• Textile Coloration and Finishing
• /
• v.27 no.1
• /
• pp.1-10
• /
• 2015

The aim of the current study is to identify the dimerization and decomposition kinetics of the F-$D_M$ type. The regeneration of F-VS from $F_iF_j-D_M$ or the reversibility of the dimerizations were investigated. The order of real rate constants of the dimerization('$K_D{^{ij}}$) would seem to be similar to that of rate constants of a dimerization($K_D{^{ij}}$) for VS dyes at a given pH because of the constancy of the equilibrium constants($K_a{^j}$-value). The reverse reactions of the $D_M$ types are appeared to occur in two steps, the deprotonation of ${\alpha}$-carbon of the $D_M$ types and disproportionation. The ratio of the decomposition of the $D_M$ type to F-Hy and F-VS appears to be related with the ratio of $K_i/K_j$. Similarities were also found among various other reactions, including homo- and mixed dimerization. VS dyes undergoing fast hydrolysis have difficulty in forming a dimer. The higher the reactivity with cellulose or hydroxide ion, the smaller the dimerization. The easiness of the dimerization was thus found to be inversely proportional to the rate of hydrolysis.

• Journal of Environmental Science International
• /
• v.29 no.4
• /
• pp.383-393
• /
• 2020

To increase electrolysis performance, the applicability of seawater to the iron-fed electro-Fenton process was considered. Three kinds of graphite electrodes (activated carbon fiber-ACF, carbon felt, graphite) and dimensionally stable anode (DSA) electrode were used to select a cathode having excellent hydrogen peroxide generation and organic decomposition ability. The concentration of hydrogen peroxide produced by ACF was 11.2 mg/L and those of DSA, graphite, and carbon felt cathodes were 12.9 ~ 13.9 mg/L. In consideration of durability, the DSA electrode was selected as the cathode. The optimum current density was found to be 0.11 A/㎠, the optimal Fe²⁺ dose was 10 mg/L, and the optimal ratio of Fe²⁺ dose and hydrogen peroxide was determined to be 1:1. The optimum air supply for hydrogen peroxide production and Rhodamine B (RhB) degradation was determined to be 1 L/min. The electro-Fenton process of adding iron salt to the electrolysis reaction may be shown to be more advantageous for RhB degradation than when using iron electrode to produce hydrogen peroxide and iron ion, or electro-Fenton reaction with DSA electrode after generating iron ions using an iron electrode.

• Journal of Institute of Convergence Technology
• /
• v.5 no.1
• /
• pp.1-5
• /
• 2015

SI thermochemical hydrogen production process achieves water splitting into hydrogen and oxygen through three chemical reactions. The process is comprised of three sections and one of them is HI decomposition into $H_2$ and $I_2$ called as Section III. The production of $H_2$ included processes involving EED for concentrating a product stream from Section I. Additionally an $I_2$ crystallization would be considered to reduce burden on EED by removing certain amount of $I_2$ out of a process stream prior to EED. In this study, the current thermodynamic model of SI process was briefly described and the calculation results of the applied Electrolytes NRTL model for phase equilibrium calculations was illustrated for ternary systems of Section III. We calculated temperature and heat duty of an $I_2$ crystallizer and heat duty of heaters using UVa model and heat balance equation of simulation tool. The results were expected to be used as operation information in optimizing HI decomposition process and setting up material balance throughout SI process.

• Smart Structures and Systems
• /
• v.1 no.1
• /
• pp.29-46
• /
• 2005

In this study, a wavelet packet based method is proposed for identifying damage occurrence and damage location for beam-like structures. This method assumes that the displacement or the acceleration response time histories at various locations along a beam-like structure both before and after damage are available for damage assessment. These responses are processed through a proper level of wavelet packet decomposition. The wavelet packet signature (WPS) that consists of wavelet packet component signal energies is calculated. The change of the WPS curvature between the baseline state and the current state is then used to identify the locations of possible damage in the structure. Two numerical studies, one on a 15-storey shear-beam building frame and another on a simply-supported steel beam, and an experimental study on a simply-supported reinforced concrete beam are performed to validate the proposed method. Results show the WPS curvature change can be used to locate both single and sparsely-distributed multiple damages that exist in the structure. Also the accuracy of assessment does not seem to be affected by the presence of 20-15dB measurement noise. One advantage of the proposed method is that it does not require any mathematical model for the structure being monitored and hence can potentially be used for practical application.

