• 제목/요약/키워드: DBT

검색결과 113건 처리시간 0.031초

Isolation and Characterization of a Dibenzothiophene Degrading Sulfate-Reducing Soil Bacterium

  • Kim, Hae-Yeong;Kim, Tae-Sung;Kim, Byung-Hong
    • Journal of Microbiology and Biotechnology
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    • 제1권1호
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    • pp.1-5
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    • 1991
  • Sulfate-reducing bacteria have been isolated from soil and their abilities to degrade dibenzothiophene (DBT) were compared with those of type cultures. Among the strains tested a soil isolate M6 showed the highest ability to degrade DBT. Isolate M6 was characterized as a mesophilic obligatory anaerobe. The morphology of the bacterium was vibrioid with the size of $0.4-0.7{\;}\mu\textrm{m}{\;}by{\;}1.0-1.5{\;}\mu\textrm{m}$. Gram reaction was negative and nonsporulating. Desulfoviridin is present. Lactate, pyruvate, ethanol and malate supported growth of the bacterium in the presence of sulfate. Sulfate, sulfite, thiosulfate and sulfur served as electron acceptors for growth. Hydrogenase was present. The mol% of guanine and cytosine of DNA was determined as 56%. The bacterium produced viscous material. From these results, the isolate M6 was identified as Desulfovibrio desulfuricans.

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계면활성제가 Rhodococcus erythropolis IGTS8에 의한 dibenzothiophene의 탈황에 미치는 영향 (Influence of Surfactant on Biodesulfurization of Dibenzothiophene by Rhodococcus erythropolis IGTS8)

  • 김충식;백기태;신현재;이현호;양지원
    • KSBB Journal
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    • 제14권3호
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    • pp.380-383
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    • 1999
  • 본 연구를 통하여 Rhodococcus erythropolis IGTS8은 배양증애 유기 황화합물인 dibenzothiophene을 2-hydroxybiphenyl로 탈황하며 이 과정에서 계면활성 물질을 분비함을 확인하였다. 생산된 계면활성제로 인하여 배지내의 탁도와 균체의 건조증량 사이에는 비례관계가 없음을 확인하였다. 인위적으로 Tween 80을 넣어준 결과 균체성장 속도, 즉 DBT 분해율은 증가되었으며 2%(v/v)이상의 Tween 80 농도에서는 오히려 저해 효과를 보았다.

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제주도 성산항내 부틸주석화합물의 분포와 생물체에 미치는 영향 (Distribution and Effect on Organisms of Butyltin Compounds Inside Songsan Harbor of Cheju Island)

  • 김상규;안이선;고병철;조은일;이기호
    • 한국환경과학회지
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    • 제9권4호
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    • pp.285-294
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    • 2000
  • Butyltin compounds (BTs) in seawater, sediments and organisms (Thais clavigera, Liolophura japonica and Cellana nigrolineata), were quantitatively determined to evaluate their distribution inside Songsan Harbor of Cheju Island. In addition, imposex in T. clavigera was used to assess the effect on organisms of BTs. Analysis of the samples collected in seawater, sediments (March, June and August) and organisms (May, July and August) in 1998, confirmed the contamination of BTs in the aquatic environment inside Songsan Harbor. The main BTs species in seawater and sediments was monobutyltin (MBT), tributyltin (TBT), respectively, irrespective of survey time. In oranisms, TBT and dibutyltin (DBT) were detected in similar concentrations for T. clavigera and L. japonica, but for C nigrolineata, DBt concentration was the highest. TBT, the most toxic to aquatic organisms among BTs, was found at concentrations which were sufficient to have a serious effect on the sensitive organisms upon chronic exposure, The relatively high correlations (r>0.83) between BTs indicated that DBT and MBT were mainly degraded from TBT based on antifouling paint and their sources were negligible. The sedimentary organic matters did not have influence on the distribution of BTs in marine environment, and lipid content in T. clavigera did not show a correlation with TBT concentrations. The rate of occurrence of imposex in T. clavigera was 100%, and the relative penis length index (RPLI) and the relative penis size index (RPSI) which represent the degree of imposex were 79.7%, 58.1%, respectively. Measurement of imposex in T. clavigera was expected to be a very helpful tool for preliminary survey of BTs prior to trace analysis of BTs.

