• Title/Summary/Keyword: Current collector

Search Result 258, Processing Time 0.028 seconds

Electrochemical Performance of Ti-Si Alloy Anode using Nodule Type Current Collector

  • Shin, Min-Seon;Park, Jung-Bae;Lee, Sung-Man
    • Journal of the Korean Electrochemical Society
    • /
    • v.20 no.4
    • /
    • pp.61-66
    • /
    • 2017
  • The cycle performance of Ti-Si alloy anode material for Li-ion batteries has been investigated as a function of loading level of electrode using a nodule type of substrate, in which the current collector of flat foil is also used for comparison. The Ti-Si alloy powders are prepared by mechanical alloying method. The electrodes with the nodule type of current collector exhibit enhanced cycling performance compared to those using the flat foil because the alloy particles are more strongly adhered to substrate and the stress caused by lithiation and delithiation reaction can be effectively relaxed by nodule-type morphology. It appears, however, that the cycle performance is critically dependent on the loading level of electrode, even when the nodule type of current collector is applied. With high loading level, cracks are initiated at surface of electrode due to a steep stress gradient through the electrode thickness during cycling, leading to capacity fading.

The Analysis of DC and AC Current Crowding Effects Model in Bipolar Junction Transistors Using a New Extraction Method (새로운 측정방법을 이용한 바이폴라 트랜지스터에서의 직류 및 교류 전류 편중 효과에 관한 해석)

  • 이흥수;이성현;김봉렬
    • Journal of the Korean Institute of Telematics and Electronics A
    • /
    • v.31A no.8
    • /
    • pp.46-52
    • /
    • 1994
  • DC and AC current crowding effects for microwave and high speed bipolar transistors are investigated in detail using a new and accurate measurement technique based on Z-parameter equationa. Using the new measurement technique dc and ac current crowding effects have been explained clearly in bipolar junction transistors. To model ac crowding effects a capacitive element defined as base capacitance (C$_b$), called ac crowding capacitance is added to base resistance in parallel thereby treating the base resistance(R$_b$) as base impedance Z$_b$. It is shown that base resistance decreases with increasing collector current due to dc current crowding and approaches to a certain limited value at high collector current due to current crowding and approaches to a certain limited value at high collector currents regardless of the emitter size. It is also observed that due to ac current crowding base capacitance increases with increasing collector current. To quantigy the ac crowding effects for SPICE circuit simulation the base capacitance(C$_b$) including the base depletion and diffusion components has been modeled with an analytical expression form.

  • PDF

A Self-standing and Binder-free Electrodes Fabricated from Carbon Nanotubes and an Electrodeposited Current Collector Applied in Lithium-ion Batteries

  • Luais, Erwann;Mery, Adrien;Abou-Rjeily, John;Sakai, Joe;Tran-Van, Francois;Ghamouss, Fouad
    • Journal of Electrochemical Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.373-380
    • /
    • 2019
  • In this paper, we report the preparation of a flexible, self-standing and binder-free carbon nanotubes (CNTs) electrode with an electro-generated current collector. The copper current collector layer was electrodeposited on the backside of CNTs self-standing film obtained by a simple filtration process. The obtained CNTs-Cu assembly was used as a negative electrode in Li-ion batteries exhibiting good performance along with proving its applicability in flexible batteries.

Effects of anode and current collector materials on the power density of solid oxide electrolyte direct carbon fuel cell (고체산화물 전해질 직접탄소 연료전지의 전극 및 집전부 재질이 출력밀도에 미치는 영향)

  • Hwang, J.Y.;Yoon, J.E.;Kang, K.;Kim, J.H.;Lee, B.J.
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.392-394
    • /
    • 2009
  • Direct Carbon Fuel Cells (DCFCs) generates electricity directly converting the chemical energy in coal. In the present study, effects of anode and current collector materials on the power density of DCFC are investigated experimentally. The adopted DCFC system is combined type of solid oxide fuel cells (SOFC) and molten carbonate fuel cells (MCFC) with the use of a liquid-molten salt anode and a solid oxide electrolyte, proposed by SRI. Power densities of 25 mm button cells with various combination of anode materials and current collector materials are measured.

  • PDF

Prevention of Oil Contamination in the Excitation System of a Power Plant Generator (발전용 발전기 여자설비의 오일 오염방지)

  • Choi, Jae-Gyu;Yoo, Ho-Seon;Moon, Seung-Jae
    • Plant Journal
    • /
    • v.7 no.2
    • /
    • pp.30-38
    • /
    • 2011
  • The purpose of this paper is to review the understanding of pollution causes in the excitation system and how to solve the problem. The cause of the problem was in-leakage of bearing lubricant oil through the gap between rotor and outer in the air deflector, which was triggered by a negative pressure with respect to the operation of a collector ring fan in the collector house. In order to prevent exciting current transmission equipment pollutant, the reduction of the negative gage pressure of the inside of collector house is required. The protection in-leakage of bearing lubricant oil through the gap between rotor and outer of the air deflector are necessary. The reduction of the inside diameter of air deflector and the expansion of inlet filter of collector house are inevitable.

