• Title/Summary/Keyword: Cu additive

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A Study on the Low-Firing Dielectric Material (저온 소결 유전체에 관한 연구)

  • Lee, Jong-Kyu;Kim, Wang-Sup;Kim, Kyeong-Yong
    • Korean Journal of Materials Research
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    • v.2 no.4
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    • pp.263-269
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    • 1992
  • Low-firing dielectric materials with negative small temperature coefficients were investigated. The newly developed materials are based on Ti$O_2$(100-x)/ CuOx(X=1~5wt%) with small amount of Mn$O_2$ additive. The sample without CuO was not sintered at 90$0^{\circ}C$. As CuO content was increased the sample could be sintered at low temperature. However, the dielectric constant was decreased and the dielectric loss was increased. In the case of adding 3wt% CuO and 0.6wt% Mn$O_2$, the dielectric constant and the Q values appeared very high.

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A Study of Sliding Friction and Wear Properties of Bronze added $Cu_2S$ as Solid Lubricants (고체윤활제 $Cu_2S$첨가 청동의 미끄럼 마찰마모특성 연구)

  • Lee Hanyoung;Kim Taejun;Cho Yongjae
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.60-65
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    • 2004
  • [ $MoS_2S$ ] is a well-known metal sulfide applied as solid lubricants and an additive to prolong the life of sintered bearings under severe conditions. However, the high price of $MoS_2S$ limited its wide application. This study is aimed to investigated the possibility for application to solid lubricants for $Cu_2S$ as a substitute of v. Bronzes added $Cu_2S$ and $MoS_2S$ are produced by powder metallurgy in this study, and then evaluated their friction and wear properties. The sliding wear test using pin-on-disc type machine, was conducted at several sliding speeds for three type test pieces, bronze and bronzes added $Cu_2S/MoS_2$. Addition of $Cu_2S$ to bronze leads to relatively good friction and wear properties, although it is not so good as addition of $MoS_2S$. But the properties of bronze added $Cu_2S/MoS_2$ would be not suitable for the condition under the high sliding speed.

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Electrophoretic Deposition of Superconducting $YBa_2Cu_3O_{7-\delta}$ Films Added with Silver Addition

  • Li, Fenghua;Wang, Jue;Soh, Dea-Wha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.260-261
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    • 2005
  • $YBa_2Cu_3O_{7-\delta}$ superconductor films have been prepared on silver substrates by electrophoretic deposition. As silver does not react with $YBa_2Cu_3O_{7-\delta}$ compound and has little influence on its superconductivity, it is usually doped in $YBa_2Cu_3O_7$ to improve the strength of the material and eliminate micro-cracks. It has been proved that Ag additive can lower the melting temperature of $YBa_2Cu_3O_{7-\delta}$ and act as linking bridge among $YBa_2Cu_3O_{7-\delta}$ particles, thus in this paper Ag doped $YBa_2Cu_3O_{7-\delta}$ thick films are prepared by electrophoretic co-deposition. As there are only some referenced experience formula and models for co-electrophoretic deposition and does not exist unified explanation, the behavior of Ag particles during co-electrophoretic deposition is also studied.

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Synthesis of Cu Nanoparticles through a High-Speed Chemical Reaction between Cuprous Oxide and Sulfuric Acid and Enhancement of Dispersion by 3-Roll Milling (아산화동과 황산간의 고속 화학반응에 의한 미세 Cu 입자의 합성과 삼본밀에 의한 분산성 개선)

  • Chee, Sang-Joo;Lee, Jong-Hyun;Hyun, Chang-Yong
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.125-133
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    • 2016
  • With the aim of using a filler material in a conductive paste, fine Cu nanoparticles were synthesized through the high-speed chemical reaction between cuprous oxide ($Cu_2O$) powder and sulfuric acid in distilled water. Under external temperature of $7^{\circ}C$, sulfuric acid concentration of 48%, and $Cu_2O$ amount of 30 g, the $Cu_2O$ particles were eliminated and slightly aggregated Cu nanoparticles were synthesized. Futhermore, Cu nanoparticles of 224 nm, in which the aggregation between particles was obviousiy much suppressed, were synthesized with the choice of an additive. In the particle sample, occasionally there are coarse particles formed by the aggregation of fine nanoparticles and weak linkages between the nanoparticles. However, the coarse particles were destroyed and the linkages were broken after mixing with a resin formulation, indicating the behavior of untangling the aggregation between nanoparticles.

Studies of Magnetic Properties of Ni-Zn-Cu Ferrite with Low Loss and High Permeability (저손질, 고투자율을 갖는 Ni-Zn-Cu ferrite의 자기적 특성 연구)

  • 김용복;고재귀
    • Journal of the Korean Magnetics Society
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    • v.8 no.2
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    • pp.62-66
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    • 1998
  • We have studied on the magnetic properties of the specimen with additives Bi$_2$O$_3$and$V_2O_5$ that sintered at 900 $^{\circ}C$ for 4 hours for sybthesizing optimal Ni-Zn-Cu ferrite. Curie temperature rises from 240 $^{\circ}C$ to 270 $^{\circ}C$ as Ni contents increase. Magentic maximum induction$(B_m)$ increases from 2650 G to 3300 G, 3500 G in the specimens with $V_2O_5$ and Bi$_2$O$_3$resectively. On the contrary coercive force $(H_c)$ lowers to 2.05 Oe~1.05 Oe. Permeability all increase in the specimen with additives. In the specimen with additive Bi$_2$O$_3$, we have obtained the low relative loss factor of $6.3{\times}10^{-5}~7.84{\times}10^{-5}$ in the range of 1MHz due to increase of resistivity in grain boundary. In the specimen with additive $V_2O_5$ in spite of increase permeability relative loss factor increase of due to decrease of Q-value.

