• Title/Summary/Keyword: Cure property

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The Effect of Surface Area of Silicas on Their Reinforcing Performance to Styrene-butadiene Rubber Compounds

  • Ryu, Changseok;Kim, Sun Jung;Kim, Do Il;Kaang, Shinyoung;Seo, Gon
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.128-137
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    • 2016
  • The effect of the surface area of silicas on their reinforcing performance to styrene-butadiene rubber (SBR) compounds was systematically investigated. The feasibility of the Brunauer-Emmett-Teller surface area ($S_{BET}$) as a parameter representing the characteristics of the silicas was discussed compared to the mesopore volume, c value, oil absorption, and uptake of silane. The increase in $S_{BET}$ of silicas caused a considerable increase in Mooney viscosity, minimum torque, and hysteresis loss of the silica-filled SBR compounds, while significantly enhancing their abrasion property. These changes were explained by the attrition between the hydrophilic silica surface and the hydrophobic rubber chains. As expected, the change in $S_{BET}$ did not induce any remarkable changes in the cure, processing, tensile, and dynamic properties of the silica-filled SBR compounds because the crosslinking density of the rubber chains mainly determined these properties.

An Experimental Study on Improving Water Tightness of Concrete Surface Applied High Growth Organic Crystalization Material (고성장 유기결정체의 성장 특성을 이용한 콘크리트 표층부의 수밀성 개선에 관한 연구)

  • Song Je-Young;Kang Hyo-Jin;Oh Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.817-820
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    • 2004
  • Our country was much developments in change of construction environment along with fast economy development. But, various problems that must think in problem of safety and quality were appeared. Constructions which build through rapid economy development are getting many social criticisms to problem of crack and water leakage at use process. Is situation that huge repair expense to cure this is engaged. Safety problem of construction is indicated socially through various media mediums again.

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Strength Properties of the Mortar According to the Curing Condition of the Modified Sulfur Mortar (개질유황 모르타르의 양생조건에 따른 모르타르의 강도특성)

  • Jung, Byeong-Yeol;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.332-333
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    • 2013
  • This research utilizes the modified sulfur having the low melting point which 65℃ is tries to study the strength property of the mortar according to the cure method of the modified sulfur mortar. And we try to use as basic data for investigating the curing condition of the light panel optimum utilizing the modified sulfur. We experimented by five kinds; 20℃ water curing method and 20, 40, 60, 80(℃) air dry curing method. In 3 day curing, the compressive strength was improved caused by high curing temperature. But the compressive strength was degraded caused by enhanced temperature in 7day curing and 28day curing. Therefore, the curing temperature of the modified sulfur mortar is determined that it comes 20 time case curing and the water curing is the most recommendable.

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Water and Oil Repellency of Wool Fabric Treated with Nano-type Finishing Agent (Wool 직물의 나노 발수 발유가공)

  • Choi, Bo-Ryun;Han, Sam-Sook;Lee, Mun-Cheul
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.26-34
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    • 2008
  • Wool fabric having high moisture content were treated with fluorocarbon-based water and oil repellent finishing agents by pad-dry-cure system. Three types of finishing agents which were regular-type or nano-type were adapted to compare the surface chemical composition, water and oil repellent property, crease recovery angle, and durability to repeated laundering. From the surface chemical compositions resulted by ESCA and C1s curve-fitting, it was shown that the regular-type finishing agent were easily taken off from the finished wool fabrics after repeated laundering. On the other hand, the fluoroalkyl groups of nano-type finishing agents turned round from fabric surface to fiber internal after repeated laundering. The water repellency of the wool fabrics treated with regular-type agent had a little changes according to the treatment condition changes and sharply decreased with repeated laundering. However, these values when treated with nano-type agents increased with the concentration and cure temperature and were maintained after 20 times laundering. The wool fabrics treated with nano-type agent had a great oil repellency irrespective of treatment conditions. Furthermore, the wrinkle recovery values of the wool fabrics treated with nano-type agents were higher than those of the fabrics treated with regular-type agent and were unchanged after 20 times laundering.

