• Title/Summary/Keyword: Defect concentration

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Behavior of Reinforced Earth Retaining Wall for Permitting Reinforcement to Subside with Monitoring (현장계측을 통한 보강재 침하형 보강토 옹벽의 거동특성)

  • Chung, Jin-Hyuck;Oh, Jong-Keun;Lee, Song
    • Journal of the Korean Geotechnical Society
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    • v.25 no.2
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    • pp.5-15
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    • 2009
  • The conventional reinforced earth retaining wall has the connector system to fix the reinforcement and block. However, this system defect may cause the crack of block and the rupture of reinforcement due to the stress concentration near the face of reinforced earth retaining wall. Hence, the new connector system which was able to allow the settlement of reinforcement was developed in this study and a test was carried out in the study area which is divided into the conventional reinforced earth retaining wall and reinforced Earth Retaining Wall driving the settlement. As the results of field monitoring in situ, the ratio of tensile force calculated at maximum value on contiguous portion of front block showed that the settlement type decreased the stress concentration near the face of front block greater than the conventional type.

Synthesis of Semiconducting $KTaO_3$ Thin films

  • Bae, Hyung-Jin;Ku, Jayl;Ahn, Tae-Won;Lee, Won-Seok
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.1265-1268
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    • 2005
  • In this study, the synthesis and semiconducting properties of cation and defect-doped $KTaO_3$ film is reported. $KTaO_3$ is an important material for optoelectronic and tunable microwave applications. It is an incipient ferroelectric with a cubic structure that becomes ferroelectric when doped with Nb. While numerous studies have investigated the thin-film growth of semiconducting perovskites, little is reported about semiconducting $KTaO_3$ thin films. In this work, the films were grown on (001) MgO single crystal substrates using pulsed-laser deposition. Semiconducting behavior is achieved by inducing oxygen vacancies in the $KTaO_3$ lattice via growth in a hydrogen atmosphere. The resistivity of semiconducting $KTaO_3:Ca$ films was as low as 10cm, and n-type semiconducting behavior was indicated. Hall mobility and carrier concentration were $0.27cm^2/Vs$ and $3.21018cm^{-3}$, respectively. Crystallinity and microstructure of the $KTaO_3:Ca$ films were examined using X-ray diffraction and field-emission scanning microscopy.

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Growth of GaAs Crystal by an Improved VGF Apparatus

  • Chul-Won Han;Kwang-Bo Shim;Young-Ju Park;Seung-Chul Park;Suk-Ki Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.1
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    • pp.17-25
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    • 1991
  • The construction details of VGF apparatus with a DM(direct monitoring) furnace for the growth of low defect crystal and characteristics of GaAs crystal grown by this apparatus are described. The average dislocation densities and EL2 concentration of as-grown undoped GaAs along the different solidified fractions exhibit $4{\times}10^{2}-7{\times}10^{3}cm^{-2}$ and $6{\times}10^{14}-4{\times}10^{15}cm^{-3}$, which are less than those observed for liquid encapsulated Czochralski(LEC) or high-pressure vertical gradient freeze(VGF) crystals. These remarkable reduction of the dislocation densities and EL2 concentrations were explained by the lower temperature gradient ($dT/dx-10^{\circ}/cm$) and slower rates of post - growth cooling ($20^{\circ}C/hr:1240-1000^{\circ}C,\;30^{\circ}C/hr:1000-700^{\circ}C$). Also, The Hall mobilities, carrier concentrations show uniform distribution throughtout 80% of the ingot length.

