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Novel Photocatalytic and Antibacterial Activities of Three-Dimensional (3D) Polycrystalline Anatase TiO2 Structures

  • Lee, Hyun Uk;Yun, Hyung Joong;Son, Byoungchul;Seo, Jung Hye;Kim, Hyeran;Choi, Saehae;Jeon, Cheolho;Kim, Hae Jin;Lee, Jouhahn
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.635-635
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    • 2013
  • We report three-dimensional polycrystalline anatase TiO2 structures (3D a-TiO2) for environmental and bio-medical applications. The 3D a-TiO2 was synthesized without thermal treatment by the growth of rod-like polycrystals on Degussa P25 (P25) via low temperature (< $85^{\circ}C$) modified alkali hydrothermal processing. X-ray diffraction and high-resolution transmission electron microscopic results showed that the rod-like polycrystals of 3D a-TiO2 possessed the highly anatase nanostructures. The photocatalytic activity of 3D a-TiO2 was found to be 2.2 times higher than that of P25. The recyclability of the 3D a-TiO2 was found to be high: the decolorization rate was 94.8% of the initial value after fifteen cycles. In addition, 3D a-TiO2 exhibited excellent antibacterial activities for the sterilization of gram-negative Escherichia coli (E. coli) and gram-positive Staphylococcus aureus (S. aureus). Even at the 10th recycled use, more than 98.4% of E. coli and S. aureus can be killed. These results indicated that 3D a-TiO2 might have utility in several promising applications such as photocatalytic water/air purification and bactericidal agents.

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3D NAND Flash Memory에 Ferroelectric Material을 사용한 Current Path 개선 (Improvement of Current Path by Using Ferroelectric Material in 3D NAND Flash Memory)

  • 이지환;이재우;강명곤
    • 전기전자학회논문지
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    • 제27권4호
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    • pp.399-404
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    • 2023
  • 본 논문에서는 3D NAND Flash memory의 O/N/O(Oxide/Nitride/Oxide) 구조와 blocking oxide를 ferroelectric material로 대체한 O/N/F(Oxide/Nitride/Ferroelectric) 구조의 current path를 분석했다. O/N/O 구조는 Vread가 인가되면 neighboring cell의 E-field로 인해 current path가 channel 후면에 형성된다. 반면 O/N/F 구조는 ferroelectric material의 polarization으로 인해 electron이 channel 전면으로 이동하여 current path가 전면에 형성된다. 또한 channel thickness와 channel length에 따른 소자 특성을 분석했다. 분석 결과 O/N/F 구조의 전면 electron current density 증가는 O/N/O 구조보다 2.8배 더 높았고 O/N/F 구조의 전면 electron current density 비율이 17.7% 높았다. 따라서 O/N/O 구조보다 O/N/F 구조에서 전면 current path가 더 효과적으로 형성된다.

Photodissociation to Several Atomic Terms: Near-threshold Resonance for Production of O($^3$P) and O($^1$D) in OH Photodissociation

  • 이성열
    • Bulletin of the Korean Chemical Society
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    • 제22권12호
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    • pp.1333-1336
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    • 2001
  • A theoretical analysis is presented for the multichannel type resonance at energies above the dissociation threshold to O(1D) in the photodissociation of OH. Dissociations to both oxygenic terms O(3P) and O(1D) are treated. Total cross sections for producing these oxygen terms display asymmetric resonance due to the quantum interference resulting from complicated interplay of electronic states correlating to these two oxygenic terms. The branching ratios of O(3Pj, j = 0, 1, 2), and the vector properties of O(3Pj, j =0,1,2) and O(1D) display extensive changes near the threshold resonance as the result of the interactions among the electronic states correlated with O(3P) and O(1D).

3D NAND Flash Memory에서 Tapering된 O/N/O 및 O/N/F 구조의 Threshold Voltage 변화 분석 (The Analysis of Threshold Voltage Shift for Tapered O/N/O and O/N/F Structures in 3D NAND Flash Memory)