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Toxic Effects of Binary Mixtures of Heavy Metals on the Growth and P Removal Efficiencies of Alcaligenes sp. (Alcaligenes sp.의 생장과 인 제거에 미치는 이종 중금속 혼합의 독성 효과)

  • Kim, Deok Hyun;Yoo, Jin;Chung, Keun Yook
    • Korean Journal of Environmental Agriculture
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    • v.35 no.1
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    • pp.79-86
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    • 2016
  • BACKGROUND: This study was initiated to quantitatively evaluate the effects of five heavy metals on the growth and P removal efficiencies of Alcaligenes sp., known as the Phosphorus Accumulating Organisms (PAOs). It was cultivated in the batch system with five heavy metals, such as Cd, Cu, Zn, Pb and Ni, added in single and binary mixtures, respectively.METHODS AND RESULTS: IC50 (half of inhibition concentration of bacterial growth) and EC50 (half of effective concentration of phosphorus removal Efficiencies) were used to quantitatively evaluate the effects of heavy metals on the growth and phosphorus removal Efficiencies of Alcaligenes sp. In addition, Additive Index Value (A.I.V.) method was used to evaluate the interactive effects between Alcaligenes sp. and heavy metals. As a result, as the five heavy metals were singly added to Alcaligenes sp., the greatest inhibitory effects on the growth and P removal efficiencies of each bacteria was observed in the cadmium (Cd). In the binary mixture treatments of heavy metals, the treatments of lowest IC50 and EC50 were the Cd + Cu treatment. Based on the IC50 and EC50 of the binary mixtures of heavy metals treatments, most interactive effects between the heavy metals were found to be antagonistic.CONCLUSION: Based on the results obtained from this study, it appears that they could provide the basic information about the toxic effects of the respective treatments of single and binary mixtures of heavy metals on the growth and P removal efficiencies of Alcaligenes sp. through further study about the characterization of functional proteins involved in toxic effects of heavy metals.

Magnetic Properties of NiZnCu Ferrite for Multilayer Chip Inductors (칩인덕터용 NiZnCu Ferrite의 자기적 특성 연구)

  • An, Sung-Yong;Moon, Byeong-Chol;Jung, Hyun-Chul;Jung, Hyun-Jin;Kim, Ic-Seob;Hahn, Jin-Woo;Wi, Sung-Kwon
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.58-62
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    • 2008
  • $Ni_{0.4}Zn_{0.4}Cu_{0.2}Fe_2O_4$ ferrite was fabricated by solid stat reaction method and sol-gel method. Because of the drawbacks of each method, we combined these two methods together. We proposed and experimentally verified that nanocrystalline ferrite additive was effective on improving the densification behavior and magnetic properties of NiZnCu ferrites for multilayer chip inductors. The initial permeability of the toroidal core Sample with 20 wt% nanocrystalline ferrite increased from 78.1 to 178.2 as annealing temperature is increased from $880^{\circ}C$ to $920^{\circ}C$. The density, shrinkage and saturation magnetization were increased with increasing annealing temperature, which was attributed to the decrease of additive grain size and increase of sintering density.

Study on the Effect of Alkylamines on Cu Electroplating (구리전해도금에서 알킬아민의 영향 연구)

  • Lee, Jaewon;Shin, Yeong Min;Bang, Daesuk;Cho, Sung Ki
    • Journal of the Korean Electrochemical Society
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    • v.25 no.2
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    • pp.81-87
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    • 2022
  • In this study, the effect of alkylamine on copper electroplating was analyzed using cyclic voltammetry. When water-soluble alkylamines were added to the plating solution, the reduction reaction of Cu2+ was inhibited. The inhibition effect of 1,12-diaminododecane has been investigated at various concentrations and conditions of the plating solution. 1,12-diaminododecane was protonated in the acidic plating solution, and therefore, it did not act as a complexing agent for Cu2+. Accordingly, it was confirmed that the inhibiton effect of 1,12-diaminododecane was attributed to adsorption on the Cu surface. The adsorption of 1,12-diaminododecane exhibits two characteristics: (i) protonation and subsequent electrostatic attraction with anions pre-adsorbed on Cu surface, and (ii) direct adsorption on Cu surface via amine functional group. The adsorbed 1,12-diaminododecane caused three-dimensional growth and grain refining, as well as the inhibition effect, during Cu electroplating.

Effects of Morphologies of Carbon Nanomaterials on Conductivity of Composites Containing Copper/Carbon Nanomaterial Hybrid Fillers (탄소 나노 물질의 형상에 따른 구리/탄소나노물질 하이브리드 필러의 전도성 향상 거동 분석)

  • Lee, Yeonjoo;Hong, Sung-uk;Choi, Hyunjoo
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.435-440
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    • 2018
  • In the present study, we develop a conductive copper/carbon nanomaterial additive and investigate the effects of the morphologies of the carbon nanomaterials on the conductivities of composites containing the additive. The conductive additive is prepared by mechanically milling copper powder with carbon nanomaterials, namely, multi-walled carbon nanotubes (MWCNTs) and/or few-layer graphene (FLG). During the milling process, the carbon nanomaterials are partially embedded in the surfaces of the copper powder, such that electrically conductive pathways are formed when the powder is used in an epoxy-based composite. The conductivities of the composites increase with the volume of the carbon nanomaterial. For a constant volume of carbon nanomaterial, the FLG is observed to provide more conducting pathways than the MWCNTs, although the optimum conductivity is obtained when a mixture of FLG and MWCNTs is used.