• Title/Summary/Keyword: Curing solution

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Numerical simulation on integrated curing-leaching process of slag-blended cement pastes

  • Xiang-Nan Li;Xiao-Bao Zuo;Yu-Xiao Zou;Guang-Pan Zhou
    • Computers and Concrete
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    • v.32 no.1
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    • pp.45-60
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    • 2023
  • Concrete in water environment is easily subjected to the attack of leaching, which causes its mechanical reduction and durability deterioration, and the key to improving the leaching resistance of concrete is to increase the compaction of its microstructure formed by the curing. This paper performs a numerical investigation on the intrinsic relationship between microstructures formed by the hydration of cement and slag and leaching resistance of concrete in water environment. Firstly, a shrinking-core hydration model of blended cement and slag is presented, in which the interaction of hydration process of cement and slag is considered and the microstructure composition is characterized by the hydration products, solution composition and pore structure. Secondly, based on Fick's law and mass conservation law, a leaching model of hardened paste is proposed, in which the multi-species ionic diffusion equation and modified Gérard model are established, and the model is numerically solved by applying the finite difference method. Finally, two models are combined by microstructure composition to form an integrated curing-leaching model, and it is used to investigate the relationship between microstructure composition and leaching resistance of slag-blended cement pastes.

A comparative study on the mechanical properties of ultra early strength steel fiber concrete

  • Yi-Chun Lai;Ming-Hui Lee;Yuh-Shiou Tai
    • Advances in concrete construction
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    • v.16 no.5
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    • pp.255-267
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    • 2023
  • The production of ultra-early-strength concrete (UESC) traditionally involves complexity or necessitates high-temperature curing conditions. However, this study aimed to achieve ultra-early-strength performance solely through room-temperature curing. Experimental results demonstrate that under room-temperature (28℃) curing conditions, the concrete attained compressive strengths of 20 MPa at 4 hours and 69.6 MPa at 24 hours. Additionally, it exhibited a flexural strength of 7.5 MPa after 24 hours. In contrast, conventional concrete typically reaches around 20.6 MPa (3,000 psi) after approximately 28 days, highlighting the rapid strength development of the UESC. This swift attainment of compressive strength represents a significant advancement for engineering purposes. Small amounts of steel fibers (0.5% and 1% by volume, respectively) were added to address potential concrete cracking due to early hydration heat and enhance mechanical properties. This allowed observation of the effects of different volume contents on ultra-early-strength fiber-reinforced concrete (UESFRC). Furthermore, the compressive strength of 0.5% and 1% UESFRC increased by 16.3% and 31.3%, respectively, while the flexural strength increased by 37.1% and 47.9%. Moreover, toughness increased by 58.2 and 69.7 times, respectively. These findings offer an effective solution for future emergency applications in public works.

Strength Characteristic according to the 80℃ Water Curing Time Variation of the Ternary System Inorganic Binder (3성분계 무기결합재의 80℃ 수중양생 시간변화에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.100-101
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    • 2014
  • The global warming because of the CO2 emission and solution about this emerge as the international enviroment problem. Particularly, it is the absolutely it is needed for reducing the CO2 in the cement industry and harmful material actual condition. And the construction of home and abroad and material manufacturers tries for the technology development for the carbon dioxide and harmful material reduction which the portland cement in manufacture is usually emitted along with the increase of concerns about the environment-friendly concrete and panel. Therefore, in this research, the compressive strength of the inorganic binder and flexural strength tries to be measured in order to draw the inappropriate high temperature cure time of the ternary system inorganic binder using the blast furnace slag, red mud, silica fumewhich is the industrial byproduct with the cement substitute material, and etc.

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Application of Cold Weather Concrete using Accelerator for Freeze Protection (내한촉진제를 사용한 한중콘크리트의 현장적용)

  • Park, Sang-Joon;Won, Chul;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2003.05a
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    • pp.13.2-17
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    • 2003
  • When fresh concrete is exposed to low temperature, the concrete may suffer frost damage due to freezing at early ages and strength development may be delayed. One of the solution methods to resolve these problems is to lower freezing temperature of concrete by the use of chemical admixture called Accelerators for Freeze Protection. In this study, it was the results of appling cold weather concrete using Accelerator for Freeze Protection in the Daewoo Trump world field. Before the application of the cold weather concrete using accelerator for freeze protection, we executed the some test in the laboratory and mock-up test in the field. We examined the manifestation of compressive strength complying with the amount of Accelerators for Freeze Protection and curing conditions, and then made a selection of most suitable amount of Accelerators for Freeze Protection.