  • 이지환;이재우;강명곤
    • 전기전자학회논문지
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    • 제28권1호
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    • pp.110-115
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    • 2024
  • 본 논문은 3D NAND Flash memory에서 tapering된 O/N/O(Oxide/Nitride/Oxide) 구조와 blocking oxide를 ferroelectric material로 대체한 O/N/F(Oxide/Nitride/Ferroelectric) 구조의 Vth(Threshold Voltage) 변화량을 분석했다. Tapering 각도가 0°일 때 O/N/F 구조는 O/N/O 구조보다 저항이 작고 WL(Word-Line) 상부와 WL 하부의 Vth 변화량이 감소한다. Tapering된 3D NAND Flash memory는 WL 상부에서 WL 하부로 내려갈수록 channel 면적이 감소하며 channel 저항이 증가한다. 따라서 tapering 각도가 증가할수록 WL 상부의 Vth가 감소하고 WL 하부의 Vth는 증가한다. Tapering된 O/N/F 구조는 channel 반지름 길이와 비례하는 Vfe로 인해 WL 상부의 Vth는 O/N/O 구조보다 더 감소한다. 또한 O/N/F 구조의 WL 하부는 O/N/O 구조보다 Vth가 증가하기 때문에 tapering 각도에 따른 Vth 변화량이 O/N/O 구조보다 더 증가한다.

Chemical and Electrochemical Intercalation of Lithium in 2D-FeMoO$_4Cl^1$

  • 조진호;장순호;노동윤;손경아
    • Bulletin of the Korean Chemical Society
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    • 제10권1호
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    • pp.27-30
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    • 1989
  • Lithium has been intercalated into $FeMoO_4Cl$, and deintercalated from $LixFeMoO_4Cl$ both electrochemically and chemically. The inserted $Li^+$ ions are stabilized in the distorted octahedral field in interlayer space of $FeMoO_4Cl$. The crystal symmetry is reduced from tetragonal to monoclinic due to the reduction of ferric to ferrous ions in $LixFeMoO_4Cl$ upon lithium intercalation. From the magnetic and structural data, it has been concluded that the high-spin electronic configuration of $Fe^{2+}(d_{xz}^2{d_{y2}^1}{d_1}{2d_z^12}{\cdot}_y2)$, corresponding to $^5E_g$, group term in $D_{4h}$ symmetry, can be stabilized by the elongation of $FeO_4Cl_{2-}$octahedra in a weak ligand field.

ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$계 바리스터의 d.c. 스트레스에 따른 안정성에 관한 연구 (A Study on the Stability of ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$-Based Varistors with d.c. Stress)

  • 윤한수;류정선;남춘우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1670-1672
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    • 2000
  • The stability of ZnO-$Pr_{6}O_{11}$-CoO-$Cr_{2}O_{3}-Dy_{2}O_3$ based varistors with d.c. stress were investigated. ZnO varistor doped with 4.0 mol% $Dy_{2}O_3$ exhibited the highest nonlinear exponet, but stability was very poor because of low density. In particular, the varistor containing 0.5 mol% $Dy_{2}O_3$ showed very excellent V-I characteristic, which the nonlinear exponent was 67.39 and leakage current was 1.18 ${\mu}A$, and high stability.

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한.양방 협진체계 개발에 관한 연구 (A Study on Cooperative Medical Treatment System between Oriental and Western Medical Practitioners)

  • 이동희;류규수
    • 한국병원경영학회지
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    • 제3권1호
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    • pp.34-61
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    • 1998
  • A study on cooperative medical treatment system between oriental and western medical practitioners was conducted from March through August 1997 in order to determine a productive model of cooperation of two medical parts for treatment of patients. Questionnaires were distributed to 195 medical doctors(M.D.) and 195 doctors of oriental medicine(O.M.D.) working in clinics and hospitals in six major cities. Statistical analysis tools used for this study were frequency, t-test and multiple regression by using SPSS/P.C package. The results are summarized as follows: 1. The respondents were composed of male docotors(78%) and female doctors(22%) and 68.2% of M.D. and 97% of O.M.D. were interested in the other medical part. The doctors of both disciplines had some limitation on treatment of patients but they were reluctant to refer their patients to other doctors in different discipline. 2. M.D assumed that oriental medicine was more effective for chronic diseases, and O.M.D. thought that western medicine was more effective for acute diseases. 92.3% of O.M.D.s responded that even though they do not utilize western medical technology for diagnosis, they believed the results of diagnoses by western medical technology. 3. 60.5% of O.M. and 93.3% of O.M.D. said that cooperative medical treatment system could be necessary for patients and it would be effective for control of diseases and 69% of western medical doctors and 99% of oriental medical doctors agreed that oriental medical practice would be more effective for cerebellar vascular accidents than other diseases. 77.4% of western medical doctors and 92.3% of oriental medical doctors responded that the students of two different disciplines have to be taught on the other disciplines. 82.6% of western medical doctors and 83.3% oriental medical doctors agreed that it would be necessary to have collaborative research between scientists in two disciplines. 81.5% of M.D.s and 93.3% of O.M.D.s believed that they had prejudice and distrust on other discipline 4.90% of the doctors were not satisfied with the government medical policies on health insurance, legal matters, and health delivery system. 5. 75.4% of M.D.s and 50.2% of O.M.D.s said that two medical disciplines should be integrated, but they were skeptical on that. 75.3% of M.D.s thought that western hospitals should employ O.M.D.s Finally this study recommended that western medical students study oriental medicine and the vice versa, and M.D.s and O.M.D.s should have seminars and workshops to exchange knowledge, and experiences. It is also recommended that medical laws be revised to allow medical doctors refer the patients whom they can not handle to oriental medical doctors and the vice versa.

