• Title/Summary/Keyword: Decomposition behaviors

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Overload Analysis and Fatigue Life Prediction Using an Effective J-Integral of Spot Welded Specimens (점용접시편의 과부하해석 및 유효 J-적분에 의한 피로수명예측)

  • Lee, Hyeong-Il;Choe, Jin-Yong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.567-580
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    • 2000
  • This paper proposes an integrated approach, which is independent of specimen geometry and loading type, for predicting the fatigue life of spot welded specimens. We first establish finite element models reflecting the actual specimen behaviors observed on the experimental load-deflection curves of 4 types of single spot welded specimens. Using finite element models elaborately established, we then evaluate fracture parameter J-integral to describe the effects of specimen geometry and loading type on the fatigue life in a comprehensive manner. It is confirmed, however, that J-integral concept alone is insufficient to clearly explain the generalized relationship between load and fatigue life of spot welded specimens. On this ground, we introduce another effective parameter $J_e$ composed of $J_I$, $J_{II}$, $J_{III}$, which has been demonstrated here to more sharply define the relationship between load and fatigue life of 4 types of spot welded specimens. The crack surface displacement method is adopted for decomposition of J, and the mechanism of the mixed mode fracture is also discussed in detail as a motivation of using $J_e$.

Characteristic behaviors of ozone decomposition and oxidation of pharmaceuticals during ozonation of surface waters in Ulsan (울산시 상수원수에서의 오존분해 특성 및 의약물질 분해 거동 연구)

  • Lee, Hye-Jin;Lee, Hongshin;Lee, Changha
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.39-47
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    • 2013
  • This study demonstrates the oxidative degradation of pharmaceutical compounds during ozonation of surface waters in Ulsan. Diclofenac, carbamazepine, bezafibrate, and ibuprofen were selected as surrogate pharmaceutical compounds, and ozonation experiments were performed using raw waters collected from the Sayeon Dam and the Hoeya Dam in Ulsan. Diclofenac and carbamazepine which have high reactivity with molecular ozone showed higher removal efficiencies than bezafibrate and ibuprofen during ozonation. The addition of tert-butanol, a hydroxyl radical scavenger, increased the removal efficiencies of diclofenac and carbamazepine by increasing the ozone exposure. However, the oxidation of bezafibrate and ibuprofen was inhibited by the presence of tert-butanol due to the suppression of the exposure to hydroxyl radical. The elimination of the selected pharmaceuticals could be successfully predicted by the kinetic model base on the $R_{ct}$ concept. Depending on the experimental condition, $R_{ct}$ values were determined to be $(1.54{\sim}3.32){\times}10^{-7}$ and $(1.19{\sim}3.04){\times}10^{-7}$ for the Sayeon Dam and the Hoeya Dam waters, respectively. Relatively high $R_{ct}$ values indicate that the conversion of $O_3$ into $^{\cdot}OH$ is more pronounced for surface waters in Ulsan compared to other water sources.

Decomposition of volatile aromatic compounds by photochemical treatment (광화학적 방법을 이용한 휘발성 방향족 화합물의 분해)

  • Kim, Jong Hyang
    • Clean Technology
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    • v.4 no.1
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    • pp.35-44
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    • 1998
  • Photodecomposition behaviors of volatile organic compounds (VOCs ; benzene, toluene, ethylbenzene and xylenes) over UV irradiation and UV irradiation with $TiO_2$ powder catalyst were studied and the extent of degradation were also investigated under various reaction conditions. The reactions were conducted in a quartz annular reactor equipped with a medium pressure mercury lamp. As a result, the extents of degradation were 92% for toluene and ethylbenzene, 83% for benzene, and 82% for xylenes under UV irradiation. And they were 92% for toluene, 82% for xylene and ethylbenzene, and 53% for benzene under UV irradiation with $TiO_2$ powder. Analyses of reacted samples by FID-gas chromatograph with Purge & Trap concentrator and GC-MS indicated that the aromatics formed many intermediates.

