• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.169-172
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• 2003

Time dependent deflections of double composite box girders are investigated based on the on going laboratory experiments scheduled for 3months long. Two of 2-span double composite box girders with 2.5m each span length are cast and time dependent behaviors are measured using 30 strain gages and 2 LVDTs after 5 days' curing. The measured experimental results are compared with the numerical predictions performed based on the one dimensional finite element method adopting beam element. The FEM formulation adopts the time dependent concrete constitutive model which is derived in an incremental format by expanding the total form of stress-strain relation by the first order Taylor series with respect to the reference time. A good agreement between the measured and predicted results are observed and the effects of the bottom concrete placed at the negative moment region of the bridge girder are discussed.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.04a
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• pp.180-183
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• 2003

In this work. a potential inexpensive epoxy resin. epoxidized soybean oil (ESO) was synthesized and applied as a toughening agent for 4.4'-tetradiglycidyl diaminodiphenyl methane (TGDDM). The chemical structure of ESO was characterized by FT-IR, $^1H NMR, and ^{13}C NMR$ spectroscopy. The curing behaviors. thermal stabilities. fracture toughness. and flexural strength of TGDDM/ESO blend systems were investigated by using the dynamic DSC. thermogravimetric analysis (TGA). and flexural tests. The thermal stabilities of TGDDM/ESO blend systems were decreased with increasing ESO contents. whereas the critical stress intensity factor ($K_{IC}$) and flexural strength ($\sigma_f$) were increased with ESO contents up to 10 wt% ESO.

• Journal of the Korean Graphic Arts Communication Society
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• v.18 no.2
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• pp.113-124
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• 2000

It is well known that the characteristics of liquid crystal polymer composite(LCPC) films are possessed of large-area and flexible display, polarizer free, high contrast, wide angle of visual filed and high responsiveness. In this study, we have investigated to the best optimal mixing rates chiral nematic liquid crystals and UV-curable resins having different properties acrylate moleculars. The purpose of this study has been the development of new functional application with liquid crystal polymer composite films. For example the films were applied a new thermal sensor. In results, best phase separation behaviors turned out liquid crystal/monomer/oilgomer mixture system.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.127-128
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• 2005

UV-curable pressure sensitive adhesives were prepared by blending acrylic copolymer, copolymerized with butyl acrylate (BA), acrylic acid (AA) and vinyl acetate (VAc) by solution polymerization, triethyl amine (TEA) and trimethylolpropane triacrylate (TMPTA). The PSAs were evaluated by peel strength with varying contents of TMPTA and UV dose, and also glass transition temperature($T_g$) of PSAs were measured. When exposed on UV irradiation, the PSAs showed the decreased peel strength and increased $T_g$. And following UV irradiation, the PSAs did not leave any residue on wafer after peel off PSA.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.6
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• pp.9-17
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• 2019

Cement hydrates and the related characteristics change with ages, and the behaviors are much related with chloride diffusion. In this work, 30% replacement ratio with FA(Fly Ash) and GGBFS(Ground Granulated Blast Furnace Slag) are considered for concrete with three levels of W/B (Water to Binder ratio) and 2 years of curing period. Chloride diffusion coefficients from accelerated condition are obtained at 5 measurement period (28days, 56days, 180days, 365days, and 730days), and the results are compared with porosity, binding capacity, and permeability from program-DUCOM. The similar changing pattern between chloride diffusion and permeability is observed since permeability is proportional to the square of porosity. Curing period is grouped into 4 periods and the changing ratios are investigated. Cement hydrate characteristics such as porosity, permeability, and diffusion coefficient are dominantly changed at the early ages (28~56 days), and diffusion coefficient in OPC concrete with low W/B continuously changes to 180days.

• Textile Coloration and Finishing
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• v.29 no.1
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• pp.37-44
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• 2017

An issue of major concern in the utilization of laminated composites based epoxy resin is associated with the occurrence of delaminations or interlaminar cracks, which may be related to manufacturing defects or are induced in service by low-velocity impacts. A strong interfacial filament/brittle epoxy resin bonding can, however, be combined with the high fracture toughness of weak interfacial bonding, when the filaments are arranged to have alternate sections of shear stress. To improve this drawback of the epoxy resin, UV-thermal dual curable resin were developed. This paper presents UV-thermal dual curable resin which were prepared using epoxy acrylate oligomer, photoinitiators, a thermal-curing agent and thermoset epoxy resin. The UV curing behaviors and characteristics of UV-thermal dual curable epoxy resin were investigated using Photo-DSC, DMA and FTIR-ATR spectroscopy. The mechanical properties of UV-thermal dual curable epoxy resin impregnated CF prepreg by UV curable resin content were measured with Tensile, Flextural, ILSS and Sharpy impact test. The obtained results showed that UV curable resin content improves the epoxy toughness.