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제올라이트 담체상의 디벤조티오펜 수첨탈황반응에서 저온활성 및 선택성 (Activity and Selectivity in Low Temperature for Dibenzothiophene Hydrodesulfurization based Zeolite Support)

  • 김문찬
    • 공업화학
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    • 제9권1호
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    • pp.101-106
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    • 1998
  • 제올라이트를 담체로 사용하여 활성금속으로 코발트와 몰리브덴을 담지시킨 촉매와 상용공정에 사용되는 $NiMo/{\gamma}-Al_2O_3$촉매를 제조하여, 저온에서의 DBT 탈황활성과 선택성에 대하여 비교하였다. 고정층 고압 연속흐름반응기에서 수행된 탈황반응에서, 저온 영역인 $200^{\circ}C$$225^{\circ}C$에서는 제조된 $NiMo/{\gamma}-Al_2O_3$촉매보다 CoMo/zeolite 촉매에서 탈황활성이 더 높았으며, $275^{\circ}C$ 이상의 고온 영역에서는 $NiMo/{\gamma}-Al_2O_3$촉매의 탈황활성이 더 높게 나타났다. $NiMo/{\gamma}-Al_2O_3$촉매에서는 biphenyl과 cyclohexylbenzene이 주생성물인데 비하여 zeolite를 담체로 사용한 촉매의 경우 알킬화반응이 일어나 생성물 분포가 매우 다름을 보여주고 있으며, 알킬화반응과 수소첨가반응의 두 가지 경로를 통해서 최종 생성물질인 alkylcyclohexane을 생성하는 것으로 추정된다. 제올라이트 담체상에서 molybdenum은 flesh 촉매에서 $MoO_3$형태로 존재하고 있으며, aged 촉매상에서는 $MoO_3$$MoS_2$형태로 황화되어 있음을 알 수 있었다.

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넙치의 혈청, 간 및 근육 중 Tributyltin 축적 경향 (Accumulation of Tributyltin (TBT) in Blood, Liver and Muscle of Olive Flounder)

  • 김남숙;홍상희;심원준;전중균
    • Environmental Analysis Health and Toxicology
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    • 제22권1호
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    • pp.19-26
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    • 2007
  • Accumulation of tributyltin (TBT) in serum, liver and muscle of olive flounder (Paralichtys olivaceus) was investigated in a 60-d static renewal exposure at $0.1{\mu}g$ TBT/L. Tributyltin accumulated rapidly from 83 ng Sn/g to 2,227 ng Sn/g on a wet weight basis in the serum of the olive flounder and to a greater extent than in the other tissues. The accumulated TBT concentrations in tissues were in the order of serum>liver>muscle on wet or dry-weight basis. High concentrations of dibutyltin (DBT: 990 ng Sn/g dry wt) and monobutyltin (MBT: 141 ng Sn/g dry wt), degradation products of TBT were found in liver of olive flounder at the end of exposure. On the other hand, DBT and MBT was below the detection limits in muscle during the exposure, and only low concentration of DBT (56 ng Sn/g) were detectefd in serum. Butyltin compounds were also quantitatively determined in feral fine-spotted flounder (Pleuronichthys cornutus) collected from Gwangyang Bay as one of polluted area and Sori Island as a reference site. All three butyltin compounds were detected from the fine-spotted flounder from Gwangyang Bay up to 3,107 ng Sn/g of total butyltins in liver, while 120 ng Sn/g of total butyltin concentration was found in the liver of fish from Sori Island.

Identification of Anti-Cancer Targets of Eco-Friendly Waste Punica granatum Peel by Dual Reverse Virtual Screening and Binding Analysis