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대규모 동적 O/D 생성을 위한 추정 방법론 연구: 첨두 출근통행을 기준으로 (A Methodology for Estimating Large Scale Dynamic O/D of Commuter Working Trip)

  • 한혁;홍기만;김태균;황준문;홍영석;조중래
    • 대한교통학회지
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    • 제36권3호
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    • pp.203-215
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    • 2018
  • 본 연구는 통행자의 통행패턴이 도착지의 토지이용패턴에 따라 변화하는 특징을 반영하여 대규모 동적 O/D를 구축하는 방법을 제안하였다. 기존 동적 O/D 추정 방법 관련 연구들을 살펴보면 자료수집의 어려움으로 소규모 지역에 국한하여 적용 가능하거나, 고속도로망 혹은 대중교통망 등 특정 교통망에 제한하여 O/D를 구축하는 등 한계가 존재한다. 이에 본 연구에서는 빅데이터 시대에 발맞추어 쉽게 수집, 이용이 가능한 교통 관련 자료들을 기반으로 분석 지역의 범위 제약 없이 동적 O/D를 추정하는 기법을 제시하였다. 군집 분석(Clustering Analysis) 기법을 이용하여 군집별 도착시간 기준 통행분포 비율로 출발시간 통행분포 비율을 산정하고 첨두 출발시간 분포함수를 추정하였다. 추정된 분포함수를 조사자료에 적용하여 비교 검증을 진행해본 결과 통계적으로 유의하게 나타났다.

자소엽(Perillae Folium) 열수추출물의 식물화학성분 연구 (Phytochemical Study of Hot-Water Extract of Perillae Folium)

  • 길현우;노태웅;윤기동
    • 생약학회지
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    • 제51권1호
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    • pp.55-64
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    • 2020
  • In this study, 15 compounds were elucidated from the hot-water extract of Perillae Folium. Fifteen isolates were determined to be protocatechuic acid (1), caffeic acid (2), (R)-rosmarinic acid (3), (S)-shisoflavanone A (4), luteolin-7-O-β-D-glucuronopyranoside (5), scutellarein-7-O-β-D-glucuronopyranoside (6), apigenin-7-O-β-D-glucuronopyranosyl(1→2)-O-β-D-glucuronopyranoside (7), luteolin-7-O-β-D-glucuronopyranosyl(1→2)-O-β-D-glucuronopyranoside (8), kelampayoside A (9), trans-N-feruloyloctopamine (10), 3-(4-hydroxy-3-methoxyphenyl)-N-[2-(4-hydroxyphenyl)-2-methoxyethyl]acrylamide (11), perilloside C (12), perilloside A (13), (6S,9R)-9-hydroxy-megastigma-4,7-dien-3-one-9-O-β-D-glucopyranoside (14) and (6S,9R)-roseoside (15) through spectroscopic evidences. The HPLC analysis revealed that hot-water extract of Perillae Folium contained caffeic acid, rosmarinic acid and glycosides of apigenin, luteolin and scutellarein as main constituents.

The Study on the Fabrication and Characterization of Dielectric Materials of Front and Back Panel for PDP(Plasma Display Panel)

  • Chang, Myeong-Soo;Lee, Yoon-Kwan;Ryu, Byung-Gil;Park, Myung-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.181-182
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    • 2000
  • The glass compositions of $PbO-SiO_2-B_2O_3$ system and $P_2O_5-PbO-ZnO$ system for the transparent dielectric materials for front panel and $P_2O_5-ZnO-BaO$ and $SiO_2-ZnO-B_2O_3$ for the reflective dielectric materials for back panel of PDP(Plasma Display Panel) were investigated. As a transparent dielectric materials for front panel, $PbO-SiO_2-B_2O_3$ glass showed good dielectric properties, high transparency and proper thermal expansion matching to soda-lime glass substrate. And the reflective dielectric materials for back panel were prepared from parent glass of $SiO_2-ZnO-B_2O_3$ system and oxide filler. It was found that these glass-ceramics are useful materials for reflective dielectric layers, as those have a similar thermal expansion to soda-lime glass plate, high reflectance, low sintering temperature.

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