• 제목/요약/키워드: Decomposition Products

검색결과 380건 처리시간 0.025초

Decomposition and Super-efficiency in the Korean Life Insurance Industry Employing DEA

  • Lee, Hyung-Suk;Kim, Ki-Seog
    • International Journal of Contents
    • /
    • 제4권3호
    • /
    • pp.1-9
    • /
    • 2008
  • The Korean life insurance industry has undergone profound changes, such as the beginning of the variable insurance in July 2001 and the bancassurance enforcement in August 2003. However, little empirical research has analyzed data that includes the bancassurance of life insurance companies operating in Korea. In response to this lack of research, this paper applies DEA (data envelopment analysis) models to measure and decompose their efficiency. We discovered that life insurance companies operating in Korea are a little different in their composition ratio of inputs and outputs, due to the increased variety of distribution channels and new products. We provided efficiency scores, return to scale, and reference frequencies. We also decomposed CCR, BCC, and SBM efficiency into scale efficiency and MIX efficiency. So, we try to investigate whether the sources of inefficiency were caused by the inefficient operation of DMU, disadvantageous conditions, the difference of the composition ratio in inputs and outputs with reference sets, or any combination of the above. Most companies in the sample display had either constant or decreasing returns to scale. The efficiency rankings were less consistent among models and efficient DMUs. In response to this problem, we used the super-efficiency model to rank them and then compared the rankings of the DMUs among the various models. It was also concluded that the availability of panel data, rather than cross-sectional data, would greatly improve the validity of the efficiency estimates.

리빙 음이온 중합법에 의한 SIS Triblock 공중합체의 제조 및 유류 고형화 특성 (Synthesis of SIS Triblock Copolymer by Living Anionic Polymerization and Its Oil Gelling Capacity)

  • 허재준;이민규;김시영;주창식
    • 한국환경과학회지
    • /
    • 제15권6호
    • /
    • pp.593-600
    • /
    • 2006
  • SIS triblock copolymers, one of the major raw materials of oil gelling agent, were synthesized by living anionic polymerization and the resultant copolymers formed with various shapes and sizes were used to examine their oil gelling capacities. Coupling method was adapted to form final triblock products from diblock living polymers. Prior to polymerization, the impurities in monomers and solvents were throughly removed by killing technique. We experimentally investigated the effects of operating parameters of synthesis and forming of SIS triblock copolymers on oil gelling capacity. The photocatalytic decomposition of SIS triblock copolymer under ultraviolet circumstance was also investigated and it is found that the addition of P-25 enhances the photocatalytic decomposition.

Oxalate 공침법에 의한 $\beta$-Alumina 합성과 결정화 거동 (Synthesis of $\beta$-Alumina By Oxalate Coprecipitation Method and Its Crystallization Behavior)

  • 박용민;양유철;김형욱;박성수;손영국
    • 한국세라믹학회지
    • /
    • 제32권4호
    • /
    • pp.455-461
    • /
    • 1995
  • To investigate the synthesis of $\beta$-Al2O3 and its crystallization behavior by oxalate coprecipitation method, the optimum pH range for oxalate coprecipitates has been theoretically calculated from the solubility products and the equilibrium constans of each metal ionic species and their solubility diagram wa obtained. The optimum pH range for oxalate coprecipitates at room temperature was estimated as <4. In experiment, we found that the optimum condition for oxalate coprecipitates was pH<1, which was not doped with pH controller. The Na+ ions were easily exchanged for the NH4+ ions of NH4OH which was used as pH controller, and those NH4+ ions were supposed to affect the crystallization behavior of $\beta$-Al2O3. The thermal decomposition of all complexes was almost complete below 40$0^{\circ}C$. The primary product of the decomposition process was m-Al2O3, which transformed to $\beta$"- or $\beta$-Al2O3 at temperature higher than 100$0^{\circ}C$. We found that the powder prepared at 120$0^{\circ}C$ had only $\beta$"- and $\beta$-Al2O3.EX>-Al2O3.