• Korean Journal of Social Welfare
• /
• v.66 no.2
• /
• pp.159-177
• /
• 2014

This study examines gender differentials in depression among Korean older adults. Using logistic regression and decomposition methods, this study analyzes factors that predict depression of a full sample and separate male/female samples, respectively. Further, this study decomposes factors that affect gender differentials in depression into two components: the distributions of individual variables and the returns to risk. This study finds the variables that separately predict depression by gender. For male, having a smaller social network is associated with depression; however for female, the number of falls is associated with depression. This study also finds that being married, having greater satisfaction with current financial situation, and having good physical health increases the gap between males' and females'depression. Married male have greater returns from marriage than females. If females had the same returns as male, then the gap would have decreased by about 40%.

• Journal of Electrical Engineering and Technology
• /
• v.10 no.3
• /
• pp.766-776
• /
• 2015

It is well known that series arc faults in Low Voltage DC (LVDC) distribution system occur at unintended points of discontinuity within an electrical circuit. These faults can make circuit breakers not respond timely due to low fault current. It, therefore, is needed to detect the series fault for protecting circuits from electrical fires. This paper proposes a novel scheme to detect the series arc fault using Wavelet Singular Value Decomposition (WSVD) and state diagram. In this paper, the fault detector developed is designed by using three criterion factors based on the RMS value of Singular value of Approximation (SA), Sum of the absolute value of Detail (SD), and state diagram. LVDC distribution system including AC/DC and DC/DC converter is modeled to verify the proposed scheme using ElectroMagnetic Transient Program (EMTP) software. EMTP/MODELS is also utilized to implement the series arc model and WSVD. Simulation results according to various conditions clearly show the effectiveness of the proposed scheme.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2005.11b
• /
• pp.39-50
• /
• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• Journal of Broadcast Engineering
• /
• v.21 no.2
• /
• pp.149-156
• /
• 2016

We proposed a blind watermarking scheme using singular vectors based on Discrete Wavelet Transform (DWT) and Redundant Discrete Wavelet Transform (RDWT) combined with Singular Value Decomposition (SVD) for copyright protection application. We replaced the 1st left and right singular vectors decomposed from cover image with the corresponding ones from watermark image to overcome the false-positive problem in current watermark systems using SVD. The proposed scheme realized the watermarking system without a false positive problem, and shows high fidelity and robustness.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.2
• /
• pp.781-789
• /
• 2018

This paper proposes a new approach utilizing empirical mode decomposition (EMD) reconstruction to process vibration signals of a transformer under DC bias caused by high voltage direction transmission (HVDC), which is the potential cause of additional vibration and noise from transformer. Firstly, the Calculation Method is presented and a 3D model of transformer is simulated to analyze transformer deformation characteristic and the result indicate the main vibration is produced along axial direction of three core limbs. Vibration test system has been built and test points on the core and shell of transformer have been measured. Then, the signal reconstruction method for transformer vibration based on EMD is proposed. Through the EMD decomposition, the corrupted noise can be selectively reconstructed by the certain frequency IMFs and better vibration signals of transformer have been obtained. After EMD reconstruction, the vibrations are compared between transformer in normal work and with DC bias. When DC bias occurs, odd harmonics, vibration of core and shell, behave as a nonlinear increase and the even harmonics keep unchanged with DC current. Experiment results are provided to collaborate our theoretical analysis and to illustrate the effectiveness of the proposed EMD method.

• The Journal of Fisheries Business Administration
• /
• v.46 no.1
• /
• pp.93-107
• /
• 2015

This study aims to analyze causalities among Hairtail prices by distribution channel using a vector autoregressive model. This study applies unit-root test for stability of data, uses Granger causality test to know interaction among Hairtail Prices by distribution channel, and employes the vector autoregressive model to estimate statistical impacts among t-2 period variables used in model. Analyzing results of this study are as follows. First, ADF, PP, and KPSS tests show that the change rate of Hairtail price by distribution channel differentiated by logarithm is stable. Second, a Granger causality test presents that the producer price of Hairtail leads the wholesale price and then the wholesale price leads the consumer price. Third, the vector autoregressive model suggests that the change rate of Hairtail producer price of t-2 period variables statistically, significantly impacts change rates of own, wholesale, and consumer prices at current period. Fourth, the impulse response analysis indicates that impulse responses of the structural shocks with a respectively distribution channel of the Hairtail prices are relatively more powerful in own distribution channel than in other distribution channels. Fifth, a forecast error variance decomposition of the Hairtail prices points out that the own price has relatively more powerful influence than other prices.