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Synthesis and Properties of the Vertical Alignment Materials containing Liquid Crystal-like Side Chain

  • Lee, J.B.;Kang, K.H.;Kim, Y.B.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.389-392
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    • 2005
  • Poly(amic acid) precursors were prepared by mixing various main chain dianhydrides, main chain diamines and side chain diamines. The side chain diamine has an alkylbicyclohexyl group as a side chain. The copolyimide films, produced by casting the poly (amic acids) solution, exhibited the vertical alignment property without the rubbing process in the range of the curing themperature from $90^{\circ}C$ to $240^{\circ}C$ for 1h. The thermal and surface properties of the poly(amic acids) depending on the curing temperature was examined.

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Strength Property of Ternary System Non-Cement Matrix according to the Curing Method (3성분계 무시멘트 경화체의 양생방법에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Sang-Soo
    • The Journal of the Korea Contents Association
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    • v.14 no.4
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    • pp.389-396
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    • 2014
  • This study was conducted as the basic research for the replacement of Blast Furnace Slag, Red Mud, Silica Fume, etc., with cement as a solution to the problems arising from the global warming caused by the generation of $CO_2$, and conducted the experimental review to examine the feasibility of matrix having properties identical to those of cement by using the Blast Furnace slag, Red mud, Silica fume, and alkali-activator. For this, by using the the inorganic binder, such as Blast Furnace Slag, Red Mud, Silica Fume, etc., and NaOH, $Na_2SiO_3$ and others as the cement substitute material, the strength characteristic according to the mixture time variation was performed in the tentative experiment. Based on the preceding experiment, this study performed the experiment to analyze the strength properties of hardener through the curing by air-dry temperature, curing by temperature in water, coating curing, and Korean paper curing. For the water curing at $80^{\circ}C$, the compressive strength and flexural strength were found to be the most excellent at the age of the 28th day, and furthermore, it was found that the non-cement hardener could be made, which is considered to affect the production of eco-friendly concrete.

MONOMER RELEASE FROM PIT AND FISSURE SEALANT FOLLOWING BY SURFACE TREATMENT AND CURING TIME (치면열구전색제의 표면처리와 중합시간 증가에 따른 미반응 모노머 용리 평가)

  • Seo, Hyun-Woo
    • Journal of the korean academy of Pediatric Dentistry
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    • v.34 no.1
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    • pp.122-129
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    • 2007
  • The purpose of this study was to evaluate the effects of a various light curing time on the residual monomers released from light-cured dental sealant, and to examine the effectiveness of surface treatment in reducing the oxygen-inhibited layer of light-cured dental sealant($Helioseal^{(R)}$ F, Vivadent, Liechtenstein). Specimens were cured with a halogen light curing unit(XL 3000, 3M, USA) for 20, 40, 60s. Surface treatment of a light-cured dental sealant included no treatment(control group), a 10-seconds exposure to distilled water(Group I), 10-seconds manual application using a cotton pellet wetted with 75% alcohol(Group II), and 10-seconds application of a water/pumice slurry using a rubber cup on a slow-speed handpiece The specimens were eluted in distilled water for 10 minutes. All elutes were analyzed by HPLC for identification and quantitive analysis of monomers. The results of this study can be summarized as follows. 1. None of the chromatograms of the tested sealant displayed peaks with the same retention time as that of the standard solution, except for TEGDMA. 2. The release of TEGDMA decreased with increasing curing time in conventional halogen light. 3. All surface treatment group had a decrease of monomer release in comparison with no treatment group. 4. Treatment that Group III eliminated the greatest amount of any type of residual monomers. 5. The elution of unreacted monomers from curing with halogen curing unit for 60s and Group III was less than other groups.