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Residual static strength of cracked concrete-filled circular steel tubular (CFCST) T-joint

  • Cui, M.J.;Shao, Y.B.
    • Steel and Composite Structures
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    • v.18 no.4
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    • pp.1045-1062
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    • 2015
  • Concrete-filled circular t steel tubular joints (CFSTJs) in practice are frequently subjected to fluctuated loadings caused by wind, earthquake and so on. As fatigue crack is sensitive to such cyclic loadings, assessment on performance of CFSTJs with crack-like defect attracts more concerns because both high stress concentration at the brace/chord intersection and welding residual stresses along weld toe cause the materials in the region around the intersection to be more brittle. Once crack initiates and propagates along the weld toe, tri-axial stresses in high gradient around the crack front exist, which may bring brittle fracture failure. Additionally, the stiffness and the load carrying capacity of the CFSTJs with crack may decrease due to the weakened connection at the intersection. To study the behaviour of CFSTJs with initial crack, experimental tests have been carried out on three full-scale CFCST T-joints with same configuration. The three specimens include one uncracked joint and two corresponding cracked joints. Load-displacement and load-deformation curves, failure mode and crack propagation are obtained from the experiment measurement. According to the experimental results, it can be found that he load carrying capacity of the cracked joints is decreased by more than 10% compared with the uncracked joint. The effect of crack depth on the load carrying capacity of CFCST T-joints seems to be slight. The failure mode of the cracked CFCST T-joints represents as plastic yielding rather than brittle fracture through experimental observation.

High Temperature Electrical Conductivity of Perovskite La0.98Sr0.02MnO3 (페로프스카이트 $La_{0.98}Sr_{0.02}MnO_3$의 고온전기특성)

  • 김명철;박순자
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.900-904
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    • 1992
  • High temperature electrical conductivity was measured for perovskite La0.98Sr0.02MnO3 at 200~130$0^{\circ}C$ as a function of Po2 and 1/T. Perovskite La1-xSrxMnO3 system is the typical oxygen electrode in solid oxide fuel cell (SOFC). Acetate precursors were used for the preparation of mixed water solution and the calcined powders were reacted with Na2CO3 flux in order to obtain highly reactive powders of perovskite La0.98Sr0.02MnO3. The relative density was greatly increased above 90% because of the homogeneous sintering. From the conductivity ($\sigma$)-temperature and conductivity-Po2 at constant temperature, the defect structure of La0.98Sr0.02MnO3 was discussed. From the slope of 1n($\sigma$) vs 1/T, the activation energy of 0.069 and 0.108eV were evaluated for above 40$0^{\circ}C$, respectively. From the relationship between $\sigma$ and Po2, it was found that the decomposition of La0.98Sr0.02MnO3 was occurred at 10-15.5 atm(97$0^{\circ}C$) and 10-11 atm(125$0^{\circ}C$). It is supposed that the improvement of p-type conductivity may be leaded by the increase of Mn4+ concentration through the substitution of divalent/monovalent cations for La site in LaMnO3.

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Room Temperature Preparation of Electrolytic Silicon Thin Film as an Anode in Rechargeable Lithium Battery (실리콘 상온 전해 도금 박막 제조 및 전기화학적 특성 평가)

  • Kim, Eun-Ji;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.8-15
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    • 2012
  • Silicon-based thin film was prepared at room temperature by an electrochemical deposition method and a feasibility study was conducted for its use as an anode material in a rechargeable lithium battery. The growth of the electrodeposits was mainly concentrated on the surface defects of the Cu substrate while that growth was trivial on the defect-free surface region. Intentional formation of random defects on the substrate by chemical etching led to uniform formation of deposits throughout the surface. The morphology of the electrodeposits reflected first the roughened surface of the substrate, but it became flattened as the deposition time increased, due primarily to the concentration of reduction current on the convex region of the deposits. The electrodeposits proved to be amorphous and to contain chlorine and carbon, together with silicon, indicating that the electrolyte is captured in the deposits during the fabrication process. The silicon in the deposits readily reacted with lithium, but thick deposits resulted in significant reaction overvoltage. The charge efficiency of oxidation (lithiation) to reduction (delithiation) was higher in the relatively thick deposit. This abnormal behavior needs to clarified in view of the thickness dependence of the internal residual stress and the relaxation tendency of the reaction-induced stress due to the porous structure of the deposits and the deposit components other than silicon.

