• Title/Summary/Keyword: Curie point

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Electrical Properties of (Pb, LaITiO$_3$ Thin Films fabricated by Sol-Gel Processing (Sol-Gel 법에 의한 (Pb, La)TiO$_3$ 박막의 전기적 특성)

  • 구본혁;박정흠;장낙원;마석범;박창엽
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.48-51
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    • 1997
  • (Pb. La)TiO$_3$ thin films were fabricated by sol-gel Processing and spin-coated on the Pt substrate. The spin-coated PLT films were sintered at 75$0^{\circ}C$ for 5min by rapid thermal ann La content dependence of the electrical properties of the PLT thin films are discussed. Wit La mole% from 20 to 36mo1e%. the dielectric constant of the PLT thin films decreased f 570. P-E hysteresis loops changed from ferroelectric to paraelectric. and the charge storage charging time decreased. The Curie Point decreased with increasing La content. The leak density also decreased and La 36mo1% species shows mood characteristics less than 10- electric field 500 (KV/cm) Because of the broad range of composition-controlled ferroelectric PLT thin films are suitable for memory application.

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A Study on the Electrical and the Optical Characteristics of W/65/35 PLZT Ferroelectric Thin Films (X/65/35 PLZT 강유전 박막의 전기 및 광학 특성에 관한 연구)

  • Hur, Woon-Haing;Choi, Hyung-Wook;Paik, Dong-Soo;Kim, Jun-Han;Park, Chang-Yub
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.209-211
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    • 1994
  • X/65/35 PLZT ferroelectric thin films were fabricated by sol-gel processing. Thin films were crystallized after rapid thermal processing at $750^{\circ}C$ for 5 min. The microstructure, the relative dielectric constant the curie point, the hysteresis curve and the optical transmittance of thin films were investigated.

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The Electronic Properties of the $BT-(BaNaK)(TiNb)O_3$ System for Lead Free PTC

  • Lee, Mi-Jae;Park, Jeong-Muk;Jeong, Yeong-Hun;Lee, U-Yeong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.12-12
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    • 2009
  • We weal know that PbO was poisonous and prone to volatilize, then to pollute the circumstance and hurt to people, so we should dope other innocuous additives instead of lead to increase Tc of composite PTC material. In order to prepare lead-free $BaTiO_3$-based PTC with middle Curie point, the incorporation on $(BaNaK)(TiNb)O_3$ into $BaTiO_3$-based ceramics was investigated on samples containing 0.05, 0.07 and 0.1mol% of $(BaNaK)(TiNb)O_3$. $(BaNaK)(TiNb)O_3$ was compounded as standby material by conventional solid-state reaction technique. The starting materials were $Na_2O_3$,$K_2CO_3$, $BaCO_3$, $TiO_2$ and $Nb_2O_5$ powder, and using solid-state reaction method, too. The microstructure of samples were investigated by SEM, DSC, XRD and dielectric properties. Phase composition and lattice parameters were investigated by X-ray diffraction. Also, we are measure the resistivity of sintered bodies with calcinations condition.

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Behaviors of Rubber Particles, Lead and Zinc in Atmospheric Particulate Classified by Particle Size Range (대기 부유분진중의 고무성분 및 납과 아연의 입도별 거동)

  • 이용근;원정호;김경섭;황규자
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.2
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    • pp.60-65
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    • 1986
  • Atmospheric particulates were collected at a site near the front gate of the Yonsei University using nine stages Andersen air sampler and the distribution of seasonal particle size was investigated. Rubber, Pb and Zn contents of the collected particulates in each stage were determined. Particle size distribution of atmospheric particulate, which was made by concentration distribution curve method, was usually divided into two groups, course (particles larger than 1 - 2 $\mu m in diameter$) and fine (particles smaller than 1 - 2 \mu m in diameter$) groups, regardless of sampling period. More than 80 percent of the total rubber contents in atmospheric particulates were larger than $5 \mu m$ in diameter, meaning that most of rubber particles were originated from tire tread. After benzene extraction for 4 hrs, the extracts were analyzed by Curie-point pyrolysis gas chromatography for rubber content. Pb and Zn contents were determined by atomic absorption spectroscopy. The annual average concentration of rubber particles was $4.2 \mu g/m^3$, which corresponded to 2.2% of the annual average total suspended particulates. Average concentration of styrene brtadiene rubber was about five times that of natural rubber. Annual average concentrations of Pb and Zn were $1.2 \mu g/m^3 and 0.4 \mu g/m^3$ respectively, which corresponded to about 0.7% and 0.2% of the annual average total suspended particulates.