  • PDF

Effect of carrier collector on the Efficiency of DSSCs

  • Ramasamy, Easwaramoorthi;Lee, Won-Jae;Lee, Dong-Yun;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.633-634
    • /
    • 2005
  • Transparent conducting glasses exhibit high ohmic losses that are apparent in the case of large size Dye Sensitized Solar Cells (DSSCs). In this study, we investigated the impact of current collectors over the efficiency of DSSCs. The Silver current collectors were prepared on both counter electrode and working electrode surface by screen printing method. For long term stability in electrolyte environment and also to avoid the charge recombination, current collectors are protected by sodium silicate overcoat layer. These current collectors were characterized for their microstructure parameters. Also current collector's stability in electrolyte environment has been investigated.

  • PDF

Improvement of Electrochemical Characteristics and Study of Deterioration of Aluminum Foil in Organic Electrolytes for EDLC

  • Lee, Mun-Soo;Kim, Donna H.;Kim, Seung-Cheon
    • Journal of Electrochemical Science and Technology
    • /
    • v.9 no.1
    • /
    • pp.9-19
    • /
    • 2018
  • The anodic behavior of aluminum (Al) foils with varying purity, capacitance, and withstand voltage in organic electrolytes was examined for EDLC. The results of cyclic voltammetry (CV) and chronoamperometry (CA) experiments showed that the electrochemical stability improves when Al foil has higher purity, lower capacitance, and higher withstand voltage. To improve the electrochemical stability of EDLC current collectors made of low-purity foil (99.4% Al foil), the foil was modified by chemical etching to reduce its capacitance to $60{\mu}F/cm^2$ and forming to have withstand a voltage of 3 Vf. EDLC cells using the modified Al foil as a current collector were made to 2.7 V with 360 F, and a constant voltage load test was subsequently performed for 2500 hours at high temperature under a rated voltage of 2.7 V. The reliability and stability of the EDLC cell improved when the modified Al foil was used as a current collector. To understand the deterioration process of the Al current collector, standard cells made of conventional Al foil under a constant voltage load test were disassembled, and the surface changes of the foil were measured every 500 hours. The Al foil became increasingly corroded, causing the adhesion between the AC coating layer and the Al foil to weaken, and it was confirmed that partial AC coating layer peeling occurred.

A Study on the Thermal Deformation of Current Collectors by Burning Heat Pellets in Thermal Batteries (열전지의 열원 연소에 따른 전류집전체 열변형에 관한 연구)

  • Ji, Hyun-Jin;Kim, Jong-Myong;Kim, Young-Chul;Cho, Sung-Baek
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.15 no.4
    • /
    • pp.527-534
    • /
    • 2012
  • Thermal batteries are primary batteries that use molten salts as an electrolyte and employ an internal pyrotechnic source to heat the battery stack to operating temperatures, typically between 450 and $550^{\circ}C$. The unit cell of thermal batteries consists of an anode, an electrolyte, a cathode, a heat pellet and a current collector. The heat source for such batteries is typically heat pellets based on $Fe/KClO_4$. The elevated temperature by combustion of heat pellet is supposed to cause a flatness non-uniformity, buckling, with a lateral extension diameter of current collector. This paper mainly focused on the combustion and buckling model of current collector to simulate the effect of heat source. Mechanical stresses in the current collector caused by thermal stress is a critical design consideration of thermal batteries because the internal short circuit could be occurred.

Relative Magneto-current of Magnetic Tunnel Transistor with Amorphous n-type Si Film

  • Lee, Sang-Suk;Lee, Jin-Yong;Hwang, Do-Guwn
    • Journal of Magnetics
    • /
    • v.9 no.1
    • /
    • pp.23-26
    • /
    • 2004
  • A magneto-current (MC) was investigated for magnetic tunnel transistor (MTT) with amorphous n-type Si film. A relative MC (more than 49.6%) was observed at an emitter-base bias voltage ($V_{EB}$) of 0.65 V at room temperature. Above a $V_{EB}$ of 0.70 V, however, a rapid decrease in MC was observed in the amorphous Si-based MTT. The collector current increasing and transfer ratio as emitter-base voltage were mainly due to the rapid creation electrons of conduction band states in the Si collector. This approach would make integration in various components and systems easier than a MTT grown on a semiconductor wafer.