Fast and Low Temperature Deposition of Polycrystalline Silicon Films by Hot Wire CVD (Hot Wire CVD를 이용한 다결정 Si 박막의 고속 저온 증착)

  • Lee, Jeong-Chul;Kang, Ki-Whan;Kim, Seok-Ki;Yoon, Kyung-Hoon;Song, Jin-Soo;Park, I-Jun
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1427-1429
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    • 2001
  • Polycrystalline silicon(poly-Si) films are deposited on low temperature glass substrate by Hot-Wire CVD(HWCVD). The structural properties of the poly-Si films are strongly dependent on the wire temperature($T_w$). The films deposited at high $T_w$ of 2000$^{\circ}C$ have superior crystalline properties; average lateral grain sizes are larger than $1{\mu}m$ and there at·e no vertical grain boundaries. The surface of the high $T_w$ samples are naturally textured like pyramid shape. These large grain size and textured surface are believed to give high current density when applied to solar cells. However, the poly-si films are structurally porous and contains high defect density, by which high concentration of C and O resulted within the films by air-penetration after removed from chamber.

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Poly-Si Thin Film Solar Cells by Hot-wire CVD

  • Lee, J.C.;Chung, Y.S.;Kim, S.K.;Yoon, K.H.;Song, J.S.;Park, I.J.;Kwon, S.W.;Lim, K.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1034-1037
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    • 2003
  • Microcrystalline silicon(c-Si:H) thin-film solar cells are prepared with intrinsic Si-layer by hot wire CVD. The operating parameters of solar cells are strongly affected by the filament temperature ($T_f$) during intrinsic layer. Jsc and efficiency abruptly decreases with elevated $T_f$ to $1400^{\circ}C$. This deterioration of solar cell parameters are resulted from increase of crystalline volume fraction and corresponding defect density at high $T_f$. The heater temperature ($T_h$) are also critical parameter that controls device operations. Solar cells prepared at low $T_h$ ($<200^{\circ}C$) shows a similar operating properties with devices prepared at high $T_f$, i.e. low Jsc, Voc and efficiency. The origins for this result, however, are different with that of inferior device performances at high $T_f$. In addition the phase transition of the silicon films occurs at different silane concentration (SC) by varying filament temperature, by which highest efficiency with SC varies with $T_f$.

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Investigation of the Carrier Lifetime of Cz-Si after Light Induced Degradation (빛에 의한 Cz 실리콘 기판의 carrier lifetime 감소에 대한 연구)

  • Lee, Ji-Youn;Lee, Soo-Hong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.985-988
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    • 2004
  • The carrier lifetime of boron doped Cz silicon samples after light induced degradation could be improved by optimized rapid thermal processing (RTP). The important five different parameters varied in order to investigate which parameter is important for the stable lifetime after light induced degradation, $\tau_d$. The Plateau temperature and the Plateau time influenced on the lifetime after light induced degradation. Especially, the Plateau temperature showed a strong influence on the stable lifetime. The optimal plateau temperature is approximately $900^{\circ}C$ t for a plateau time of 120 s. The stable lifetime increased from $15\mu}s$ to $25.5{\mu}s$. The normalized defect concentration, $N_t^*$, decreased from $0.06{\mu}s^{-1}$ to $0.037{\mu}s^{-1}$ by RTP-process.

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Prediction of Fatigue Life using Extreme Statistics Analysis (표면미소균열의 극치통계해석을 이용한 피로수명예측)

  • Lee, Dong-U;Hong, Sun-Hyeok;Jo, Seok-Su;Ju, Won-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.9
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    • pp.1746-1752
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    • 2002
  • Fatigue fracture in machine components is produced by surface micro-crack from stress concentration area such as notch and material defect. It is difficult to predict the remaining fatigue lift of mechanical components because the surface micro-crack on critical area initiates and grows with statistical distribution. Plane bending fatigue tests were carried out on the plain specimen of Al 2024-T3 and the initiation and growth behavior of surface micro cracks were observed. The statistical distribution of surface length of multiple micro cracks and their maximum length were investigated. The maximum surface crack length distributions were analyzed on the basis of the statistics of extremes in order to examine the prediction of remaining life.