• International Journal of Highway Engineering
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• v.17 no.6
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• pp.47-54
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• 2015

PURPOSES : The objective of this study is to evaluate the early adhesive characteristic of asphalt emulsions, including polymer-modified emulsions, for chip seals using the surface energy concept, the bitumen bond strength (BBS) test, and the Vialit test. METHODS : Two general methods, the BBS test and Vialit test, were applied to investigate the bond strength and the aggregate loss, respectively. A new theory, the surface free energy (SFE) theory, was used to evaluate the adhesive characteristic between the emulsion and the aggregate. Based on the theory, the contact angles were measured, and then the surface energy components were calculated. Using those components, the work of adhesion (Wa) was calculated for each emulsion. To ensure reliable results, all the tests were performed under the same conditions, i.e., at $25^{\circ}C$ for 240 minutes of curing time. For the materials, three emulsions (CRS-2, CRS-2L, and CRS-2P) and one aggregate type (granite) were employed. RESULTS AND CONCLUSIONS : Under the same conditions, the modified emulsions showed better adhesive characteristics and curing behaviors than the unmodified emulsions. In addition, there was no significant difference between the various modified emulsions. One of the important findings is that the analysis by Wa presents more sensitive results than other methods. The results of the Wa showed that the CRS-2P emulsion has the best adhesive characteristics. Consequently, the use of modified emulsions for chip seals could prevent aggregate loss and allow open traffic earlier.

• Geomechanics and Engineering
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• v.28 no.3
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• pp.255-263
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• 2022

Lime stabilization has conventionally been listed amid the key techniques of chemical stabilization. Replacing lime with sustainable agro-based by-products have gained prominence in recent decades. Bagasse ash (BA) is one such potential alternatives, an industrial waste with abundance in production, and industries exploring sustainable solutions for its safe disposal. Supplementing BA with lime could be an ideal approach to reduce lime consumption. However, suitability of BA and lime for the stabilization of expansive clays, such as black cotton (BC) soil is yet to be explored. This paper therefore aims to investigate the suitability of BA-lime mixtures to stabilize BC soil with emphasis to compaction behaviors and unconfined compressive strength (UCS) using standard laboratory procedures. Suitability of BA-lime mixture is then assessed against addition of calcium sulphate which, from previous experience, is detrimental with lime stabilization. Experimental outcomes nominate 15% BA as the optimum value observed from both compaction and UCS data, while addition of 4% lime to 15% BA showed the best results. Mineralogical and microstructural analysis show the presence of cementitious compounds with addition of lime and calcium sulphate with curing periods. While, formation of Ettringite needles were noted with the addition of calcium sulphate in BA-lime mixtures (at optimum values) after 90-day curing, and UCS results showed a decrease at this point. To this end, addition of BA in lime stabilization showed encouraging results as assessed from the compaction and UCS results. Nonetheless usage of calcium salts, with utmost emphasis on calcium sulphate and equivalent should be avoided.

• Journal of the Korean Geotechnical Society
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• v.22 no.11
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• pp.25-35
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• 2006

This paper investigates the mechanical characteristics of reinforced lightweight soil (RLS) using waste fishing net. RLS used in this experiment consists of dredged soil taken from construction site of Busan New Port, cement, air foam and waste fishing net. Several series of laboratory tests were performed to compare behavior characteristics between RLS and unreinforced lightweight soil, in which the reinforced effect by waste fishing net on RLS was evaluated. The experimental results of RLS indicated that the stress-strain relationship and the unconfined compressive strength are strongly influenced by the content of waste fishing net. Compressive strength of RLS Increased with the increase in curing time and generally increased by adding waste fishing net, but the amount of increase in compressive strength was not proportional to the content of waste fishing net. In this test, the maximum increase in compressive strength was obtained at 0.25% content of waste fishing net. On the other hand, water content of RLS rapidly decreased up to 7 days of curing time and converged to constant value.

• Journal of Adhesion and Interface
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• v.10 no.4
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• pp.191-198
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• 2009

UV-curable aliphatic epoxy acrylates were prepared by the reaction of glycerol diglycidyl ether (GDE) with 2-carboxyethyl acrylate (2-CEA) or 2-hydroxyethyl acrylate (2-HEA). The structures of the epoxy acrylates were characterized by FT-IR, $^1H$-NMR, and $^{13}C$-NMR and the yield was obtained by prep-LC. The UV- and the thermal-curing behaviors of the product were investigated using photo-DSC and DSC, respectively. The reactivity of 2-CEA was higher than 2-HEA and the yield of the product (GEA-C) which was prepared using 2-CEA was about 83%. The maximum UV-curing time ($T_{max}$) of the GEA-C contained non-reactive components and by-product was about 10 seconds. The GEA-C showed low color difference (${\Delta}E^*$), low viscosity, and good thermal stability - its value was 2.51, 192 cps, and $299^{\circ}C$ (at 5% weight loss), respectively. The activation energies ($E_a$) of thermal-curing reaction calculated from Kissinger and Ozawa-Flynn-Wall method were 91~92 kJ/mol.