin composite in which two different translucent fiber posts were inserted into the center and photo-polymerized for 40 seconds. The degree of conversion of the cured composite at bottom surface were examined using Fourier transform infrared attenuated total reflection spectrometer (FTIR/ATR) at 0.1, 0.5 and 1.0 mm apart from the post surface. RESULTS. The degree of conversion of the 0.1 mm, 0.5 mm, 1.0 mm apart from the post surface was highest at the 2 mm level and continuously decreased when the distance from the light source was increased and drastically decreased when the depth from the top of the post was greater than 4-6 mm. For each level, the highest degree of conversion was at 0.1 mm from the post surface and decreased continuously when the distance apart from the post surface was increased. CONCLUSION. The quantity of light transmission depends on the type of post and the light transmission capability of the post, especially after 4-6 mm depth and the area further apart from the post surface, are insufficient for clinical light activation of resin composite.

수종 복합레진 내의 bis-GMA와 TEGDMA의 구성비가 레진 인레이 법에 의한 부가적 열처리시 복합레진의 표면 및 내부의 중합률 변화에 미치는 영향 (CORRELATION BETWEEN BIS-GMA : TEGDMA RATIO AND DEGREE OF CONVERSION IN VARIOUS LAYERS OF COMPOSITE AFTER ADDITIONAL HEAT CURING)

  • 박성호;정찬문
    • Restorative Dentistry and Endodontics
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    • 제21권2호
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    • pp.642-651
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    • 1996
  • The purpose of this study was to evaluate the relationship between monomer compositions and the changes in the degree of conversion in the various layers of composites after additional heat curing. Four types of composites and 3 types of inlay ovens were used in this study. Composite was placed in a 4-mm thick teflon mold, and light cured from the top for 60 seconds. Ten samples were prepared for each composite ; 5 of these were additionally heat cured in an inlay oven as the manufacturer recommended. After light curing or light and heat curing, the samples were sectioned into four parts and assigned to groups A, B, C, or D according to their distance from the light source. These sections were then thinned to 50-$70{\mu}m$, and these wafers were analyzed with a Fourier Transform Infrared Spectrometer(FI-IR) to determine the degree of conversion. A standard baseline technique was used to calculate the degree of conversion. $^{13}C$ NMR spectra of bis-GMA, TEGDMA and bis-EMA, were acquired using a Varian Gemini spectrometer operated at 200 MHz. $CDCl_3$ solvent was used for qualitative analysis. The degree of conversion was affected by bis-GMA : TEGDMA ratio but it seemed to be also affected by other factors. When the composites were heat cured, significant increases in the degree of conversion were noted throughout the samples, but the amount of increase differed between materials. Thus, clinical performance of a heat-treated composite inlay may be different depending on materials.

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복합레진 표면의 중합률 (THE RELATIVE DEGREE OF CONVERSION OF THE COMPOSITE RESIN SURFACE)

  • 박성호
    • Restorative Dentistry and Endodontics
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    • 제21권1호
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    • pp.360-365
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    • 1996
  • The purpose of this study was to evaluate the changes in the degree of conversion on a composite resin surface following heat treatment and mylar strip finishing. The effects of the time interval between the light-curing and heat-curing process were also evaluated. The composite resin surface which had been covered with a coverglass showed a lower conversion rate than the surface from which a layer of $500{\mu}m$ was ground away. The composite resin surface was definitely affected by oxygen during the heat curing process when it had not been insulated. When the composite resins were heat cured after 3 days of storage following the light curing process, the increased in the degree of conversion through heatcuring was limited.

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수치영상을 이용한 토량환산계수 산정 (The Estimation of Soil Conversion Factor using Digital Imagery)

  • 이종출;차성렬;장호식;김진수
    • 한국측량학회:학술대회논문집
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    • 한국측량학회 2003년도 추계학술발표회 논문집
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    • pp.169-174
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    • 2003
  • Design of a rational earth volume conversion coefficient is required as the earth volume conversion coefficient may give great influence on construction work volume and construction costs in the civil engineering works where large-scaled earth volume is excavated. However, there are a great deal of difficulties in the calculation of the exact spoil surface earth and Insufficient earth volume by adopting the figures presented on the generally used design specifications which are not the results obtained from the selection tests in calculating the earth volume conversion coefficient. In this connection, it would be desirable to calculate the earth volume conversion coefficient by carrying out large-scaled site test adequate for the relevant environment. In consequence, this study aims at calculating the exact earth volume conversion coefficient of cutting and banking areas of weathering rocks in large-scaled construction sites where land is being developed into home lots. For this, we have excavated the respective 20 sites of the cutting and banking areas in the said site and then calculated the volume after the excavation. As a result, the relative exactness degree of the crossing was calculated at 0.5% in average. The relative exactness degree of 0.5% in the volume may be judged as an exact measurement as it corresponds to 0.17% of the relative exactness degree in the length measurement. We have calculated the exact earth volume conversion coefficient by the use of function ratio as per the wet unit weight and the indoor soil quality test as per volume calculated. And then we have found out minor differences as a result of the comparison and analysis with the earth volume conversion coefficient determined by the dry unit weight test as per sand replacement method. This may be judged as a rational design method for the calculation of earth volume conversion coefficient, as well as high reliability of site test as a precision photogrammetry is adopted for volume measurement of the irregular excavating areas.