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Elasto-Plastic Finite Element Analysis in Consideration of Phase Transformations (상변태를 고려한 탄소성 유한요소 해석)

  • Lee, M.G.;Kim, S.J.;Jeong, W.C.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.334-336
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    • 2009
  • An elastic-plasticity model during the austenitic decomposition was derived and implemented to incorporate the two important deformation behaviors observed during the phase transformations: the volumetric strain and transformation induced plasticity due to the temperature change and phase transformation. To obtain transformed phase volume fractions during cooling, the fourth order Runge-Kutta method was used to solve the Kirkaldy's phase kinetics model which is function of temperature, austenitic grain size and chemical composition. The volumetric strain was calculated by considering the densities of constituent phases, while the transformation induced plasticity was based on the micro-plasticity due to the volume mismatch between soft austenitic phase and other harder phases. The constitutive equations were implemented into the implicit finite element software and a simple boundary value problem was chosen as a model problem to validate the effect of transformation plasticity on the deformation behavior of steel under cooling from high temperature. It was preliminary concluded that the transformation plasticity plays a critical role in relaxing the developed stress during forming and thus reducing the magnitude of springback.

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Oxidation Behaviors of SiCf/SiC Composites Tested at High Temperature in Air by an Ablation Method

  • Park, Ji Yeon;Kim, Daejong;Lee, Hyeon-Geun;Kim, Weon-Ju;Pouchon, Manuel
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.498-503
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    • 2018
  • Using the thermal ablation method, the oxidation behavior of $SiC_f/SiC$ composites was investigated in air and in the temperature range of $1,300^{\circ}C$ to $2,000^{\circ}C$. At the relatively low temperature of $1,300^{\circ}C$, passive oxidation, which formed amorphous phase, predominantly occurred in the thermal ablation test. When the oxidation temperature increased, SiO (g) and CO (g) were formed by active oxidation and the dense oxide layer changed to a porous one by vaporization of gas phases. In the higher temperature oxidation test, both active oxidation due to $SiO_2$ decomposition on the surface of the oxide layer and active/passive oxidation transition due to interfacial reaction between oxide and base materials such as SiC fiber and matrix phase simultaneously occurred. This was another cause of high temperature degradation of $SiC_f/SiC$ composites.

Analytic solution of Timoshenko beam excited by real seismic support motions

  • Kim, Yong-Woo
    • Structural Engineering and Mechanics
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    • v.62 no.2
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    • pp.247-258
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    • 2017
  • Beam-like structures such as bridge, high building and tower, pipes, flexible connecting rods and some robotic manipulators are often excited by support motions. These structures are important in machines and structures. So, this study proposes an analytic method to accurately predict the dynamic behaviors of the structures during support motions or an earthquake. Using Timoshenko beam theory which is valid even for non-slender beams and for high-frequency responses, the analytic responses of fixed-fixed beams subjected to a real seismic motions at supports are illustrated to show the principled approach to the proposed method. The responses of a slender beam obtained by using Timoshenko beam theory are compared with the solutions based on Euler-Bernoulli beam theory to validate the correctness of the proposed method. The dynamic analysis for the fixed-fixed beam subjected to support motions gives useful information to develop an understanding of the structural behavior of the beam. The bending moment and the shear force of a slender beam are governed by dynamic components while those of a stocky beam are governed by static components. Especially, the maximal magnitudes of the bending moment and the shear force of the thick beam are proportional to the difference of support displacements and they are influenced by the seismic wave velocity.

Roles of Fundamental and Additional Hardening Precipitates on the Changes of Mechanical Properties and Electrical Resistivity in Al-Li Alloys Containing Cu and Mg (Cu, Mg을 함유한 Al-Li 합금의 기계적 성질과 전기저항 변화에 미치는 기본 및 추가 강화상들의 역할)

  • Chung, D.S.;Song, K.H.;Woo, K.D.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.77-87
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    • 1994
  • Roles of fundamental and additional hardening precipitates on the changes of mechanical properties and electrical resistivity during precipitation decomposition in binary Al-Li, ternaty Al-Li-Cu and multi-Li-Cu-Mg-Zr alloys have been investigated by the detailed measurement of electrical resistivity, hardness and tensile strength and the observation of transmission electron micrographs. Peek hardness and tensile strength in multi-component Al-Li-Cu-Mg-Zr Alloy had higher than that of the other alloys and the results of measurement of hardness, strength and electrical resistivity in each alloys aged at 90 and $190^{\circ}C$, precipitation behaviors and mechanical properties in binary, ternary and multi-component Al-Li alloys were contributed to the ${\delta}^{\prime}$ precursory phase of ${\delta}^{\prime}$, $T_1$, G.P.B. zone and S' phases, repectively.

