• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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• pp.358-361
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• 2004

The photocatalytic degradation of Endocrine Discruptors, dibuthyl phthalate(DBP) has been investigated over TiO$_2$ photocatalysts irradiated with a ultraviolet (UV) light. The effect of operational parameters, i.e., reaction time, light intensity, pH and additive on the degradation rate of aqueous solution of Endocrine Discruptors has been examined. Results show that the employment of efficient photocatalysts and the selection of optimal operational parameters may lead to degradation of Endocrine Discruptors solutions.

• 도시과학
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• 제8권2호
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• pp.13-18
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• 2019

Using self-made coil dielectric barrier discharge reactor, the removal efficiency of ethyl acetate under simulated experimental parameters such as initial concentration of waste gas, total flow rate, relative humidity and voltage was investigated. The results show that the degradation rate of ethyl acetate increases with the increase of output voltage. When other conditions remain unchanged, the degradation rate decreases with the increase of initial concentration of ethyl acetate; with the increase of total flow rate, the degradation rate of ethyl acetate decreases; with the increase of relative humidity, the degradation rate first increases and then decreases, and when the relative humidity is 64%, the degradation efficiency is the highest.

• 대한기계학회논문집A
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• 제26권5호
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• pp.881-889
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• 2002

Newly developed continuous indentation technique has made nondestructive assessment of tensile properties possible. The present study was undertaken to determine new parameters for indicating time-dependent material degradation of petro-chemical plant. Continuous indentation tests were performed for Cr-Ni steel and Cr-Mo steel which are widely used as facilities of petro-chemical plant. From the results, it was found that yield strength and tensile strength cannot be used as general degradation parameters because the changes in the strengths with aging time didn't show any tendency. On the other hand, work hardening exponent and yield ratio showed consistent tendency with increasing aging time. Therefore, nam attention of this work was paid on them as new degradation parameters, and the in-field applicability of the parameters was evaluated and discussed.

• 한국식품과학회지
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• 제33권1호
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• pp.66-71
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• 2001

가열에 의한 품종별 고구마 조직의 변화에 대한 반응속도론적 상수를 biphasic model과 fractional conversion method를 사용하여 결정하였다. Biphasic model에 따라 고구마의 가열에 의한 조직의 변화는 2단계의 연속적인 1차 반응식으로 표시할 수 있었으며, 활성화에너지는 고구마의 품종에 따라 $71.0{\sim}75.1\;kJ/mol$ 및 $48.4{\sim}59.6\;kJ/mol$이었다. 또한 고구마의 가열에 의한 조직변화를 fractional conversion method를 사용하여 1개의 1차 반응식으로 표시할 수 있었는데, 이 때의 활성화에너지는 $67.5{\sim}75.3\;kJ/mol$로서 biphasic model에 의한 제 1단계의 반응에 대한 값과 유사한 값을 나타냈다. 이들 방법으로 결정된 반응속도론적 상수들 사이에는 kinetic compensation 효과가 있었으며, 두 방법 모두 고구마의 가열에 의한 조직변화에 대한 반응속도론적 상수들을 결정하는데 적용할 수 있음을 알 수 있었다.

• 한국신뢰성학회지:신뢰성응용연구
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• 제16권4호
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• pp.356-363
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• 2016

Purpose: The purpose of this study is to propose efficiency of equipment testing the luminance degradation of OLED. Methods: The degradation model of Exponential model and Stretched exponential model is analyzed by goodness of fit test using calculated R-square. The degradation model having the higher R-square is finally selected. Scale parameter and Shape parameter using the selected degradation model is estimated. The activation energy and current density n using peck model among the accelerated model is estimated. the estimated parameters are analyzed by t-test. Results: The results of t-test show that the estimated parameters on chamber and hotplate are equal statistically. we can know the similarity of the luminance degradation rate and degradation pattern on chamber and hotplate. Conclusion: The result of the degradation test on chamber and hotplate is similar. when the accelerated degradation test on the panel of the OLED TV is performed, hotplate is requiring less samples, time and cost than chamber. so the accelerated degradation test on the panel of the OLED TV using the hoplate is efficient of time and cost.

• Journal of Microbiology and Biotechnology
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• 제11권4호
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• pp.607-613
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• 2001

The biodegradation rates of diesel oil by a selected diesel-degrading bacterium, Pseudomonas stutzeri strain Y2G1, and microbial consortia composed of combinations of 5 selected diesel-degrading bacterial were determined in liquid and soil systems. The diesel degradation rate by strain Y2G1 linearly increased $(R^2=0.98)$ as the diesel concentration increased up to 12%, and a degradation rate as high as 5.64 g/l/day was obtained. The diesel degradation by strain Y2G1 was significantly affected by several environmental factors, and the optimal conditions for pH, temperature, and moisture content were at pH8, $25^{\circ}C$, and 10%, respectively. In the batch soil microcosm tests, inoculation, especially in the form of a consortium, and the addition of nutrients both significantly enhanced the diesel degradation by a factor of 1.5 and 4, respectively. Aeration of the soil columns effectively accelerated the diesel degradation, and the initial degradation rate was obviously stimulated with the addition of inorganic nutrients. Based on these results, it was concluded that the major rate-limiting factors in the tested diesel-contaminated soil were the presence of inorganic nutrients, oxygen, and diesel-degrading microorganisms. To resolve these limiting parameters, bioremediation strategies were specifically designed for the tested soil, and the successful mitigation of the limiting parameters resulted in an enhancement of the bioremediation efficiency by a factor of 11.