Effect of The activating blood flow and removing blood stasis Method to Prostatic disease (전립선(前立腺) 질환(疾患)에 대한 활혈거어법(活血祛瘀法)의 효과(效果))

  • Song, Bong-Keun;Kim, Joong-Kil;Park, Seung-Won;Song, Un-Yong;Jeong, In-Seok
    • The Journal of Internal Korean Medicine
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    • v.21 no.4
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    • pp.615-619
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    • 2000
  • Objective : The prostatic disease is characterized as relatively incurable, chronic and recurrent illness. Because of this property, we have the difficulty in treating this illness. Besides, the drug selectivity is restricted to the specific prostatic membrane, the barrier of prostate. This study was to evaluate the efficency of the activating blood flow and removing blood stasis Method to Prostatic disease. Methods : We investigated 51 prostatic patiens with NIH chronic prostatitis symptom index, digital rectal examination(DRE), expressed prostatic secretion(EPS). After investigation we treated the patients with herb which was aimed to activate the blood flow and remove the blood stasis method to prostatic disease. Results : After the treatment, symptom index score of the prostatic patients was reduced from 11.7 to 7.4. The cure rate of 51 prostatic patients was 76.5%. Also the cure rate of the patients who was treated over 4 weeks was higher than the patients treated below 4 weeks, 87.5% to 66.7% respectively. conclusions : These results indicate that oriental medical theraphy is useful enough to treat the prostatic patients. Therefore, the more research about the herb which has activating blood flow and removing blood stasis effect is necessary.

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A study on the Damping Properties of NR Vulcanizates. (천연(天然)고무의 Damping Property에 관(關)한 연구(硏究))

  • Choi, Jae-Woon;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.20 no.3
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    • pp.189-204
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    • 1985
  • The purpose of this study is to examine the dynamic properties, especially the damping and fatigue properites, of NR vulcanizates and to find out the vulcanizate which can be used as damping materials in industry. The results of this study can be summarized as follows: 1. In the ODR test, the S-2 vulcanizate was the fastest one in terms of having reached to optimum cure times($t_{90}$) and, with the same formula, when 50phr of HAF carbon black loaded, the shortest optimum cure times has shown. 2. The S - 2 vulcanizate was the best than the others in the physical properties. In aging properties, however, the E - 1 vulcanizate appeared to be better than the other vulcanizates. 3. The results of the RDS test for the NR vulcanization system under the condition of 0.1% strain amplitude and 1 Hz frequency showed no connection between Tg and the the nature of the crosslinking system, but 50phr loading of HAF carbon black increased Tg. The damping values of vulcanizates in the elastic region showed a strong relations the damping values and the crosslinking system. The S - 2 vulcanizate with higher crosslink density had lower damping values than other vulcanizates, and furthermore, the SH - 2 vulcanizates with 50phr loading of HAF carbon black increased the damping values. 4. The Goodrich Flexometer test showed that the heat buildup for the gum NR vulcanizates was less than for those which contained 50phr of HAF carbon black. In particular, the fatigue life of the vulcanizate with lower damping values appeared to be longer than that of the vulcanizates with higher damping values. In the fatigue test, the increasment of the loading or the temperature, applied to the vulcanizates, appeared to be shorten their fatigue life.

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Effect of Acrylonitrile-Butadiene Rubber on the Properties of Silica-Filled Styrene-Butadiene Rubber Compounds: Reduction of Silane Coupling Agent and Diphenylguanidine (실리카로 보강된 SBR 배합물의 특성에 미치는 NBR 효과: 실란커플링제와 DPG의 사용량 감소)

  • Choi, Sung-Seen;Chang, Dong-Ho;Kim, Ik-Sik
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.217-223
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    • 2002
  • Silica-filled rubber compounds show poor filler dispersion and slow cure characteristics compared to carbon black-filled ones. In general, a silica-filled rubber compound contains silane coupling agent (bis-(3-(triethoxysilyl)-propyl)-tetrasulfide, TESPT) and diphenylguanidine (DPG) to improve the filler dispersion and to make fast cure characteristics. Acrylonitrile-butadiene rubber (NBR) improves the filler dispersion in silica-filled styrene-butadiene rubber (SBR) compounds. In this study, effect of NBR on the properties of silica-filled SBR compounds was investigated. Properties of the compounds which contain NBR without DPG or with small amount of TESPT (Compound A) were compared with those of the compounds which contain TESPT and DPG without NBR (Compound B). Scorch time of Compound A is faster than those of Compound B. Modulus and tensile strength of Comound A are slightly lower than those of Compound B. Traction property of the Comound A is better than that of the Compound B. Addition of NBR leads to reduction of the used amount of TESPT and DPG.

