• Title/Summary/Keyword: DMP

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Chracteristics of Thermo and UV reactive Organophosphonate Flame Retardants

  • Kim, Tae-Gyeong;Park, Hui-Mun;Jeong, Byeong-Deok;Go, Sang-Hui
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.10a
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    • pp.135-136
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    • 2008
  • EU-Reach Regulation 대비 유해물질 대체약품 개발 프로그램인 SVHC(Substance of very high concern)로부터 환경친화적인 방염제의 스크리닝으로 LOI 30이상의 Halogen-free 유기계 Organo-Phosphonate 화합물들이 유력한 후보로 선별되었으며 여기에 반응형 저에너지 타입 아(메타)크릴계 광기능성기를 도입하여 에너지 절감형이면서 친환경적인 가공약제를 개발 하였다. 먼저 열경화형 타입중에서도 면섬유에 취급이 용이한 DMP(dimethylphosphite)를 출발물질로한 N-Methylol type의 열경화형 인/질소 타입 알코올 함유 면섬유용 방염제를 제조한후 -OH기에 광반응형 아크릴 기능성기를 도입하여 개시제와 함께 광경화 방염가공 후 물성에 관한 특성를 관찰 하였다.

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Pseudomonas sp. strain DJ77 균주에서 extradiol dioxygenase 를 암호화하고 있는 phnE 유전자의 염기배열

  • 김영창;신명수;윤길상;박영순;김욱현
    • Korean Journal of Microbiology
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    • v.30 no.1
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    • pp.8-14
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    • 1992
  • Nucleotide Sequence of phnE Gene Encoding Extradiol Dioxygenase fromPseudomonas sp. Strain DJ77Kim, Young-Chang'.", Myeong-Su Shin1, Kil-Sang Younl, Young-Soon Park1, andUg-Hyeon Kim'.' (Department of Microbiology, C'hungbuk National University.Cheongju 360-763, KOREA. and 'Research Center for Molecular Microbiology,Seoul National University)nal University)

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A Study on the CIM Justification (CIM구축의 타당성평가에 관한 연구)

  • 한성배;이석주;이순효
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.18 no.34
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    • pp.51-60
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    • 1995
  • The key competition factor of manufacturing industries has progressively changed from cost to quality and time. Recently, the manufacturing environments more rapidly change than before. So, many companies want to introduce a advanced manufacturing system like CIMS to meet various user's needs and short delivery. But there is a considerable gap between the decision to invest and the achievement of promised benefits. Managers, generally, cannot afford CIM invesment unless they can determine beforehand that CIM will work in thier company and that will provide a coherent strategy and satisfactory return on investment In many cases, it is impossible to justify CIM investment by only economical analysis. Decision making problems like CIM investment are of a multiple objective nature. So, decision making process and multiattribute utility function are very useful methods to evaluate CIM justification In this paper, we described the key functions of CIM justification evaluation using IDEF methodology and developed the applicattion procedure of DMP and MUF method for CIM justification.

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A study of Voltage Dmp in Electrical Wiring System for Railway Vehicles (철도 차량 배선의 전압강하에 대한 고찰)

  • Son, Min-Kyu;Jung, Ho-Young;Park, Du-Man
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.959-965
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    • 2009
  • To meet the demand increasing passengers in railway vehicles, railway transportation service companies are increasing the numbers of cars per train-set. Two solutions, Variable train-set formations and Multiple train-set operation, are common way to increase the transportation capability. These kind of long distance train-set can effect train-set command and control system, and sometimes the digital signals using train line from master cabin can not reach to the systems located the other extremity slave car. This is so called Voltage Drop. This phenomenon is originated from the electrical power consumption and electrical cable resistance, and cause to the equipments or cars located end of the electrical cable way, malfunction or abnormal operations. This voltage drop happens not only in train lines but also Battery Power Lines. The purpose of this investigation is to design high reliability railway vehicles by clarifying the possibility of happening these events case by case, by analyzing the reasons, and finally by finding the best solutions.

