• 제목/요약/키워드: Degradation behavior

검색결과 909건 처리시간 0.029초

Improvement of Electrochemical Characteristics and Study of Deterioration of Aluminum Foil in Organic Electrolytes for EDLC

  • Lee, Mun-Soo;Kim, Donna H.;Kim, Seung-Cheon
    • Journal of Electrochemical Science and Technology
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    • 제9권1호
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    • pp.9-19
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    • 2018
  • The anodic behavior of aluminum (Al) foils with varying purity, capacitance, and withstand voltage in organic electrolytes was examined for EDLC. The results of cyclic voltammetry (CV) and chronoamperometry (CA) experiments showed that the electrochemical stability improves when Al foil has higher purity, lower capacitance, and higher withstand voltage. To improve the electrochemical stability of EDLC current collectors made of low-purity foil (99.4% Al foil), the foil was modified by chemical etching to reduce its capacitance to $60{\mu}F/cm^2$ and forming to have withstand a voltage of 3 Vf. EDLC cells using the modified Al foil as a current collector were made to 2.7 V with 360 F, and a constant voltage load test was subsequently performed for 2500 hours at high temperature under a rated voltage of 2.7 V. The reliability and stability of the EDLC cell improved when the modified Al foil was used as a current collector. To understand the deterioration process of the Al current collector, standard cells made of conventional Al foil under a constant voltage load test were disassembled, and the surface changes of the foil were measured every 500 hours. The Al foil became increasingly corroded, causing the adhesion between the AC coating layer and the Al foil to weaken, and it was confirmed that partial AC coating layer peeling occurred.

Side-NSM composite technique for flexural strengthening of RC beams

  • Hosen, Md. Akter;Jumaat, Mohd Zamin;Saiful Islam, A.B.M.;Salam, Md. Abdus;Kim, Hung Mo
    • Computers and Concrete
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    • 제20권4호
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    • pp.439-448
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    • 2017
  • Reinforced concrete (RC) infrastructures often require strengthening due to error in design, degradation of materials properties after prolong utilization and increases load carrying capacity persuaded by new use of the structures. For this purpose, a newly proposed Side Near Surface Mounted (SNSM) composite technique was used for flexural strengthening of RC beam specimens. Analytical and non-linear finite element modeling (FEM) using ABAQUS were performed to predict the flexural performance of RC specimens strengthened with S-NSM using steel bars as a strengthening reinforcement. RC beams with various SNSM reinforcement ratios were tested for flexural performance using four-point bending under monotonic loading condition. Results showed significantly increase the yield and ultimate strengths up to 140% and 144% respectively and improved failure modes. The flexural response, such as failure load, mode of failure, yield load, ultimate load, deflection, strain, cracks characteristic and ductility of the beams were compared with those predicted results. The strengthened RC beam specimens showed good agreement of predicted flexural behavior with the experimental outcomes.

아라미드 시트와 에너지 소산 장치에 의한 기존 골조의 능력 향상 (Capacity Development of Existing Frame by Aramid Sheet and Energy Dissipation Device)

  • 이현호
    • 한국구조물진단유지관리공학회 논문집
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    • 제19권5호
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    • pp.112-119
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    • 2015
  • 본 논문에서는 기둥이 취약한 골조의 내진성능을 향상시키기 위한 공법을 제안하였다. 이를 위하여 기둥을 아라미드 시트로 횡구속하여 취성적인 특성을 개선하였으며, S형 스트럿을 가지는 강재 댐퍼를 설치하여 에너지 소산 능력을 증진시켰다. 비보강 실험체 및 보강 실험체를 실물크기로 제작하여 수평하중 저항 능력을 평가하였다. 파괴 양상, 강도, 강성 저하 및 에너지 소산 능력 등에서 보강 실험체의 효과를 확인할 수 있었다. 또한 ABAQUS를 이용한 FE 해석으로부터, 대상 실험체의 이력 거동을 예측 및 평가하였다.

