• 제목/요약/키워드: Crystal phase

검색결과 1,919건 처리시간 0.031초

Biphenyl thioester 계열 강유전성액정의 합성 및 물성에 관한 연구 (Synthesis and mesomorphic properties of biphenly thioester series in ferroelectric liguke crystal)

  • 전영재
    • 한국재료학회지
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    • 제3권1호
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    • pp.72-83
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    • 1993
  • 비페닐 티오에스터 계열 강유전성 액정물질에 대한 새로운 합성방법이 논의되었다. 합성된 많은 액정물질들은 강유전성 스메틱 C상 뿐만 아니라 키랄네마틱과 스메틱 A상을 나타내었으며, $10^{-8}$C/c$m^2$ 이상의 큰 자발분극을 나타내었다. 이 계열들로써 우리는 비대칭 탄소에 붙은 치환체의 크기와 분극도가 자발분극에 미치는 영향을 조사하였으며 치환체의 크기에 대한 Sc*상의 안정도를 결정할 수 있었다.

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단결정 초내열합금에서 응고속도에 따른 응고 및 공정조직의 형성 거동 (Formation of Solidification and Eutectic Microstructures with Solidification Rates in the Single Crystal Superalloy CMSX 10)

  • 이재현
    • 한국재료학회지
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    • 제18권11호
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    • pp.577-582
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    • 2008
  • Directional solidification experiments were carried out at $1-300\;{\mu}m/sec$ solidification rates in the single crystal superalloy, CMSX 10. The solid/liquid interface morphology changed from planar to dendritic, and the dendrite spacing became finer as the solidification rate increased. The pool size of the ${\gamma}/{\gamma}'$ eutectic, formed between dendrites, reduced as the solidification rate increased. The phase formation temperatures, such as the solidus, liquidus and eutectic, were estimated by differential scanning calorimetry (DSC) analysis. The morphology of the ${\gamma}/{\gamma}'$ phase, known to be eutectic, showed ${\gamma}'$ cells with a $\gamma$ intercellular network, and this ${\gamma}/{\gamma}'$ was composed of coarse and fine ${\gamma}/{\gamma}'$ regions. In this study, it is suggested that the ${\gamma}/{\gamma}'$ phase was a coupled peritectic.The solidification procedure of the ${\gamma}/{\gamma}'$ between dendrites is also discussed.

LCD with Tunable Viewing Angle by Thermal Modulation of Optical Layer

  • Gwag, Jin-Seog;Lee, You-Jin;Han, In-Young;Yu, Chang-Jae;Kim, Jae-Hoon
    • Journal of Information Display
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    • 제10권1호
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    • pp.19-23
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    • 2009
  • In this paper, we review the proposed liquid crystal display (LCD) with a tunable viewing angle consisting of a conventional liquid crystal display (LCD) panel and a thermally variable retardation layer (TVRL) characterized by uniformly aligned LC film with transparent indium-tin-oxide electrodes for Joule heating. In the TVRL, nematic phase is transitioned into isotropic by Joule heating. The numerical calculation showed that the intrinsic wide viewing angle was achieved at the isotropic phase of the TVRL by Joule heating, whereas the narrow viewing angle was obtained at the nematic phase of the TVRL. The simulated and experimental results of the proposed LCD show continuous and symmetrical viewing angle characteristics by tuning the retardation of TVRL using Joule heating. The structure of the viewing angle control proposed here is adoptable to all LCD modes with wide viewing angle characteristics.