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Setting Behavior of Polystyrene Mortars with Elapsed Curing Time (폴리스티렌 모르타르의 양생재령에 따른 경화거동)

  • Choi Nak-Woon;Kim Han-Sang
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.54-60
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    • 2004
  • This study deals with the setting behavior of polystyrene mortars using waste expanded polystyrene(EPS) solution-based binders. The binders for polystyrene mortars are made by mixing crosslinking agent with EPS solutions prepared by dissolving EPS in styrene. Polystyrene mortars are prepared with various EPS concentrations of EPS solutions and crosslinking agent contents, subjected to a dry curing, and tested for working life, peak exotherm temperature and 10h-length change. From the test results, He working lives of polystyrene mortars are shortened with raising EPS concentration of EPS solution and crosslinking agent content. Low-shrinkage or non-shrinkage polystyrene mortars could be obtained by adjusting EPS concentration of EPS solution and crosslinking agent content.

Physical Properties of Cotton Fabric Treated with BTCA and P olyalkyleneoxide-modified amino-functional silicone (BTCA와 실리콘 처리 면직물의 물리적 성질)

  • 남승현;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.4
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    • pp.525-534
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    • 1998
  • Cotton fabrics were finished with mixture of BTCA(1,2,3,4,-butanetetracarboxylic acid) and polyalkyleneoxide-modified amino-functional silicone by pad-dry-cure process to achieve better DP performance with a higher retention of physical properties as compared to those of finished with BTCA alone. The results indicated that BTCA improved the wrinkle recovery but reduced significantly the tensile and tear strength of the treated fabrics. Whereas silicone imparted a lower wrinkle recovery, a lower loss of tensile strength than BTCA, in addition improved considerably the tear strength owing to reduction in inter-fiber and/or inter-yarn frictional forces. The concentration and curing temperature needed to enhance physical properties were as follows; for BTCA treatments 6%, at 18$0^{\circ}C$, for silicone treatments 1% at 14$0^{\circ}C$. This optimum concentration of silicone was observed by using the mixture of BTCA and silicone. The wrinkle recovery and DP rating of cotton fabrics treated with mixture of 4% BTCA and 1% silicone at a curing temperature of 17$0^{\circ}C$ was similar to those of treated with 6% BTCA at a curing temperature of 18$0^{\circ}C$, and other performance properties observed were; an increase in tensile strength, extension, toughness, abrasion resistance and moisture regain due to the reduction of BTCA concentration and curing temperature, futhermore an improvement in bending and surface properties due to the lubricating effect of silicone. On the other hand 1% aqueous silicone solution showed the lowest surface tension. Such nonionic surface activity resulted in a more uniform and rapid deposition of BTCA on the fiber or fabric.

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Improvement of hot work environment in the curing processes of a tire manufacturing company (타이어 제조공장 가류공정의 온열환경 개선에 관한 연구)

  • Lim, Jung-ho;Kim, Tae-Hyeung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.21 no.1
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    • pp.1-10
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    • 2011
  • Generally, the tire curing process is the process in which the sulfur is added and subsequently the tire is heated to give the tire elasticity. In this process, all kinds of the chemicals in the tire are emitted with a lot of heat. The chemical fume and heat aggravate the work environment. To solve this problem, 92 local exhaust ventilators and 8 gravity ventilators were used, but not satisfactory yet. Preliminary survey showed that the temperatures in the process were very high: 30.3, 32.9 and $37.2^{\circ}C$ at 2, 4 and 6m above the ground level, respectively in the winter (outside temperature was $2^{\circ}C$). It can be imagined that the process is severely hot in the summer time. The higher temperature distribution in the higher space tells us that the hot plume could not be removed with the existing ventilation systems. Therefore, in this study, some alternative ventilation systems were designed. The partitions were used to contain the hot plume to increase the capture efficiency. The gravity ventilators were newly designed to improve the extraction efficiency of hot fume. To satisfy the balance of pressure in the curing process, some supply air system was introduced by renewing the existing air conditioning system. Many alternative solutions were evaluated by using computational fluid dynamics modelling. The best and applicable solution was selected and the existing ventilation system was modified. After implementing the new ventilation system, the hot environment was much improved. The temperature reduction in the curing process was about $6.4^{\circ}C$.