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B$\'{e}$zier 곡선의 차수감소와 최대오차의 계산 (Degree Reduction and Computation of the Maximum Error of B$\'{e}$zier Curves)

  • 김혁진
    • 한국컴퓨터정보학회논문지
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    • 제4권4호
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    • pp.25-33
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    • 1999
  • 서로 다른 기하학적 모델링 시스템을 사용하는 곡선 및 곡면의 자료 교환에서, 주어진 허용 오차 내에서 시스템이 지원하는 차수로 근사하는 차수감소를 종종 필요로 한다 본 논문에서는 기하학적 표현이 서로 다른 시스템간의 곡선 및 곡면의 교환에서 $\'{e}$의 차수감소에 의한 근사 변환 문제를 다룬다. 여러 가지 n차 $\'{e}$ 곡선을 n-1차 $\'{e}$ 곡선으로 감소하는 차수감소 방법들을 구현하고 각 방법들의 근사 변환한 실험적인 결과를 제공한다.

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지르코니아 투명도 및 두께에 따른 레진 시멘트의 중합률 (The degree of conversion of dual-cured resin cement as a function of transmittance and thickness)

  • 노형록;주규지;선금주
    • 대한치과기공학회지
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    • 제38권3호
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    • pp.193-199
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    • 2016
  • Purpose: The purpose of this study was to know of photopolymerization effect of self-etch dual-cured resin cement on different transmittance and thickness of zirconia disks. Methods: The two types of transparent and opaque zirconia speciments were prepared. The five speciments of each groups were seperated with 0.5mm and 1.0mm thickness. Degree of conversion(DC) were studied by FT-IR spectroscopy using ATR method before and after irradidaion for 40 sec. Results: The relative DC was showed the higher results of ZS5 as compared with ZS10 (p < 0.05). And OP5 and OP10 were lower results than ZS10 (p < 0.05). Conclusion: The photopolymerization effect of dual-cured resin cement were affected by the transmittance and thickness of zirconia.

광원에 따른 조사거리의 증가가 복합레진의 중합도에 미치는 영향 (INFLUENCE OF TIP DISTANCE ON DEGREE OF CONVERSION OF COMPOSITE RESIN IN CURING WITH VARIOUS LIGHT SOURCES)

  • 김상배;박호원
    • 대한소아치과학회지
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    • 제31권2호
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    • pp.273-279
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    • 2004
  • 최근에 소개된 single high-intensity LED 중합기는 이전의 LED 중합기에 비해 높은 광도를 가지며 짧은 중합시간에 적절한 물성을 가질 수 있다고 한다. 본 연구는 single high-intensity LED 중합기의 중합성능을 평가하기 위하여 거리에 따른 중합도를 조사하였다. Mylar strip사이에 복합레진(Filtek Z250)을 넣고 압접시켜 만든 얇은 필름형 시편을 LED 중합기(Elipar Freelight 2, 10초), 플라스마 중합기(Flipo, 6초)와 할로겐 중합기 (XL3000, 20초)를 사용해 0mm, 2mm, 4mm, 6mm에서 광도를 측정하고 중합시켰다. 중합된 시편을 Fourier Transform Infrared Spectrometer(FTIR)를 이용해 중합도를 측정한 후 다음과 같은 결론을 얻었다. 1. 모든 중합기에서 거리가 증가할수록 유의하게 광도가 감소하였으며 LED중합기의 경우 6mm에서 다른 중합기에 비해 가장 많은 광도 감소율을 보였다(p<0.05). 2. 모든 중합기에서 거리가 증가함에 따라 4mm까지는 중합도가 감소하였지만 유의한 차이는 보이지 않았다(p>0.05). 하지만 4mm와 6mm사이에서는 모든 중합기에서 유의하게 감소하였다(p<0.05). 3. 각 거리에 따른 중합기간의 중합도 차이는 0mm, 2mm, 4 mm에서 LED중합기가 다른 중합기보다 유의하게 높은 중합도를 보였으며 (p<0.05) 플라스마 중합기와 할로겐 중합기 사이에서는 유의한 차이가 없었다. 하지만 6 mm에서는 모든 중합기 사이에 유의한 차이를 보이지 않았다(p>0.05).

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Numerical studies on dynamic response of interactive system between atmosphere and ocean

  • Ryu, Chan-Su;Lee, Soon-Hwan
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.226-231
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    • 2003
  • A coupling system of MM5 and POM using Stampi with different kinds of parallel computer is proposed and comparative numerical simulations of mesoscale wind induced by topography around East Sea/Sea of Japan are carried out. The results are as follows: 1) Strong horizontal conversion is induced by high mountain Pekdoo at its leeside. 2) The conversion winds at lee of high mountain are not clear in monthly and yearly mean NCEP-reanalysis because of coarse resolution of 1.86 degree by 1.86 degree. But Wind conversion is well simulated at atmosphere and ocean coupling system. And the conversion area of lee side of mountain is also agreed well with observed data of NSCAT launched in satellite ADEOS. 3) The surface ocean current is well correspondent with wind direction, induced by high mountains. And small different wind field information lead the different of particle distribution in numerical experiments of particle distribution on ocean surface.