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Experimental and Numerical Study on the Air-assist Atomizer Spray Droplets (2유체 분무 액적의 거동에 관한 실험 및 수치 해석적 연구)

  • Kim, D.I.;Oh, S.H.
    • Journal of ILASS-Korea
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    • v.3 no.4
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    • pp.65-76
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    • 1998
  • An experimental and numerical study of a spray flow is performed to investigate the spray characteristics using an air-assisted atomizer. A Partical Dynamic Analyzer(PDA) is used to measure SMD, dmp velocity, and drop number density whose the initial conditions have considerable effect on the numerical results. The measured experimental data have been used to asses the accuracy of model predictions. Numerical investigation is made with the Eulerian - Lagrangian formulism. Turbulent dispersion effects using a Monte-Carlo method, turbulent modulation effect and entrainment of air are also numerically simulated. Results show that the numerical predictions of SSF(Stochastic Separated Flow) analysis yielded reasonable agreement with the experimental data. However, the model calculations for small drops produced the inconsistent numerical results due to the effect of surrounding air entrainment.

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Photodegradation of Phosphamidon and Profenofos (Phosphamidon과 Profenofos의 광분해성)

  • 민경진;차춘근
    • Journal of Environmental Health Sciences
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    • v.26 no.2
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    • pp.49-58
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    • 2000
  • The present study was performed to investigate photodegradation rate constants and degradation products of phosphamidon and profenofos by the USEPA method. The two pesticides were very stable in 16 days exposure of sunlight from September 3 to 22, 1999 and humic acid had no sensitizing effect on the photolysis of each pesticide in sunlight. In the UV irradiation test, phosphamidon was rapidly degraded as increasing UV intensity. In case of UV irradiation with TiO2 and with TiO2 powder amount, degradation of profenofos showed no significant difference with UV irradiation. Photodegradation rate of profenofos was slower than that of phosphamidon. In order to identify photolysis products, the extracts of degradation products were analyzed by GC/MS. The mass spectra of photolysis products of phosphamidon were at m/z 153 and 149, those of the profenofos were at m/z 208 and 240, respectively. It was suggested that the photolysis products of phosphamidon were 0, 0-dimethyl phosphate(DMP) and N, N-diethylchloroacetamide, those of profenofos were 4-bromo-2-chlorophenol and 0-ethyl-S-propyl phosphate.

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Hydrogen Bonding between Thioacetamide and Some N,N-dimethylalkylamides in Chloroform

  • Park, Hee-Suk;Choi, Jae-Young;Kim, Yong-Ae;Huh, Young-Duk;Yoon, Chang-Ju;Choi, Young-Sang
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.367-371
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    • 1990
  • The near-IR spectra of thioacetamide were recorded for the investigation of hydrogen bonding between thioacetamide (TA) and N,N-dimethylalkylamides (DMF, DMA, DMP) in chloroform over the range of 5$^{\circ}C$ to 55$^{\circ}C$. The ${\nu}_{\alpha}$ + amide II combination band has been resolved into contributions from monomeric TA, 1:1 hydrogen bonded complex and 1:2 complex by the parameterized matrix modeling method. The association constants ($K_c$) of the complex have been obtained at various temperatures and used to determine the thermodynamic parameters for the hydrogen bonding by the usual Van't Hoff method. It was found that N,N-dimethylalkylamide forms less stable hydrogen bonded complex with TA in chloroform than in carbon tetrachloride.

