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Effect of Urethane Modification on the Anti-Bullet Property of Dyneema/vinylester Composites

우레탄 수지 첨가에 의한 다이니마/비닐에스터 복합재료의 방탄효과 향상 연구

  • Received : 2011.06.14
  • Accepted : 2011.12.13
  • Published : 2011.12.31

Abstract

Polyurethane oligomers (PUOs) such as UA8297, UP127 and EB8200 were utilized to enhance the anti-bullet property of Dyneema$^{(R)}$/vinylester composites. First, prepregs of PUO and vinylester (XSR10) were prepared via spray coating on Dyneema$^{(R)}$ fabric at 21 % resin content (by volume). In addition, spray coating and film lamination were also carried out with a mixture of XSR10/PUO for selected PUOs. Next, the prepregs were dried at RT for 1-2 h and then at $100^{\circ}C$ for 30 min to remove the solvent and to provide partial cure when necessary. The prepregs were stacked in 24 layers and cured at $120^{\circ}C$ for 5 min under the contact pressure and for additional 25 min at 150 $kg/cm^2$. Finally, the anti-bullet properties of composite samples were evaluated by measuring $V_{50}$ with simulated fragment projectile (SFP, 17 gr). The results showed a 6.5 and 9.0 % increase of $V_{50}$ with UP127 and EB8200, respectively.

우레탄 수지 첨가에 의한 다이니마/비닐에스터 복합재료의 방탄효과 향상을 고찰하였다. 첫째로 우레탄 수지와 비닐에스터 수지를 스프레이 코팅하여 프리프레그를 제조하였으며, 수지함량을 21%로 조절하였다. 또한 혼합수지를 스프레이 코팅과 필름코팅으로 비교를 위한 프리프레그를 제조하였다. 그 다음 이들을 상온에서 1-2시간, 그리고 필요시 $100^{\circ}C$ 30분 정도 건조시켰다. 이들 프리프레그를 24층 적층한 다음 $120^{\circ}C$에서 5분 동안 정치 시킨 후 25분 동안 150 $kg/cm^2$ 압력하에서 경화 시켰다. 모의 파편탄(17 gr)을 이용하여 이들 복합재료의 방탄성능($V_{50}$)를 측정하였으며, UP127 및 EB8200으로 제조된 시편은 XSR10으로 제조된 시편에 비하여 각각 6.5 및 9.0 % 향상된 값을 보였다.

Keywords

References

  1. http://en.wikipedia.org/wiki/Bullet-proof_vest
  2. 김희재, 방탄공학, 청문각, 2004.
  3. Garcia, J.M., Garcia, F.C., Serna, F., and de la Pena, J.L., "High-performance aromatic polyamides," Progress in Polymer Science, Vol. 35, No. 5, 2010, pp. 623-686. https://doi.org/10.1016/j.progpolymsci.2009.09.002
  4. Chodák, I., "High modulus polyethylene fibres: preparation, properties and modification by crosslinking," Progress in Polymer Science, Vol. 23, No. 8, 1998, pp. 1409-1442. https://doi.org/10.1016/S0079-6700(98)00006-9
  5. Dong, Z., and Sun, C.T., "Testing and modeling of yarn pull-out in plain woven Kevlar fabrics," Composites Part A: Applied Science and Manufacturing, Vol. 40, No. 12, 2009, pp. 1863-1869. https://doi.org/10.1016/j.compositesa.2009.04.019
  6. Samara, A.Z., Harel, H., Marom, G., and Yavin, B., "Polyethylene/polyethylene composite materials of ballistic protection," SAMPE J., Vol. 33, No.4, 1997, pp 72-75.
  7. Briscoe, B.J., and Motamedi, F., "The ballistic impact characteristics of aramid fabrics: The influence of interface friction," Wear, Vol. 158, No. 1-2, 1992, pp 229-247. https://doi.org/10.1016/0043-1648(92)90041-6
  8. 최신 섬유기술동향, 한국섬유산업연합회, 2007.
  9. Rao, M.P., Duan, Y., Keefe, M., Powers, B.M., and Bogetti, T.A., "Modeling the effects of yarn material properties and friction on the ballistic impact of a plain-weave fabric," Composite Structures, Vol. 89, No. 4, 2009, pp. 556-566. https://doi.org/10.1016/j.compstruct.2008.11.012
  10. http://www.dyneemamatters.com/about_dyneema_ud?category_id=28
  11. 하헌승, 이태상, 육종일, "다공성/고강도 특수기능 경량소재개발," 국방과학연구소, 2005.
  12. MIL-DTL-44050B; Cloth, Ballistic, Aramid.
  13. Karahan, H., Kuş, A., and Eren, R., "An investigation into ballistic performance and energy absorption capabilities of woven aramid fabrics," International Journal of Impact Engineering, Vol. 35, No. 6, 2008, pp. 499-510. https://doi.org/10.1016/j.ijimpeng.2007.04.003
  14. 이승구, 박종규, 윤영주, 육종일, "케블라/PVB 변성 페놀 복합재료 경화거동," 한국복합재료학회지, 제5권 제1호, 1992, pp. 476-485.
  15. Ahmad, M.R., Yunus, W., Ahmad, W., Jamil Salleh, J., and Samsuri, A., "Effect of fabric stitching on ballistic impact resistance of natural rubber coated fabric systems," Materials & Design, Vol. 29, No. 7, 2008, pp. 1353-1358. https://doi.org/10.1016/j.matdes.2007.06.007
  16. Gryshchuk, O., Jost, N., and Karger-Kocsis, J., "Toughening of vinylester-urethane hybrid resins by functional liquid nitrile rubbers and hyperbranched polymers," Polymer, Vol. 43, No. 17, 2002, pp. 4763-4768. https://doi.org/10.1016/S0032-3861(02)00314-2
  17. Lin, S.P., Shen, J.H., Han, J.L., Lee, Y.J., Liao, K.H., Yeh, J.T., Chang, F.C., and Hsieh, K.H., "Volume shrinkages and mechanical properties of various fiber-reinforced hydroxyethyl methacrylate-polyurethane/unsaturated polyester composites," Composites Science and Technology, Vol. 68, No. 3-4, 2008, pp. 709-717. https://doi.org/10.1016/j.compscitech.2007.09.017
  18. Lin, S.P., Han, J.L., Yeh, J.T., Chang, F.C., and Hsieh, K.H., "Composites of UHMWPE fiber reinforced PU/epoxy grafted interpenetrating polymer networks," European Polymer Journal, Vol. 43, No. 3, 2007, pp. 996-1008. https://doi.org/10.1016/j.eurpolymj.2006.12.001
  19. Cheeseman, B.A., and Bogetti, T.A., "Ballistic impact into fabric and compliant composite laminates," Composite Structures, Vol. 61, No. 1-2, 2003, pp. 161-173.
  20. http://www.colt.com/mil/M16_2.asp
  21. Iremonger, M.J., and Went, A.C., "Ballistic impact of fibre composite armours by fragment-simulating projectiles," Composites Part A: Applied Science and Manufacturing, Vol. 27, No. 7, 1996, pp. 575-581. https://doi.org/10.1016/1359-835X(96)00029-2
  22. Petrovic, Z.S., and Ferguson, J., "Polyurethane elastomers," Progress in Polymer Science, Vol. 16, No. 5, 1991, pp. 695-836. https://doi.org/10.1016/0079-6700(91)90011-9