• 한국세라믹학회지
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• 제48권2호
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• pp.173-177
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• 2011

Decomposition promoting factors and decomposition mechanism in the zinc decomposition process of waste hard metals which are composed mostly of tungsten carbide and cobalt were evaluated. Zinc volatility amount was suppressed and zinc valatilization pressure was produced in the reaction graphite crucible inside an electric furnace for ZDP. Reaction was done for 2 h at $650^{\circ}C$, which 100 % decomposed the waste hard metals that were over 30 mm thick. As for the separation-decomposition of waste hard metals, zinc melted alloy formed a liquid composed of a mixture of ${\gamma}-{\beta}1$ phase from the cobalt binder layer (reaction interface). The volume of reacted zone was expanded and the waste hard metal layer was decomposed-separated horizontally from the hard metal. Zinc used in the ZDP process was almost completely removed-collected by decantation and volatilization-collection process at $1000^{\circ}C$.

• 한국식품과학회지
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• 제17권2호
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• pp.71-74
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• 1985

식용 콩기름의 가열산화과정 초기에 형성되는 가장 중요한 중간생성체인 하이드로퍼로키사이드(hydroperoxide)의 생성기구대신 분해기구의 한 모델을 설정하였다. $100^{\circ}C,\;120^{\circ}C,\;150^{\circ}C$와 $180^{\circ}C$에서 120 ml/min의 공기주입하에 가열산화된 콩기름시료의 하이드로퍼로키사이드외 분해속도를 실험을 통하여 측정하고 위의 분해기구에 적용하여 분석, 검토하였다. 이상의 분석결과 하이드로퍼로키사이드 분해반응의 반응속도차수는 1차적이었음을 알 수 있었다. 또한 이상의 분해속도 측청치에서 산출한 하이드로퍼로키사이드의 해리에너지는 15.876 Kcal/g mol이었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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• pp.157-159
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• 2015

In this study, $CF_4$ decomposition was experimentally investigated in a high temperature flow reactor. Effects of temperature, reactant composition and concentration, and residence time on its decomposition into other stable species were analyzed. Then the results were compared to numerical results obtained using Chemkin Plug Flow Reactor model with Princeton Chemistry. As a preliminary result higher decomposition rate is obtained for higher reactor temperature and long residence time when proper reactants are supplied.

• 한국추진공학회지
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• 제3권4호
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• pp.23-30
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• 1999

상안정화 질산암모늄(PSAN)의 열분해 특성에 대한 연구를 thermogravimetric analysis(TGA)를 사용하여 수행하였다. 본 연구에서는 질산칼륨과 산화아연이 상안정화제로 0%에서 8%사이에서 사용되었다. 열분해에 대한 속도론적 특성과 메카니즘들을 적분법을 사용하여 평가하였다. 활성화에너지(E)와 잦음율인자(A) 같은 열적 속도계수들은 상안정화제의 함량이 증가함에 따라 증가하였고, 분해 메카니즘 또한 변화되었다.

• 폴리머
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• 제25권6호
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• pp.866-875
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• 2001

본 연구에서는 고온 산화분위기 하에서 탄소/탄소 복합재료의 열적 향상을 위해 사용된 tetraethylorthosilicate(TEOS)의 첨가량에 따른 복합재료의 kinetic parameter에 기초한 열분해 메카니즘 및 열안정성을 열중량분석기(TGA)를 사용하여 고찰하였다 TEOS를 함유한 탄소/탄소 복합재료의 kinetic parameter, 즉 열분해 활성화 에너지 ($E_d$), 반응차수(n), 지수앞 인자 (A)는 각각 136 kJ/mol, 0차, 및 2.3$\times$$10^9s^{-1}$을 나타내었으며, 특히 IPDT 및 $E_d$로부터 살펴본 복합재료의 열안정성은 탄소/탄소 복합재료에 TEOS가 첨가되면 크게 향상되었는데, 이는 산소에 대한 산화방지막, 즉 $SiO_2$의 형성으로 인한 복합재료 표면에서의 카본 활성종에 산소의 침투를 방해하여 TEOS를 함유한 복합재료가 이를 함유하지 않은 것에 비하여 표면 산화 속도가 감소되어 열안정성이 증가하였다고 사료된다.