  • PDF

파, 부추 및 고들빼기김치 숙성 중의 Chlorophyll 및 그 유도체의 함량변화 (Changes of Chlorophylls and their Derivatives Contents during Storage of Green Onion, Leek and Godulbaegi Kimchi)

  • 이종호;김경업;김성희;정효숙;유영법
    • 한국식품영양과학회지
    • /
    • 제27권6호
    • /
    • pp.1071-1076
    • /
    • 1998
  • Threetypes of Korean traditional kimchi were prepared using green onion, leek or godulbaegi as raw materials and stored at 5oC and 20oC for 13 days. Changes in salt and ascorbic acid contents, pH and total acidity as well as the relationship of the decomposition of chlorophylls and the production of their derivatives were investigated. For the all kimchi samples tested, salt content was not significantly changed during storage at both temperatures, whereas pH and total acidity were decreased and increased, respectively. Especially their remarkable changes were shown at the third day of storage. Ascorbic acid content was remained at high level in the leek kimchi for the experimental period at both storage temperatures, meanwhile godulbaegi kimchi retained the least amount of ascorbic acid. Chlorophylls were decomposed to pheophytin and pheophorbide during storage at both storage temperatures, and this phenomenon was apparent at the third day of storage. Reduction of chlorophylls and increasements of its decomposed products such as pheophytin and pheophorbide were the least in leek kimchi and the greatest in godulbaegi kimchi during storage at both temperatures. These results indicate that decomposition of chlorophylls in kimchi and increasements of pheophytin and pheophorbide were closely related to the ascorbic acid content in kimchi.

  • PDF

기능성 복합 라텍스의 합성과 열분해 특성에 관한 연구 (A Study on Synthesis of Functional Composite Latex and Characteristics of Thermal Decomposition)

  • 권재범;김남석;이내우;설수덕
    • 한국안전학회지
    • /
    • 제19권2호
    • /
    • pp.47-53
    • /
    • 2004
  • Emulsion polymerization ws carried out using Alkyl methacrylate(RMA) like MMA, EMA, BMA and Styrene Monomer(SM) for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS(Sodium Lauryl Sulfate). FT-IR and DSC analysis are used to confirm the synthesized core-shell emulsion latexes. Moreover DSC and TGA were used to investigate the thermal characterisitcs of them. The differences of the decomposition rate and the activation energy from TGA and DSC analysis are not so big. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene. For investigating combustion products, LC50 values were calculated by FED(Fractional Effective Dose)from the Pyrolyzer-Mass sepctrometer.

SiC-Al2O3 촉매를 이용한 CF4의 마이크로파 열분해 (Microwave Thermal Decomposition of CF4 using SiC-Al2O3)

  • 최성우
    • 한국환경과학회지
    • /
    • 제22권9호
    • /
    • pp.1097-1103
    • /
    • 2013
  • Tetrafluoromethane($CF_4$) have been widely used as etching and chemical vapor deposition gases for semiconductor manufacturing processes. $CF_4$ decomposition efficiency using microwave system was carried out as a function of the microwave power, the reaction temperature, and the quantity of $Al_2O_3$ addition. High reaction temperature and addition of $Al_2O_3$ increased the $CF_4$ removal efficiencies and the $CO_2/CF_4$ ratio. When the SA30 (SiC+30wt%$Al_2O_3$) and SA50 (SiC+50wt%$Al_2O_3$) were used, complete $CF_4$ removal was achieved at $1000^{\circ}C$. The $CF_4$ was reacted with $Al_2O_3$ and by-products such as $CO_2/CF_4$ and $AlF_3$ were produced. Significant amount of by-product such as $AlF_3$ was identified by X-ray powder diffraction analysis. It also showed that the ${\gamma}-Al_2O_3$ was transformed to ${\alpha}-Al_2O_3$ after microwave thermal reaction.

Fast Hybrid Transform: DCT-II/DFT/HWT

  • 쉬단핑;신태철;단위;이문호
    • 방송공학회논문지
    • /
    • 제16권5호
    • /
    • pp.782-792
    • /
    • 2011
  • In this paper, we address a new fast DCT-II/DFT/HWT hybrid transform architecture for digital video and fusion mobile handsets based on Jacket-like sparse matrix decomposition. This fast hybrid architecture is consist of source coding standard as MPEG-4, JPEG 2000 and digital filtering discrete Fourier transform, and has two operations: one is block-wise inverse Jacket matrix (BIJM) for DCT-II, and the other is element-wise inverse Jacket matrix (EIJM) for DFT/HWT. They have similar recursive computational fashion, which mean all of them can be decomposed to Kronecker products of an identity Hadamard matrix and a successively lower order sparse matrix. Based on this trait, we can develop a single chip of fast hybrid algorithm architecture for intelligent mobile handsets.

