• Title/Summary/Keyword: Curie Temperature

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Study of Hopkinson Effect in the HDDR-treated Nd-Fe-B-type Material

  • Kwon, H.W.;Shon, S.W.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.397-406
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    • 2000
  • Hopkinson effect in the HDDR-treated Nd$\sub$15/Fe$\sub$77/B$\sub$8/ alloy was examined in detail by means of a thermomagnetic analysis with low magnetic field (600 Oe). The emergence and magnitude of maximum in magnetisation in the thermomagnetic curve due to the Hopkinson effect was correlated to the grain structure and coercivity of the HDDR-treated material. the HDDR-treated materials showed clear Hopkinson effect (maximum in magnetisation just below the Curie temperature of the Nd$\sub$2/Fe$\sub$14/B phase) on heating in the thermomagnetic curve. Magnitude of the magnetisation rise due to the Hopkinson effect became smaller as the recombination time increased. The magnetisation recovery at room temperature on cooling from above the Curie temperature became smaller as the recombination time increased. The HDDR-treated materials with shorter recombination time, finer grain size and higher coercivity showed larger magnetisation maximum due to Hopkinson effect in the thermomagnetic curve.

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Study of the Hopkinson Effect in the HDDR-treated Nd-Fe-B-type Material

  • Kwon, H.W;Shon, S.W
    • Journal of Magnetics
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    • v.6 no.2
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    • pp.61-65
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    • 2001
  • The Hopkinson effect in the HDDR-treated $Nd_{15}Fe_{77}B_8$ allay was examined in detail by means of a thermo-magnetic analysis with low magnetic field (600 Oe). The emergence and magnitude of maximum in magnetisation in the thermomagnetic curve due to the Hopkinson effect was correlated with the grain structure and coercivity of the HDDR-treated material. The HDDR-treated materials showed a clear Hopkinson effect (maximum in magnetisation just below the Curie temperature of the $Nd_2Fe_{14}B\;$ phase) on heating. The magnitude of the magnetisation rise due to the Hopkinson effect became smaller as the recombination time increased. The magnetisation recovery at room temperature on cooling from above the Curie temperature became smaller as the recombination time increased. The HDDR-treated materials with shorter recombination time, finer grain size and higher coercivity showed larger magnetisation maximum due to the Hopkinson effect in the thermo-magnetic curve.

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PRESSURE DEPENDENCE OF THE CURIE TEMPERATURE IN MnAlGe

  • Endo, S.;Matsuzaki, H.;Ono, F.;Kanomata, T.;Kaneko, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.380-382
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    • 1995
  • The pressure dependence of the Curie temperature was determined in 2-dimensional like ferromagnet, MnAlGe up to a maximum pressure of 7.5 Gpa through measurements of electric resistance vs temperature curves. The pressure coefficient was positive with a considerably high rate of 9 K/GPa in the low pressure ragion, while it decreased gradually down to one order of magnitude smaller value at the maximum pressure. It was concluded that ther is an upper limit of about 550 K in the super-exchange type ferromagnetic interaction between Mn layers.

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The Development of PTC Thermistor using a preventive of Over Heating in Electrical-Electronic Machinery and Apparatus (전기-전자기기의 과열 방지용 PTC서미스터 개발)

  • Park, Choon-Bae;Song, Min-Jong
    • Proceedings of the KIEE Conference
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    • 1995.07a
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    • pp.104-106
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    • 1995
  • A curious resistivity anomaly in high curie point barium-lead-titanate materials with positive temerature coefficient of resistivity (PTCR) has been observed just below the curie point, besides the normal PTCR anomaly. The additional resistivity anomaly was observed in the resistivity-temperature characteristics.

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A Study on the Properties of the Magnetic Semiconductor GaMnAs Depending on Thin Film Deposition and the Treatment Conditions (GaMnAs 자성반도체의 박막 특성 및 후처리에 따른 특성 변화 연구)

  • Kim, Dong-Sik
    • 전자공학회논문지 IE
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    • v.45 no.3
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    • pp.1-4
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    • 2008
  • We investigate magnetic semiconductor thin films for application towards spintronics, which can overcome current limitations in semiconductor devices. GaMnAs magnetic semiconducting films studied are easily integrated into conventional semiconductor processes and also offer a wide range of application, therefore it shows much promise as a future material. However the Curie temperature at which magnetic properties exist for GnMnAs is very low, also depending on deposition conditions the properties of the film can vary widely. In order to study these issues we investigate the best possible deposition conditions for magnetic properties.

Microstructure and PTCR Behavior of Semiconducting (1-x)$BaTiO_3$ - x$(Bi_{1/2}K_{1/2})TiO_3$ Ceramics ($BaTiO_3$ - $(Bi_{0.5}Ko_{0.5})TiO_3$계 세라믹의 PTC효과와 미세구조)

  • Park, Yong-Jun;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo;Kim, Dae-Joon;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.336-336
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    • 2008
  • A positive temperature coefficient of electrical resistivity (PTCR) was investigated in a ferroelectric lead-free perovskite-type compound $(Bi_{0.5}K_{0.5})TiO_3$ within $BaTiO_3$-based solid solution ceramics. The electrical properties and the microstructure of (1-x) $BaTiO_3$ - x $(Bi_{0.5}K_{0.5})TiO_3$ (BBKT) ceramics made using a conventional mixed and have been synthesized by an ordinary sintering technique. The Curie temperature was obviously increased with increasing of $(Bi_{0.5}K_{0.5})TiO_3$ content. The BKT ceramics (x=0.05) sintered at $1400^{\circ}C$ for 4h display low resistivity values of $10^1-10^2$ ohm cm at room temperature, PTCR effect(jump) of 1.05*$10^3$, and the Curie temperature of $T_c=141^{\circ}C$.