• 대한화학회지
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• 제37권2호
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• pp.199-205
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• 1993

구리-아민류착물에 의한 과산화수소의 초기분해속도를 pH7.3~11.8 범위에서 측정하였다. 과산화수소의 분해속도는 pH에 따라 증가하였다가 감소하였다. 이들 실험결과에 일치하는 가능한 메카니즘이 제안되었다. 이 메카니즘은 과산화수소와 구리-아민류착물의 탈양성첨가를 거친 다음에 속도 결정단계에서 퍼옥소구리착물이 생성되는 반응과정과 일치한다.

• 한국산업융합학회 논문집
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• 제4권1호
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• pp.87-94
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• 2001

In multibody dynamics, differential and algebraic equations which can satisfy both equation of motion and kinematic constraint equation should be solved. To solve this equation, coordinate partitioning method and constraint stabilization method are commonly used. The coordinate partitioning method divides the coordinate into independent and dependent coordinates. The most typical coordinate partitioning method arc LU decomposition, QR decomposition, projection method and SVD(sigular value decomposition).The objective of this research is to find a efficient coordinate partitioning method in flexible multibody systems and a hybrid decomposition algorithm which employs both LU and projection methods is proposed. The accuracy of the solution algorithm is checked with a slider-crank mechanism.

• Bulletin of the Korean Chemical Society
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• 제33권8호
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• pp.2483-2488
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• 2012

The X-ray line broadening technique was used to calculate the grain size of MgO at 1023, 1123, 1223 K respectively either in $CO_2$ or during the thermal decomposition of magnesites in air as well as in vacuum. By referring to the conventional grain growth equation, $D^n=kt$, the activation energy and pre-exponential factor for the process in air are gained as 125.8 kJ/mol and $1.56{\times}10^8\;nm^4/s$, respectively. Ranman spectroscopy was employed to study the surface structure of MgO obtained during calcination of magnesite, by which the mechanism of grain growth was analyzed and discussed. It is suggested that a kind of highly reactive MgO is produced during the thermal decomposition of magnesites, which is exactly the reason why the activation energy of the grain growth during the thermal decomposition of magnesite is lower than that of bulk diffusion or surface diffusion.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2385-2391
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• 2018

This paper is devoted to detecting decomposition characteristics of Iodotrifluoromethane ($CF_3I$) under alternating current (AC) discharges or load current interruptions. The decomposition products are measured utilizing chromatography-mass spectroscopy. It is found that less than 1% $CF_3I$ gas decomposed after several interruptions at load current of 200 A or hundred times of AC discharges. However, under interruptions at a current of 400 A, more than 95% $CF_3I$ gas decomposed into carbon tetrafluoride ($CF_4$) and hexafluoroethane ($C_2F_6$). The equilibrium compositions based on Gibbs free energy minimization of $CF_3I$ was calculated to explain the decomposition mechanism.

• Tribology and Lubricants
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• 제18권6호
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• pp.396-401
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• 2002

ln this paper, the fuction of molybdenum dialkyl dithiophosphate (MoDTP) as an oxidation inhibitor of mineral oils was investigated and compared with 2,6-Di-tert-Butyl-4-Methylphenol (DBMP). Oxidation tests were conducted using an oxygen absorption apparatus. MoDTP showed anti-oxidation property, and length of induction time prolonged by increasing MoDTP concentration. However the induction time of DBMP was longer than those of MoDTP. The anti-oxidation property of MoDTP was found to be inferior to that of DBMP The capability of hydroperoxide decomposition ability with MoDTP was much greater than that with DBMP. However the rate constant of radical scavenging with MoDTP was much better than that with DBMP. It was found that the performance of MoDTP is exellent with respect to hydroperoxide decomposition but it is susceptible to chemical decomposition. From the fact that formation of phenol was observed when MoDTP was added to hexane solution of cumene hydroperoxide (CHPO), it is indicated that the decomposition of hydroperoxide with MoDTP occurs by means of ionic mechanism.