• 대한산업공학회지
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• 제33권1호
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• pp.153-163
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• 2007

An adaptive framework paradigm where the bandwidth values of the ongoing calls vary according to the trafficsituations is one of the promising concepts for overcoming poor resource conditions due to handoffs in mobilecellular networks. However, quantifying the level of bandwidth degradation of the ongoing calls in an adaptiveframework is important in view of Quality of Service (QoS) Provisioning. Therefore we introduce new QoSparameters, the Degradation Degree Ratio (DDR), which represents the average portion of the degradationdegree during degradation pehod of a call, and the Degradation Area Ratio (DAR), which represents the averageratio of a call's degradation level considering both the period and the degree of degradation jointly in multi-levelbandwidth service. We also develop a new analytical model for estimating the QoS measures such as theDegradation Pehod Ratio (DPR), DDR and DAR. We show how to calculate the QoS measures and illustrate themethod by numerical examples. The proposed model can be used to determine the optimal parameter of theCAC scheme and analyze the sensitivity ofthe QoS parameters in adaptive networks.

• 대한환경공학회지
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• 제32권3호
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• pp.241-247
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• 2010

오존 접촉 반응기에서 용존 오존 농도 및 페놀 제거에 미치는 운전변수의 영향에 대해 실험실 규모 실험을 수행하였다. 반응기로 가스상 오존이 공급되고 일정한 시간이 경과한 후에 용존 오존 농도는 포화 농도에 도달하였으며 포화 농도의 크기는 운전 변수에 의해 영향을 받는 것으로 나타났다. 수용액내의 오존은 높은 pH 조건에서 불안정하므로 용존 오존 농도는 용액의 초기 pH값이 증가함에 따라 감소하였다. 일정한 유량의 기체가 반응기로 공급되는 조건에서 가스상 오존 농도의 크기는 용존 오존의 포화농도에 중요한 영향을 미치며 일정한 농도의 가스상 오존이 공급될 때 가스 유량은 용존 오존이 포화되는 속도에 영향을 주는 것으로 관찰되었다. 페놀 제거에 미치는 운전변수의 영향은 각 운전변수가 용존 오존 농도에 미치는 영향과 밀접하게 관련되어 있는 것으로 나타났다. 용존 오존은 높은 pH 조건에서 빠르게 분해되어 페놀과의 반응성이 높은 자유라디칼을 생성시키므로 pH가 증가함에 따라 페놀 제거가 향상되었다. 동일한 pH 조건에서 가스상 오존 농도 및 가스 공급량의 증가는 용존 오존을 증가시킴으로써 페놀 분해를 증진시키는 것으로 나타났다. 메탄올의 주입은 OH 라디칼을 소비시켜 페놀 분해를 방해하는 것으로 관찰되었다.

• 상하수도학회지
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• 제26권1호
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• pp.69-76
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• 2012

A laboratory experiment on methyl orange degradation in pulsed corona discharges was carried out. Effects of operating parameters such as applied voltage, pH, conductivity and initial concentration on methyl orange degradation were investigated. The pulsed corona discharges decreased the pH of solution and increased conductivity, probably due to products generated from methyl orange degradation by corona discharges. The decrease of initial pH enhanced the methyl orange degradation. The methyl orange degradation was fastest in $100{\mu}S/cm$ conductivity solution, followed by 50 and $200{\mu}S/cm$, indicating that $100{\mu}S/cm$ is the most favorable in the aspect of radical generation among the experimented conditions. The methyl orange of initial concentration from 20 to 60mg/L was effectively degraded in pulsed corona discharges. The lower initial concentration of methyl orange, the faster degradation was observed.

• Macromolecular Research
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• 제14권5호
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• pp.491-498
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• 2006

The thermal degradation of poly(hexamethylene guanidine) phosphate (PHMG) was studied by dynamic thermogravimetric analysis (TGA) and pyrolysis-GC/MS (p-GC). Thermal degradation of PHMG occurs in three different processes, such as dephosphorylation, sublimation/vaporization of amine compounds and decomposition/ recombination of hydrocarbon residues. The kinetic parameters of each stage were calculated from the Kissinger, Friedman and Flynn-Wall-Ozawa methods. The Chang method was also used for comparison study. To investigate the degradation mechanisms of the three different stages, the Coats-Redfern and the Phadnis-Deshpande methods were employed. The probable degradation mechanism for the first stage was a nucleation and growth mechanism, $A_n$ type. However, a power law and a diffusion mechanism, $D_n$ type, were operated for the second degradation stage, whereas a nucleation and growth mechanism, $A_n$ type, were operated again for the third degradation stage of PHMG. The theoretical weight loss against temperature curves, calculated by the estimated kinetic parameters, well fit the experimental data, thereby confirming the validity of the analysis method used in this work. The life-time predicted from the kinetic equation is a valuable guide for the thermal processing of PHMG.