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Preparation and PTC properties of thin films $BaTiO_3$ ceramic system using RF/DC magnetron sputtering method (RF/DC 마그네트론 스퍼터법을 이용한 $BaTiO_3$계 세라믹 박막의 제조와 PTC특성)

  • 박춘배;송민종;김태완;강도열
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.77-82
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    • 1995
  • PTCR(Positive Temperature Coefficient of Resistivity) thermistor in thin film BaTiO$_{3}$ system was prepared by using radio frequency(13.56 MHz) and DC magnetron sputter equipment. Polycrystalline, surface structure, and R-T(Resistivity-Temperature) characteristics of the specimens were measured by X-ray diffraction(D-Max3, Rigaku, Japan), SEM(Scanning Electron Microscopy: M.JSM84 01, Japan), and insulation resistance measuring system (Keithley 719), respectively. Thin films characteristics of the thermistor showed different properties depending on the substrate even with the same sputtering condition. The thin film formed on the A1$_{2}$O$_{3}$ substrate showed a good crystalline and a low resistivity at below curie point. However, the thin films prepared on slide glass and Si wafer were amorphous. The thicknesses of the three samples prepared under the same process conditions were 700[.angs.], 637.75[.angs.], and 715[.angs.], respectively.

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Sintering and Electric Prooperties of Pb(Zn, Nb)$O_3$-Pb(Ni, Nb))$O_3$-$PbTiO_3$-$PbZrO_3$ System (Pb(Zn, Nb)$O_3$-Pb(Ni, Nb))$O_3$-$PbTiO_3$-$PbZrO_3$계 세라믹스의 소결 및 전기적 특성)

  • 박재성;이기태;남효덕
    • Journal of the Korean Ceramic Society
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    • v.27 no.7
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    • pp.934-942
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    • 1990
  • The quarternary system ceramics 0.5[yPb(Zn1/3Nb2/3)O3-(1-y)Pb(Ni1/3Nb2/3)O3]-0.5[xPbTiO3-(1-x)PbZrO3](PZN-PNN-PT-PZ) was fabricated by the columbite precursor method to obtain a stabilized perovskite structure and by conventional method to evaluate the efficiency of the former methd. Dielectric and piezoelectric properties were investigated and the stability of the perovskite phase was studied as a function of PZN and PT contents and firing temperature. In the samples prepared by the columbite precursor method, the pyrochlore phase, which is detrimental to both the dielectric and piezoelectric properties, was not observed in the absence of PZN, and electric properties were improved even when fabricated at low temperature. By adding PZN, some pyrochlore phase appeared and the morphotropic phase boundary of the samples shifted to more Zr-rich composition. The temperature dependence of piezoelectric constant decreased with the addition of PZN, due to the rising of the Curie point.

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Spin-glass behavior in (A,B)-site deficient manganese perovskites

  • Lee, Kyu-Won;Phan, Manh-Huong;Yu, Seong-Cho;Nguyen Chau;Tho, Nguyen-Duc
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.150-151
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    • 2003
  • In the past years, a giant magnetoresistance (GMR) effect found in perovskite-like structured materials has attracted considerable attention among scientists and manufacturers, since, a practical point of view, the capacity of producing magnetic and sensing sensors. In a stream of this interest, further efforts to understand the underlying mechanism that leads to the GMR effect relative to the correlation between transport and magnetic properties, have been extensively devoted. In these cases, spin-glass-like behaviors are ascribed to the frustration of random competing exchange interactions, namely the ferromagnetic double-exchange interaction between Co$\^$3+/ (or Mn$\^$3+/) and Co$\^$4+/(or Mn$\^$4+/) and the antiferromagnetic one like spins. Noticeably, the distinction of spin-glass region from cluster-glass one, involved in the remarkable changes in transport and magnetic properties at a critical value of doping concentration, was observed. Magnetic anomalies in zero-field-cooled (ZFC) magnetization as well as ac magnetic susceptibility below Curie temperature T$\sub$c/ and the charge/orbital fluctuation were also realized. In this work, we present a study of magnetic properties of a deficient manganese perovskites system of La$\sub$0.6/Sr$\sub$x/MnTi$\sub$y/O$_3$, and particularly provide its new magnetic phase diagram.