  • Usha, Talambedu;Goyal, Arvind Kumar;Lubna, Syed;Prashanth, H.P.;Mohan, T. Madhan;Pande, Veena;Middha, Sushil Kumar
    • Asian Pacific Journal of Cancer Prevention
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    • 제15권23호
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    • pp.10345-10350
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    • 2015
  • Background: Punica granatum (family: Lythraceae) is mainly found in Iran, which is considered to be its primary centre of origin. Studies on pomegranate peel have revealed antioxidant, anti-inflammatory, anti-angiogenesis activities, with prevention of premature aging and reducing inflammation. In addition to this it is also useful in treating various diseases like diabetes, maintaining blood pressure and treatment of neoplasms such as prostate and breast cancer. Objectives: In this study we identified anti-cancer targets of active compounds like corilagin (tannins), quercetin (flavonoids) and pseudopelletierine (alkaloids) present in pomegranate peel by employing dual reverse screening and binding analysis. Materials and Methods: The potent targets of the pomegranate peel were annotated by the PharmMapper and ReverseScreen 3D, then compared with targets identified from different Bioassay databases (NPACT and HIT's). Docking was then further employed using AutoDock pyrx and validated through discovery studio for studying molecular interactions. Results: A number of potent anti-cancerous targets were attained from the PharmMapper server according to their fit score and from ReverseScreen 3D server according to decreasing 3D scores. Conclusion: The identified targets now need to be further validated through in vitro and in vivo studies.

결정상과 분산도의 조절이 가능한 MoO3/SiO2 촉매의 제조 및 탈황반응특성 연구 (Preparation and Catalytic Activity of Morphologically Controlled MoO3/SiO2 for Hydrodesulfurization)

  • 하진욱
    • 공업화학
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    • 제10권2호
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    • pp.231-236
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    • 1999
  • 결정상과 분산도가 조절된 $MoO_3$/$SiO_2$ 담지촉매를 제조하여 촉매의 표면특성과 디벤조티오펜 탈황반응의 활성도를 고찰하였다. Mo의 표면담지량은 4 atoms $Mo/nm^2$이었으며, 실리카 표면 위에 형성된 $MoO_3$의 결정상은 sintered hexagonal, sintered orthorhombic, 및 dispersed hexagonal상이었다. XRD, Raman, 및 $O_2$ 흡착 결과 $MoO_3$의 표면분산도는 sintered hexagonal < sintered orthorhombic < dispersed hexagonal 순으로 증가하였다. TPR 결과 $MoO_3$ 결정은 $650^{\circ}C$에서 $MoO_2$로, $1000^{\circ}C$에서 Mo로 환원됨을 알 수 있었다. 디벤조티오펜 탈황반응을 30기압, $350{\sim}500^{\circ}C$ 온도범위에서 수행하였으며, 실험 결과 활성도는 $MoO_3$ 결정체의 $SiO_2$ 표면에서의 분산도에 비례하여 증가함을 알 수 있었다.

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Effects of Biofertilizer Rate and Application Time on Growth Characters and Grain Quality of Rice

  • Mintah, Lemuel Ohemeng;Rico, Cyren Mendoza;Shin, Dong-Il;Chung, Il-Kyung;Son, Tae-Kwon;Lee, Sang-Chul
    • 한국작물학회지
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    • 제52권4호
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    • pp.403-410
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    • 2007
  • A field experiment was conducted to investigate effects of application time and rate of biofertilizer alone and in combination with chemical NPK fertilizer on growth, yield and quality of rice. The biofertilizer used composted food waste as substrate and added with effective microorganism. The treatments included recommended NPK fertilizer(RF, $11-5.5-4.8kg\;10a^{-1}$), half recommended NPK fertilizer(HRF, $5.5-2.8-2.4kg\;10a^{-1}$), half recommended NPK fertilizer plus $250kg\;10a^{-1}$ biofertilizer(HRF+Bio 250) and $500kg\;10a^{-1}$ biofertilizer(HRF+Bio 500). The biofertilizer treatments were applied at 0, 5 and 10 days before transplanting(DBT). Grain yield of HRF+Bio 250 at 5 DBT($648.4kg\;10a^{-1}$) was statistically similar to the highest obtained in the RF($654.1kg\;10a^{-1}$). Tiller numbers at HRF plus biofertilizer treatments were already high during the maximum tillering stage, and were similar with that of the RF and higher than that of the HRF during heading stage. Likewise, ripening ratio at HRF plus biofertilizer treatments was similar with that of the RF and higher than that of the HRF. Furthermore, all the biofertilizer treatments improved protein content but reduced the amylose content and palatability compared to treatments with chemical NPK fertilizer alone. Thus, HRF+Bio 250 at 5 DBT can be used to save 50% chemical NPK fertilizer and at the same time obtain an improved rice grain yield and quality.