E-빔 조사된 폴리머의 전하 분포의 축퇴 과정 (Decay Process of Charge Distribution in E-Beam Irradiated Polymers)

  • 윤주호;최용성;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.329-330
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    • 2007
  • Decay processes of accumulated charge in e-beam irradiated polymers during elevating temperature are observed using pulsed electro-acoustic measurement system. Since the polymeric materials have many superior properties such as light-weight, good mechanical strength, high flexibility and low cost, they are inevitable materials for spacecrafts. In space environment, however, the polymers sometimes have serious damage by irradiation of high energy charged particles. When the polymers of the spacecraft are irradiated by high energy charged particles, some of injected charges accumulate and remain for long time in the bulk of the polymers. Since the bulk charges sometimes cause the degradation or breakdown of the materials, the investigation of the charging and the decay processes in polymeric materials under change of temperature is important to decide an adequate material for the spacecrafts. By measuring the charge behavior in e-beam irradiated polymer, such as polyimide or polystyrene, it is found that the various accumulation and decay patterns are observed in each material. The results seem to be useful and be helpful to progress in the reliability of the polymers for the spacecraft.

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온도 상승시에 전자빔 조사된 폴리머내의 전하 분포의 축퇴 현상 연구 동향 (A Research Trend on Space Charge Analysis in Polymer Irradiated by Electron Beam)

  • 고성민;김남용;김대열;최용성;문종대;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1992-1993
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    • 2007
  • Decay processes of accumulated charge in e-beam irradiated polymers during elevating temperature are observed using pulsed electro-acoustic measurement system. Since the polymeric materials have many superior properties such as light-weight, good mechanical strength, high flexibility and low cost, they are inevitable materials for spacecrafts. In space environment, however, the polymers sometimes have serious damage by irradiation of high energy charged particles. When the polymers of the spacecraft are irradiated by high energy charged particles, some of injected charges accumulate and remain for long time in the bulk of the polymers. Since the bulk charges sometimes cause the degradation or breakdown of the materials, the investigation of the charging and the decay processes in polymeric materials under change of temperature is important to decide an adequate material for the spacecrafts. By measuring the charge behavior in e-beam irradiated polymer, such as polyimide or polystyrene, it is found that the various accumulation and decay patterns are observed in each material. The results seem to be useful and be helpful to progress in the reliability of the polymers for the spacecraft.

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고온초전도 기기를 위한 극저온 액체 중 절연물의 전기적 특성 (Electrical Insulation Characteristics of Insulators in Cryogenic Liquid for a HTS Apparatus)

  • 백승명;곽동순;천현권;최재형;김상현;김현희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.263-264
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    • 2006
  • For practical electrical insulation design of high temperature superconducting (HTS) power apparatuses, knowledge of the dielectric behavior of insulators in cryogenic liquid such as liquid nitrogen ($LN_2$) is essential. So in this paper, we discussed experimental investigations of breakdown and V-t characteristics of several insulators such as Kapton and glass fiber reinforced plastic (GFRP) that are candidates of insulator for HTS apparatus in cryogenic liquid. And we investigated the degradation of these insulation samples after breakdown with the microscope and SEM photograph. Moreover, survival and hazard analysis were performed.

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주쇄에 광분해성 방향족 술포닐옥시이미드기를 함유한 감광성 폴리이미드 (Photosensitive Polyimides Having Aromatic Sulfonyloxyimide Groups in the Main Chain)

  • 오세용;이지영;조성열;정찬문
    • 폴리머
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    • 제24권3호
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    • pp.407-417
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    • 2000
  • 고분자 주쇄에 cyclobutane 또는 페닐과 방향족 술포닐옥시이미드 구조를 갖는 감광성 폴리이미드를 합성하여 광분해 특성에 있어서 고분자의 구조가 미치는 영향을 조사하였다. 폴리이미드는 N-히드록시와 염화 술포닐의 축중합에 의해 제조하였다. 합성된 폴리이미드는 25$0^{\circ}C$까지 열분해가 일어나지 않고 안정하였다. 254nm의 광조사에 따른 폴리이미드의 광분해는 분광학적 측정에 의해 N-O 결합의 절단 또는 이미드 moiety의 계열에 기인되는 것을 알 수 있었다. 본 연구의 폴리이미드는 포지티브형의 광분해성 고분자로의 활용이 가능한 것이 확인되었으며, 특히 pyromellitic diimide moiety를 함유하는 폴리이미드의 포지티브 화상은 높은 감도와 해상도를 나타내었다.