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A Study on Electric Safety Control Device for Prevention of Over Current and Short Circuit Faults (과전류 및 단락사고 방지용 전기안전 제어장치에 관한 연구)

  • Jo, Si-Hwan;Kwak, Dong-Kurl;Jung, Do-Young;Shim, Jae-Sun;Kim, Jung-Sook
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2100-2101
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    • 2008
  • This paper is studied on a protective control system for electrical fire and electrical faults due to over current or electric short circuit faults by using electrical thermal characteristics of PTC (Positive Temperature Coefficient) thermistor and current response characteristics of high sensitive reed switch. The PTC thermistor has characteristic of positive resistivity temperature coefficient according to the temperature variation, which is construction of a regular square and cube demarcation with BaTiO3_Ceramics of positive temperature coefficient. Also PTC thermistor shows the phenomenon which is rapidly increased in the resistivity if the temperature is increased over Curie temperature point, and reed switch, which is used for electrical fault current sensing devices, have a excellent characteristic of response velocity in degree of ${\mu}s{\sim}ms$ that sensing magnetic flux in proportion to dimension of line current. This paper is proposed on a protective control system use PTC thermistor and reed switch for sensor which is protected from electrical fire due to overload faults or electric short circuit faults. Some experimental results of the proposed electric safety control device are confirmed to the validity of the analytical results.

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General Digital Fuzzy Logic Controller Design For Resonant Inverter (공진형 인버터를 위한 범용 퍼지 논리 제어기 설계)

  • 김태언;김남수;임영도
    • Journal of the Institute of Convergence Signal Processing
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    • v.5 no.1
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    • pp.60-65
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    • 2004
  • Induction heating system is time varying system around curie point. So, it has many troubles which are system shut down and change the load impedance. In this paper has been designed the parallel resonant inverter which controlling the constant power and tracking the load resonant frequency with PLL is possible, in order to minimize switching losses and solve it's many troubles. The current full-bridge type parallel resonant inverter of an induction heating system was composed of IGBT in switching device. For regulating the output power of an induction heating system, the Fuzzy logic controller is used. The Fuzzy controller makes the control signal for a stable power regulating control and when reference is changed, it is superior to adaptability. It has been evaluated a stable behavior for a noise with switching and a load disturbance.

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Comparative analysis of the magnetic and the transport properties of electron- and hole-doped manganite films

  • Kim, K.W.;Prokhorov, V.G.;Flis, V.S.;Park, J.S.;Eom, T.W.;Lee, Y.P.;Svetchnikov, V.L.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.226-226
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    • 2010
  • Microstructure, magnetic and transport properties of as-deposited electron-doped $La_{1-x}Ce_xMnO_3$ and hole-doped $La_{1-x}Ce_xMnO_3$ films prepared by pulse laser deposition, with x = 0.1 and 0.3, have been investigated. The microstructural analysis reveals that the $La_{1-x}Ce_xMnO_3$ films have a column-like microstructure and a strip-domain phase with a periodic spacing of about 3c, which were not found for the $La_{1-x}Ce_xMnO_3$ ones. At the same time, the experimental results manifest that there is no fundamental difference in the magnetic and the transport properties between electron- and hole-doped manganite films, except the appearance of ferromagnetic response in the low-doped $La_{0.9}Ce_{0.1}MnO_3$ film at temperatures above the Curie point. The observed magnetic behavior, typical for the Griffiths-like phase, for this film is explained by the percolation mechanism of the ferromagnetic transition and by the presence of strip-domain phase which stimulates the magnetic phase separation.

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