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Statistical Analysis of the MSE for the MDPSAP Adaptive Filter (MPDSAP 적응필터를 위한 MSE의 통계적 해석)

  • Kim, Young-min;Choi, Hun
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.883-887
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    • 2009
  • This paper presents a statistical analysis of the MSE of adaptation for the MPDSAP (Maximally polyphase decomposed Subband Affine Projection) algorithm for the an autoregressive (AR) inputs with P order. In subband structure, the Affine Projection (AP) algorithm is transformed to the Normalized Least Mean Square (NLMS) algorithm by applying the polyphase decomposition and the noble identity to the adaptive filter. And also, AR input can be pre-whitened by subband filtering with the Orthonormal Analysis Filters(OAF). In the subband structure, the pre-whitening of the AR(P) inputs provides simple and valid approximations for a statistical analysis of the MSE behaviors for the SAP adaptive filter.

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Long Term Affecting Factors on Major Water Quality Items of Landfill Leachate (매립장 침출수 주요 수질항목에 대한 장기 영향요소)

  • Chun, Seung-Kyu;Kim, Min Hyuk;Won, Jong Chul
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.24-33
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    • 2021
  • Analysis of long term affecting factors on water quality items of gas emission form (BOD, COD) and leachate emission form (T-N, non-bio-degradable COD (NBDCOD)) was performed for the SUDOKWON 1st Landfill Site (LS1) and 2nd Landfill Site (LS2). As landfill gas was generated, BOD and COD decreased from 6,887 and 20,025 mg/L in 1993 to 49.5 and 670.2 mg/L in 2019, respectively. TN and NBDCOD increased with waste decomposition but gradually decreased after landfill closure because of the precipitation infiltration effect. Due to the drastic decline of carbon in the leachate, the BOD/TN ratios of LS1 and LS2 declined from 13.0 and 17.0 during early stage of the landfill to 0.07 and 0.16 in 2019, respectively; LS2 and NBDCOD/COD increased from 0.25 to 0.65 during the same period. These conditions caused carbon deficiency in denitrification treatment and a chemical post-treatment request for NBDCOD. The different behaviors of gas emission and leachate emission items suggest the necessity of different strategic approaches in the long term perspective.

Low Temperature Interface Modification: Electrochemical Dissolution Mechanism of Typical Iron and Nickel Base Alloys

  • Jiangwei Lu;Zhengyang Xu;Tianyu Geng
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.220-241
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    • 2024
  • Due to its unique advantages, electrochemical machining (ECM) is playing an increasingly significant role in the manufacture of difficult-to-machine materials. Most of the current ECM research is conducted at room temperature, with studies on ECM in a cryogenic environment not having been reported to date. This study is focused on the electrochemical dissolution characteristics of typical iron and nickel base alloys in NaNO3 solution at low temperature (-10℃). The polarization behaviors and passive film properties were studied by various electrochemical test methods. The results indicated that a higher voltage is required for decomposition and more pronounced pitting of their structures occurs in the passive zone in a cryogenic environment. A more in-depth study of the composition and structure of the passive films by X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy showed that the passive films of the alloys are modified at low temperature, and their capacitance characteristics are more prominent, which makes corrosion of the alloys more likely to occur uniformly. These modified passive films have a huge impact on the surface morphologies of the alloys, with non-uniform corrosion suppressed and an improvement in their surface finish, indicating that lowering the temperature improves the localization of ECM. Together with the cryogenic impact of electron energy state compression, the accuracy of ECM can be further improved.