A Review on the Relationship of the Life Salvage and its Remuneration (해상인명구조와 보상체계에 관한 고찰)

  • Lee, Jung-won
    • Journal of Legislation Research
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    • no.53
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    • pp.491-524
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    • 2017
  • Under the general maritime law, a life salvor has no claim against the person saved, and a pure life salvor has no right to compensation from the owner of the ship or its cargo. This harsh rule, which treats the salvor of life less generously than the salvor of property, has been modified by international conventions, statutes, so that life salvors may expect a reward in most cases. It is, especially, unreasonable that a prerequisite of a salvage award is that at least some of the property must be saved, because life of a person can not be compared to values of goods such as vessels and cargoes. Also it is not understandable that only pure life salvors can not expect a reward for the saving of life from the owners of the property. In the meantime, according to Article 39 of the Korean Maritime Search and Rescue Act (hereunder, KMSARA), any person who has gave assistance and rescued in accordance with a governmental officer's order may get a compensation for their time and labour. The above mentioned compensation which is stemmed from the KMSARA may play a role as a compliment for the lack of enough compensation to a life salvor. This means that even though a life salvor failed to save property, he may expect a minimum compensation from the KMSARA. However, it should be recognized that when a life salvor is entitled to both remuneration for the salvage of life and recourse of expenditures from the KMSARA, the total remuneration shall be paid only if and to the extent that such remuneration is greater than any reward recoverable by the salvor under the Korean Commercial Code and the KMSARA.

Development of Pilot-Scale Manufacturing Process of SiC Fiber from Polycarbosilane Precursor with Excellent Mechanical Property at Highly Oxidation Condition and High Temperature (폴리카보실란 전구체로부터 고온 산화성분위기서 기계적물성이 우수한 파이롯-규모의 탄화규소섬유 제조공정 개발)

  • Yoon, B.I.;Choi, W.C.;Kim, J.I.;Kim, J.S.;Kang, H.G.;Kim, M.J.
    • Composites Research
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    • v.30 no.2
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    • pp.116-125
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    • 2017
  • The purpose of this study is to develop silicon carbide fiber showing an excellent mechanical properties under highly oxidative conditions at high temperature. Polycarbosilane(PCS) as a preceramic precursor was used for making the SiC fiber. PCS fiber was taken by melt spinning method followed by melting the PCS at $300{\sim}350^{\circ}C$ in N2 gas. The Curing of PCS fiber was carried out in air oxygen chamber, prior to high temperature pyrolysis. Degree of cure was calculated by characteristic peak's ratio of Si-H to $Si-CH_3$ in FT-IR spectra before and after curing of PCS fiber. The properties of SiC fiber was affected greatly by the degree of cure. The SiC fiber produced by controlling fiber tension during heat treatment showed good properties. The SiC fiber exposed to $1000^{\circ}C$ at air from 1 min. up to maximum 50 hrs showed around 60% reduction in tensile strength. We found that large amount of carbon content on the fiber surface after long-term exposure has resulted in lower tensile strength.

Effect of Urethane Modification on the Anti-Bullet Property of Dyneema/vinylester Composites (우레탄 수지 첨가에 의한 다이니마/비닐에스터 복합재료의 방탄효과 향상 연구)

  • Yoon, T.H.;Cha, Y.M.;Yuck, J.I.;Paik, J.G.;Oh, Y.J.;Kim, H.J.
    • Composites Research
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    • v.24 no.6
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    • pp.7-11
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    • 2011
  • Polyurethane oligomers (PUOs) such as UA8297, UP127 and EB8200 were utilized to enhance the anti-bullet property of Dyneema$^{(R)}$/vinylester composites. First, prepregs of PUO and vinylester (XSR10) were prepared via spray coating on Dyneema$^{(R)}$ fabric at 21 % resin content (by volume). In addition, spray coating and film lamination were also carried out with a mixture of XSR10/PUO for selected PUOs. Next, the prepregs were dried at RT for 1-2 h and then at $100^{\circ}C$ for 30 min to remove the solvent and to provide partial cure when necessary. The prepregs were stacked in 24 layers and cured at $120^{\circ}C$ for 5 min under the contact pressure and for additional 25 min at 150 $kg/cm^2$. Finally, the anti-bullet properties of composite samples were evaluated by measuring $V_{50}$ with simulated fragment projectile (SFP, 17 gr). The results showed a 6.5 and 9.0 % increase of $V_{50}$ with UP127 and EB8200, respectively.