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Effects of a Radiation Crosslinking on a Drawn Microporous HDPE Film with a Nucleating Agent

  • Park, Jong-Seok;Gwon, Sung-Jin;Lim, Youn-Mook;Nho, Young-Chang
    • Macromolecular Research
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    • 제17권8호
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    • pp.580-584
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    • 2009
  • The effects of crystallinity and radiation crosslinking on the physical properties of a microporous high density polyethylene (HDPE) film with Millad3988 as a nucleating agent were investigated. The pores of the HDPE film were affected by the crystallinity. The crystallinity of the HDPE films increased with increasing Millad3988 amount up to 0.1 wt% but decreased with further addition. The mechanical characteristics of the HDPE containing Millad3988 films improved with increasing irradiation dose up to 50 kGy, but decreased at 75 kGy due to severe degradation. The thermal shrinkage behavior of the HDPE films decreased with increasing radiation dose up to 50 kGy. The porosity of the stretched HDPEIMillad3988 films after ${\gamma}$-ray radiation increased with increasing y-ray radiation dose up to 50 kGy. The pores of the irradiated films were formed more easily by a stretching due to the formation of a crosslinked structure.

지르코니아계 용사 코팅층의 Erosion 특성 (Erosion properties of plasma sprayed zirconia Based coatings)

  • 신종한;임상규;임대순
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2001년도 제33회 춘계학술대회 개최
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    • pp.346-353
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    • 2001
  • Zirconia powder containing 3 mol% yttria(3Y-PSZ) with and with out Fe$_2$O$_3$ addition was coated on tile cast iron substrate by plasma spraying method. The erosion experiments were performed at temperatures from $25^{\circ}C$ to $600^{\circ}C$. A gas blast type erosion tester was used to examine erosion behavior of the specimens. The results of 3Y-PSZ coatings showed that tile erosion rate had maximum value at 40$0^{\circ}C$. It coincided with tile results of phase transformation tetragonal phase to monoclinic phase caused by low temperature thermal degradation. The tensile stress relaxation and the micro-hardness improvement significantly influenced on the erosion rate at $600^{\circ}C$. In the case of Fe$_2$O$_3$ added 3Y-PSZ coatings, the erosion rate of tested at $25^{\circ}C$ showed maximum value at 5.0 mol% Fe$_2$O$_3$ added coating. This tendency is caused by the improvement of mechanical properties and the tensile residual stress. The erosion rate at 200'c and 400'L showed significantly decrease by Fe203 addition. This decrease is believed to be the stabilization of the tetragonal phase and the increase of micro-hardness.

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변형률속도 변화에 따른 INCONEL 718 초내열합금의 동적 물성특성 (Dynamic Material Characteristics of Superalloy INCONEL 718 with the Variation of Strain Rates)

  • 송정한;허훈
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 춘계학술대회 논문집
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    • pp.275-278
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    • 2005
  • INCONEL 718, nickel based superalloy, has good formability, high strength, excellent corrosion resistance and mechanical properties at high temperature. Owing to theses attractive properties, it finds use in applications such as combustion system, turbine engines and nuclear reactors. In such applications, components are typically required to be tolerant of high stress impact loading. This may cause material degradation and lead to catastrophic failure during service operation. In order to design optimal structural parts made of INCONEL 718, accurate understanding of material's mechanical properties, dynamic behavior and fracture characteristic as a function of strain rates are required. This paper concerned with the dynamic material properties of the INCONEL 718 for the various strain rates. The dynamic response of the INCONEL 718 at intermediate strain rate is obtained from the high speed tensile test machine test and at the high strain rate is from the split Hopkinson pressure bar test. Based on the experimental results, the effects of strain rate on dynamic flow stress, work hardening characteristics, strain rate sensitivity and elongation to the failure are evaluated. Experimental results from both quasi-static and high strain rate up to the 5000/sec are interpolated in order to construct the Johnson-Cook model as the constitutive relation that should be applied to simulate and design the structural parts made of INCONEL 718.

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