티안트렌 양이온 자유라디칼 과염소산염과 큐멘과산화수소의 반응 (Reaction of Thianthrene Cation Radical Perchlorate with Cumene Hydroperoxides)

  • 신종헌;김경태
    • 대한화학회지
    • /
    • 제27권2호
    • /
    • pp.142-149
    • /
    • 1983
  • 아세토니트릴용액중의 티안트렌 양이온 라디칼 과염소산 염(1)은 Cumene hydroperoxide(4), p-chlorocumene hydroperoxide(2), p-nitrocumene hydroperoxide(3)와 상온에서 반응한다. 이 반응의 공통 생성물로서 티안트렌을 얻었으며 4로 부터 5-(4'-hydroxyphenyl) thianthrenium perchlorate (5), 2로부터 5-(5'-chloro-2'-hydroxyphenyl) thianthrenium perchlorate (7)와 5-acetonylthianthrenium perchlorate (6), 그리고 3으로부터 6만을 얻었다. 이 반응의 양관계는 1의 2몰이 티안트렌 1몰과 티안트렌이움 염(또는 염들) 1몰을 생성한다. 1에 대한 친핵성 활성도는 페놀 > > p-클로로페놀 ${\sim}$아세톤 > > p-니트로페놀 순서임이 밝혀졌다. Hydroperoxide의 산촉매 불균일 분해반응외에도 소량의 균일분해 반응생성물이 3과 4로부터 생성됨을 알았다.

  • PDF

$BaTiO_3$고상반응 합성시 분해 반응의 고찰 (A Study on Decomposition in Synthesis of $BaTiO_3$ by Soild-solid Reaction)

  • 김종옥;임대영
    • 자연과학논문집
    • /
    • 제4권
    • /
    • pp.85-93
    • /
    • 1991
  • $BaCO_3$$TiO_2$ 등 mole비 혼합물의 고상반응은 $BaCO_3 + TiO_2\longrightarrow$ $BaTiO_3 + CO_2$의 반응식에 따라 $CO_2$ gas가 발생된다. 이 분해과정을 DTA-TG를 사용하여 속도론적으로 고찰하였다. 그 결과는 다음과 같다. 1. $TiO_2$와 공존하는 $BaCO_3$는 순수한 $BaCO_3$보다 낮은 온도에서 분해된다. 그 이유는 생성물의 free energy가 감소되기 때문이다. 2. $BaCO_3$ 분해과정의 속도론적 고찰에 사용되는 식은 Jander's식보다는 Carter's식이 더욱 의미가 있으며 Carter's식에 의해 구해진 분해 활성화 에너지는 42.8Kcal/mol이다.

Stabilizing Li2O-based Cathode/Electrolyte Interfaces through Succinonitrile Addition

  • Myeong Jun Joo;Yong Joon Park
    • Journal of Electrochemical Science and Technology
    • /
    • 제14권3호
    • /
    • pp.231-242
    • /
    • 2023
  • Li2O-based cathodes utilizing oxide-peroxide conversion are innovative next-generation cathodes that have the potential to surpass the capacity of current commercial cathodes. However, these cathodes are exposed to severe cathode-electrolyte side reactions owing to the formation of highly reactive superoxides (Ox-, 1 ≤ x < 2) from O2- ions in the Li2O structure during charging. Succinonitrile (SN) has been used as a stabilizer at the cathode/electrolyte interface to mitigate cathode-electrolyte side reactions. SN forms a protective layer through decomposition during cycling, potentially reducing unwanted side reactions at the interface. In this study, a composite of Li2O and Ni-embedded reduced graphene oxide (LNGO) was used as the Li2O-based cathode. The addition of SN effectively thinned the interfacial layer formed during cycling. The presence of a N-derived layer resulting from the decomposition of SN was observed after cycling, potentially suppressing the formation of undesirable reaction products and the growth of the interfacial layer. The cell with the SN additive exhibited an enhanced electrochemical performance, including increased usable capacity and improved cyclic performance. The results confirm that incorporating the SN additive effectively stabilizes the cathode-electrolyte interface in Li2O-based cathodes.