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조사광이 통과하는 치질의 두께와 광조사시간에 따른 광중합형 복합레진의 중합률에 관한 연구 (A STUDY ON THE DEGREE OF CONVERSION OF LIGHT CURING COMPOSITE RESIN ACCORDING TO THE THICKNESS OF TOOTH STRUCTURE PENETRATED BY LIGHT AND APPLIED LIGHT CURING TIME)

  • 황기환;장인호;이세준;이광원
    • Restorative Dentistry and Endodontics
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    • 제27권1호
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    • pp.16-23
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    • 2002
  • Physical properties of composite resins such as strength, resistance to wear, discoloration, etc depend on the degree of conversion of the resin components. The purpose of this study was to evaluate the degree of conversion of the composite resins according to the thickness of tooth structure penetrated by light and applied light curing time. The coronal portions of extracted human teeth (one anterior tooth, three posterior tooth) was embedded by pink denture material. the mounted teeth were cut into three illumination sections (1mm thickness enamel section, 1mm thickness dentin section, 2mm thicknes dentin section) and one backing section with cutting wheel. Thin resin films were made by using 6kg pressure between slide glass during 5 minutes Thin resin film was light cured on coupled illumination section during 40sec, 80sec and 120sec. each illumination section was coupled as follows; no tooth structure(X), ename section(E), enamel section + 1mm dentin section(ED1), enamel section + 2mm dentin section(ED2), enamel section + 1mm dentin section + 2mm dentin section(EDD). To simulate the clinical situation more closely, thin resin films was cured against a backing section of tooth structure. The degree of conversion of carbon double bonds to single bonds in the resin films were examined by means of Fourier Transform Infrared Spectrometer. The results were obtained as follows ; 1 As curing time was increased, conversion rate was increased and as tooth thickness which was penetrated by curing light was increased, conversion rate was decreased. 2. At all tooth thickness groups, conversion rate between 80sec and 120sec was not significantly increased(P>0.05). 3. At 40sec group and 80sec, conversion rate between no tooth structure(X) group and 1mm enamel section(E) group was not significantly decreased(P>0.05). 4. At 80sec group and 120sec, conversion rate between 1mm enamel section(E) group and 1mm enamel section + 1mm dentin section(ED1) group was not significantly decreased(P>0.05).

기질레진의 조성에 따른 복합레진의 물리적 성질에 관한 연구 (EFFECT OF RESIN MATRIX ON DEGREE OF CONVERSION AND FRACTURE TOUGHNESS OF DENIAL COMPOSITES)

  • 이연신;최경규;박상진
    • Restorative Dentistry and Endodontics
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    • 제27권1호
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    • pp.77-86
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    • 2002
  • Current composites are made with dimethacrylate monomers and silane-treated silica microfillers, either alone or with silane treated glass fillers The main reasons for clinical failure of dental composites are secondary caries, wear and fracture. Most of practitioner want to get a composite which is more tougher under occlusal stress, less polymerization contraction, and better handling properties in application clinically. The aim of this study was to investigate the influence of resin matrix with various flows on the physical proper-ties such as fracture toughness and degree of conversion of the experimental resins. It was hypothesized that flexible or tough resin composites can be designed by judicious choice of monomer composition Various flow resin matrices containing Bis-GMA, UDMA, and TEG-DMA were made by altering the pro-portion of the monomers. After the unfilled resins were light-cured for different light intensity, the fracture toughness(K$_{1c}$) was measured according to ASTM standard using the single edge notched geometry, and degree of conversion(DC) was measured by FTIR. And experimental composites were formulated with variations in the proportion of silanated quartz and strontium glass fillers as 60, 75, and 77wt%. Also, the physical properties of composites with various filer contents were evaluated as same manner. All resulting data were compared by ANOVA/Tukeys test at 0.05 level. The results were as follows; 1. The degree of conversion of high flow resin containing less Bis-GMA was higher than that of low flow unfilled resin 2. While the degree of conversion of unfilled resin was increased according to light intensity for polymerization, there was no significant increase with moderate and high light intensity. Also, the fracture toughness was not increased by high light intensity. 3. The fracture toughness was high in the low flow unfilled resin containing higher contents of Bis-GMA. 4. There was a significant increase for fracture toughness and a tendency for degree of conversion to be reduced when the content of fillers was increased. 5. In the experimental composites, the flow of resin matrix did not affected on the fracture toughness, even, which was decreased as increase of viscosity. These results showed that the physical properties of a dental composite could be attributed to the flow of resin matrix with relative content of monomers. Specific combination of resin monomers should be designed to fulfil the needs of specific indication for use.