• Elastomers and Composites
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• 제19권1호
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• pp.13-31
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• 1984

The purposes of this dissertation are to demonstrate that DSC theromoanaytical methods of vulcanization can provide useful informations on the vulcanization characteristics of industrial formulations and also provides the potential basis for a rapid and complete method of sulfur and vulcanizing accelerator analysis for quality control. The influences of those factors such as heating rate, scan temperature, vucanizing accelerator's type and concentration upon vulcanization exotherm in NR and NBR compounds in the presence of vulcanizing accelerators such as TMTD,MBTS,DPG,TMTM,CBS, and MBT were evaluated by means of DSC. In order to examine the credibility in the DSC method, the same samples which were used for DSC method were studied to compare the DSC results with the ODR (Oscillating Disk Rheometer) data. The results obtained were as follows 1. In the DSC dynamic experiments, the observed enthalpy results from vulcanization depends upon the heating rate; In the range of 2 to $20^{\circ}C/min$ of heating rate, as the heating rate was increased the enthalpy change was also increased. However, over the heating rate of $30^{\circ}C/min$ it was observed that the enthalpy change was decreased as the heating rate was further increased. Without regard to the change of enthalpy, tremendous instantaneous heat evolving was observed in the range of high heating rates. 2. For the samples which are added with various vulcanizing accelerators, the activation energies of vulcanization were as follows; 3. Regarding to the influences of vulcanizining accelerator's types upon the characteristics of vulcanization exotherm, NR and NBR compounds in the presence of thiuramsulphide compounds type accelerators such as TMTD, TMTM, were exhibited sharper and higher vulclanization exotherm than others. From the resuts of DSC thermograms which was distributed in even shape in the broad temperature range, it was clearly shown that the guanidine compounds type accelerator such as DPG acts as a delayed acting accelerator. 4. In the comparison of DSC and ODR results, the dependency of temperature in the cure rate and the observed conversions show good agreements between two results. 5. In the same curatives, by the comparison of glass transition temperatures, it was possible to predict relative values of maximum torques. Consequently, from the present studies, it is shown that the DSC thermoanalytical method can provide an alternate new method for rapid and complete quality control analysis of rubber industry.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2000년도 가을 학술발표회 논문집
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• pp.201-208
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• 2000

In this study, the behavior of saturated sandy soils under dynamic loads - pore water pressure and effective stress - was investigated using Disturbed State Concept(DSC) model. The model parameters are evaluated from laboratory test data. During the process of loading and reverse loading, DSC model is utilized to trace strain-hardening and cyclic softening behavior. The procedure of back prediction proposed in this study are verified by comparing with laboratory test results. From the back prediction of pore water pressure and effective mean pressure under cyclic loading, excess pore water pressure increases up to initial effective confining pressure and effective mean pressure decrease close to zero in good greement with laboratory test results. Those results represent the liquefaction of saturated sandy soils under dynamic loads. The number of cycles at initial liquefaction using the model prediction is in good agreement with laboratory test results. Therefore, the results of this study state that the liquefaction of saturated sandy soils can be explained by the effective tress analysis.

• 한국연초학회지
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• 제5권2호
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• pp.55-62
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• 1983

Cellulose의 열분해 반응에 대한 Kinetic Parameter를 구하기 위하여 Thermogravimetry(TG)와 Differential Scanning Calorimetry(DSC)를 이용하는 네가지 비등온법을 고찰하였다. 그 결과 DSC에 의한 가열속도법과 TG에 의한 근사법이 가장 간편하였고Kinetic Parameters의 신뢰도도 매우 높았다. Cellulose 열분해 반응에서 반응차수는 1/2차였고 활성화에너지는 42kca1/mo1로 나타났다.

• Structural Engineering and Mechanics
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• 제44권4호
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• pp.487-499
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• 2012

Dynamic instability of beams subjected to periodic axial forces is studied using the discrete singular convolution (DSC) method with the regularized Shannon's delta kernel. The principal regions of dynamic instability under different boundary conditions are examined in detail, and the non-stationary vibrations near the stability-instability critical regions have been investigated. It is found that the results obtained by using the DSC method are consistent with the analytical solutions, which shows that the DSC algorithm is suitable for the problems considered in this study. It was found that there is a narrow region of beat vibration existed in the vicinity of one side (${\theta}/{\Omega}$ > 1) of the boundaries of the instable region for each condition.