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$(Bi_{1/2}Na_{1/2})TiO_3$ - system for PTC Thermistor (PTC 써미스터를 위한 $(Bi_{1/2}Na_{1/2})TiO_3\;-\;BaTiO_3$)

  • Paik, Jong-Hoo;Park, Yong-Jun;Kim, Chang-Il;Lim, Eun-Kyung;Lee, Mi-Jae;Lee, Young-Jin;Kim, Dae-Joon;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.251-251
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    • 2007
  • A new type of a lead-free positive temperature coefficient of resistivity(PTCR) material. based on $(Bi_{1/2}Na_{1/2})TiO_3\;-\;BaTiO_3$ solid solution ceramics has been developed. The effect of $Nb_O_5$ and $Y_2O_3$ content on the electrical properties and the microstructure of (1-x) $(Bi_{1/2}Na_{1/2})TiO_3\;-\;x\;BaTiO_3$ (BNBT) ceramics made using a conventional mixed oxide process has been studied. The Curie Temperature was obviously increased with the increasing of $(B_{0.5}Na_{0.5})TiO_3$ content. The Y-doped BNBT ceramics(x=0.02) display low resistivity values of $10^2-10^3$ ohm*cm at room temperature and the Curie Temperature of $Tc=155^{\circ}C$.

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Dielectric Properties of BaTiO3 Substituted with Donor Dopants of Nb5+ and Ta5+

  • Kim, Yeon Jung
    • Journal of the Korean institute of surface engineering
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    • v.54 no.4
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    • pp.178-183
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    • 2021
  • The temperature and frequency dependence of the dielectric constant of the BaTiO3 substituted with two types of donor dopants, Nb5+ and Ta5+, respectively, were compared and analyzed. Dielectric specimens of four specific compositions, Ba0.95Nb0.05TiO3, Ba0.90Nb0.10TiO3, Ba0.95Ta0.05TiO3, and Ba0.90Ta0.010TiO3 were prepared by calcining at 1100 ℃ and sintering at 1300 ℃ to have a perovskite structure to measure capacitance. XRD and SEM analysis were used to observe the structure, with particular focus on the integration into the Nb5+ and Ta5+ substituted BaTiO3 crystal lattice. X-ray diffraction peaks in the (200) and (002) planes were observed between 45.10° and 45.45° of the BaTiO3 solid solution substituted with different fractions of Nb5+ and Ta5+. The dielectric properties were analyzed and the relationship between the properties and structure of the substituted BaTiO3 was established. The fine particles and high density of the substituted BaTiO3 were maintained like pure BaTiO3, and in particular, a shift toward the low temperature side of the phase transition temperature range was clearly found, unlike pure BaTiO3. In addition, the phase transition at a temperature higher than the Curie temperature relatively satisfies the modified Curie-Weiss law.

The Effect of Adittives on the Sintering Properties of Barium Titanate Powder Prepared by Self-propagating High-temperature Synthesis (자전연소합성법에 의해 제조된 BaTiO3 분말의 소결특성에 미치는 첨가제의 영향)

  • Lim Sung-Jae;Shin Chang-Yun;Won Hyung-Il;Won Chang-Whan
    • Journal of Powder Materials
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    • v.13 no.2 s.55
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    • pp.129-137
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    • 2006
  • In this study, high purity fine $BaTiO_3$ powders were prepared by SHS (Self-propagating High-temperature Synthesis). We would examinate the study of sintering properties and characteristics as a function of temperature with various additives (binder, sintering agent). In separately binder addition, the green and sintered density of specimen were increased as binder content increases. The increased porosity resulted in fine grain size due to the inhibition of grain boundary moving. The $Al_{2}O_{3},\;TiO_{2}$ and MgO playa role of increasing dielectric constants at room temperature. These values were decreased at curie temperature. In case of $SiO_2$, the Curie temperature was decreased. In this study, a high dielectric ceramic capacitor material with temperature stability was synthesized by using various additives.

The Phase Transition of Pb5Ge3O11 Single Crystal by the Thermal Conduction Measurement (열전도 측정에 의한 Pb5Ge3O11 단결정의 상전이)

  • Joung, Maeng-Sig
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.2
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    • pp.165-169
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    • 1999
  • The thermal diffusivity of lead germanate single crystal was measured from room temperture up to the $200^{\circ}C$ by heating method. The thermal diffusivities were measured as k=0.0117, 0.0105, and $0.0112cm^2/^{\circ}C$ at $30^{\circ}C$, $177^{\circ}C$, and $180^{\circ}C$, respectively. It is identified that the heat capacity of the lead germanate single crystal is maximum at $177^{\circ}C$, and this point is phase transition temperature of $Pb_5Ge_3O_{11}$ single crystal.

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