Diagonal motion partitions on top of QTBT block structure (QTBT 블록 구조에서 대각선 움직임 분할)

  • Ahn, Yongjo
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2018.06a
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    • pp.255-256
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    • 2018
  • 본 논문에서는 비디오 부호화 성능 향상을 위하여 QTBT (QuadTree Plus Binary Tree) 블록 구조에서 대각선 움직임 분할 (DMP: Diagonal Motion Partition) 방법을 제안한다. HEVC 이후의 비디오 압축 표준을 위한 탐색 과정에서 다양한 부호화 성능 향상 방법들이 제안되고 있으며, 그 중 제안하는 대각선 움직임 분할 방법은 하나의 정방형 혹은 직방형의 부호화 유닛 (CU: Coding Unit)을 두 개의 삼각형으로 분할하여 움직임 예측 및 보상을 수행하는 방법이다. 제안하는 방법에서는 두 가지 대각선 방향만을 사용하여 블록을 분할하지만, QTBT 블록 구조와 결합하여 다양한 임의의 블록 분할 형태를 표현하는 것이 가능하다. 본 논문에서는 제안하는 방법을 JEM-7.0에 구현하여 0.15%의 부호화 효율 향상 결과를 획득하였다.

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A Study on Developing National Research Data Repository (연구데이터 국가 리포지터리 구축에 관한 연구 - 국내외 사례를 중심으로 -)

  • Park, Kyu-Ri;An, Byoung-Goon
    • Proceedings of the Korean Society for Information Management Conference
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    • 2017.08a
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    • pp.33-38
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    • 2017
  • 본 연구는 연구데이터가 공공재로써 관리와 공유의 주체가 국가이어야 한다는 주장으로부터 시작하였다. 국내외의 대표적인 연구데이터 리포지터리 구축 사례를 통해 연구데이터의 관리 및 공유 현황에 대해 살펴보고, 이를 통해 국내 인문사회분야 대표 리포지터리인 한국연구재단 기초학문자료센터(KRM)의 개선방향을 확인하는 것을 목적으로 하였다. 미국, 영국, 호주의 경우와 KRM의 연구데이터관리 현황을 비교한 결과 가장 큰 차이점은 KRM의 경우 연구데이터 관리의 중요성에 대한 인식개선을 위한 교육과 실제 구축을 위한 DMP 및 메타데이터 작성 교육 등이 부재한 상황으로 연구자의 적극적 참여 유도에 긍정적 환경을 제시하지 못하고 있다는 것이다. 이외에도 장기보존을 위한 국제적 표준의 채택이나 전담 인력의 부족 또한 주요한 개선점으로 확인되었다.

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The analysis of endocrine distruptors in commercial cosmetics (유통 화장품 중 내분비계 장애물질 탐색 및 규명에 관한 연구)

  • Koo, Heesoo;Na, Youngran;Lee, Seungju;Min, Sangkee;Kang, Jungmi;Jin, Sung Hyun
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.212-220
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    • 2015
  • This study aims to identify the characteristics of phthalates (DMP, DEP, DBP, DEHA, BBP, DEHP, and DNOP) and heavy metals such as lead (Pb), cadmium (Cd), and mercury (Hg) in cosmetics and their containers. Phthalates and heavy metals may be endocrine distruptors. Sixty-five cosmetics were purchased from online and offline stores in Busan. This study developed a simultaneous method for the analysis of phthalates by GC-FID. The results showed that among the 65 cosmetics, DBP, DEHP, and DEP were detected at 20.0%, 7.7%, 1.5%, respectively. The amounts of DBP and DEHP detected in 18 samples were less than 100 μg/g, which satisfies the Regulations of Cosmetic Safety Standards in Korea. In order to detect phthalates in cosmetic containers, a dissolution test was conducted by extracting solutions, such as water, n-heptane, 20% ethanol, 50% ethanol and 4% acetic acid, which were prepared with different levels of pH, alcohol content, and fat content following the Korea Standards and Specifications for Utensils, Containers, and Packaging. The results showed that DMP, DBP, DEHA, BBP, DEHP, and DNOP were not detected, DEP was detected in plastics such as PE, PP, and others, when a 50% alcohol solvent was used. Phthalates may not be detected in cosmetic containers if they are not packaged with the above 20% alcohol constituent. We also analyzed the concentration of heavy metals, such as Pb, Cd, and Hg, by using ICP-OES and a mercury analyzer. The ranges of concentration were ND~2.71 μg/g for Pb, ND~0.31 μg/g for Cd, and ND~0.01 μg/g for Hg, which are below the regulated level.