• 한국안전학회지
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• 제19권2호
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• pp.47-53
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• 2004

Emulsion polymerization ws carried out using Alkyl methacrylate(RMA) like MMA, EMA, BMA and Styrene Monomer(SM) for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS(Sodium Lauryl Sulfate). FT-IR and DSC analysis are used to confirm the synthesized core-shell emulsion latexes. Moreover DSC and TGA were used to investigate the thermal characterisitcs of them. The differences of the decomposition rate and the activation energy from TGA and DSC analysis are not so big. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene. For investigating combustion products, LC50 values were calculated by FED(Fractional Effective Dose)from the Pyrolyzer-Mass sepctrometer.

• 마이크로전자및패키징학회지
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• 제12권2호
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• pp.141-147
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• 2005

나노재료 $TiO_2-SiO_2$는 2-prOH(2-propanol)를 용매로 사용하여 가수분해와 축합반응으로 제조하였고, FT-IR, DSC, XRD, FE-SEM을 사용하여 $TiO_2-SiO_2$의 특성을 조사하였다. FT-IR분석으로부터 Ti-0-Si의 흡수피크에 대해 설명하였으며, DSC분석 결과를 Ozawa 방정식에 적용하여, 결정화에 필요한 활성화 에너지를 계산하였다. 결정학적 특징은 XRD를 이용하여 하소 온도의 변화에 따른 시료의 회절패턴과 반가폭의 변화 등에 관련하여 설명하였다. FE-SEM을 통하여 Ti mol$\%$가 증가할수록 입자크기가 커지는 것을 확인 할 수 있었다.

• 한국응용과학기술학회지
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• 제28권1호
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• pp.10-14
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• 2011

Emulsion polymerization was carried out using RMA like MMA, EMA, BMA and Styrene(St.) as monomer for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS. FT-IR, TGA and DSC analysis are used to confirm synthesized core-shell emulsion latexes and to investigate the thermal characteristics of them. From analysis of TGA and DSC, the differences of the decomposition rate and the activation energy are not so large. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene.

• Structural Engineering and Mechanics
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• 제36권3호
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• pp.279-299
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• 2010

A methodology on application of the discrete singular convolution (DSC) technique to the free vibration analysis of thin plates with curvilinear quadrilateral platforms is developed. In the proposed approach, irregular physical domain is transformed into a rectangular domain by using geometric coordinate transformation. The DSC procedures are then applied to discretization of the transformed set of governing equations and boundary conditions. For demonstration of the accuracy and convergence of the method, some numerical examples are provided on plates with different geometry such as elliptic, trapezoidal having straight and parabolic sides, sectorial, annular sectorial, and plates with four curved edges. The results obtained by the DSC method are compared with those obtained by other numerical and analytical methods. The method is suitable for the problem considered due to its generality, simplicity, and potential for further development.

• Advances in materials Research
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• 제1권4호
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• pp.269-284
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• 2012

Thermoresponsive hydrogels based on N-Isopropylacrylamide (NIPAM) and 2-Hydroxyethylacrylate (HEA) were prepared by free radical polymerization. The hydrogels were characterized by elemental (CHN) analysis, differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA). DSC thermogram showed two endothermic transitions which are due to hydration of water present in different environments. One near $0^{\circ}C$ called melting transition of ice and was used to calculate the quantitative determination of the amounts of freezing and non freezing water. The other transition above the ambient temperature was due to the combination of hydrophobic hydration and hydrophilic hydration which changes with the copolymer compositions. Swelling and deswelling studies of the hydrogels were carried out using the aqueous media, salt and urea solutions. The experimental results from swelling studies revealed that copolymers have lower rates of swelling and deswelling than the homopolymer.

• 공업화학
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• 제16권2호
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• pp.292-295
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• 2005

자동차 브레이크 패드 만들 때 페놀 수지의 경화 시간은 원가 질감의 중요한 요인이 된다. 이 경화 시간은 페놀수지와 경화제인 Hexamethylenetetramine의 반응 시간을 측정함으로써 알 수 있다. 이 반응 시간은 적외선 분광법(FT-IR), 열치사 주사법(DSC) 및 열중량 분석법(TGA)에 의하여 화학 반응의 완결을 추적하여 알아낼 수 있었다.