Fabrication of Single Crystal Poly(3,4-ethylenedioxythiophene) Nanowire Arrays

  • Cho, Bo-Ram;Sung, Myung-M.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.537-537
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    • 2012
  • We have studied a fabrication of vapor phase polymerized Poly(3,4-ethylenedioxythiophene) (PEDOT) nanowire arrays for the first time. The vapor-phase polymerization (VPP) technique is a bottom-up processing method that utilizes the organic arrangement of macromolecules to easily produce ordered aggregates, including on the nanoscale, or prepare thin films of self-assembled molecules, micropatterns, or modified microstructures of pure conducting polymers. Also, liquid-bridge-mediated nanotransfer molding (LB-nTM), which was reported as a new direct patterning method recently, is for the arrayed formation of two- or three-dimensional structures with feature sizes as small as tens of nanometers over large areas up to 4 inches across and is based on the direct transfer of various materials from a mould to a substrate through a liquid bridge between them. The PEDOT nanowires grown by VPP method and transferred on a substrate to use LB-nTM method have been fabricated to single crystal PEDOT nanowires investigated Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Selected Area Electron Diffraction (SAED), X-Ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and electrical properties.

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표면상변이의 강인력 의존성 : 분배함수로 부터의 고찰 (On strong interaction dependence of the surface phase transition : Consideration through the partition function)

  • Cheol Ho Kim;Bo Seung Hwang
    • 한국결정성장학회지
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    • 제11권6호
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    • pp.264-268
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    • 2001
  • 표면계의 분배함수를 적절히 계산하여 유도하였다. 흡착등온식을 유도하였다. 유도된 흡작등온식의 분석을 통하여 표면상변이 현상은 흡착분자간에 강한 인력이 존재할 때 일어나는 것임을 보였다. 얻어진 이론적 결과는 실험 사실을 잘 설명한다는 것을 알수 있었다.

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Bariun Titanate를 고상반응으로 합성할 때 수반하는 팽창과 상과의 관계 (Volume Expansion and Crystal Phase in Solid-Solid Reaction of BaTiO3)

  • 이응상;임대영
    • 한국세라믹학회지
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    • 제24권1호
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    • pp.41-46
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    • 1987
  • When barium titanate was synthesized in soild-solid reaction the abnormal expansion occurred from 900$^{\circ}C$ to 1100$^{\circ}C$. The equi-molecular mixture of BaCO3 and TiO2 was sintered from 800$^{\circ}C$ to 1300$^{\circ}C$ on the condition of air, vacuum and CO2 atmosphere. After that the specimens were tested closely with XRD, Dilatometer, SEM and EDS. The result indicated that; 1. The crystal phase which was concerned with expansion of BaTiO3 was Ba2TiO4 as the intermediate crystal phase. 2. The formation of Ba2TiO4 was affected by the firing atmosphere. 3. The expansion occurred when BaTiO3 changed to Ba2TiO4 and pore also expanded by the expansion of BaTiO3 body just as the model of expansion.

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Simultaneous Control of Phase Transformation and Crystal of Amorphous TiO2 Coating on MWCNT Surface

  • Cha, Yoo Lim;Park, Il Han;Moon, Kyung Hwan;Kim, Dong Hwan;Jung, Seung Il;Yoon, Young Soo
    • 한국세라믹학회지
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    • 제55권6호
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    • pp.618-624
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    • 2018
  • We developed a mass production method that simultaneously controls the phase transformation and crystal size of $TiO_2$ coatings on multiwalled carbon nanotubes (MWCNTs). Initially, MWCNTs were successfully coated with amorphous 15-20-nm-thick $TiO_2$ by an in-situ sol-gel method. As the calcination temperature increased in both air and argon atmospheres, the amorphous $TiO_2$ was gradually transformed into the fully anatase phase at approximately $600^{\circ}C$, a mixture of the anatase and rutile phases at approximately $700^{\circ}C$, and the fully rutile phase above approximately $800^{\circ}C$. The crystal size increased with increasing calcination temperature. Moreover, above $600^{\circ}C$, the size of crystals formed in air was approximately twice that of crystals formed in argon. The reason is thought to be that MWCNTs, which continuously supported the stresses associated with the reconstructive phase transformation, disappeared owing to complete oxidation in air at these high temperatures.

Synthesis and characterization of powders in the La-Al-Si-O system

  • Kyoung Jin Kim;Kwang Suk Joo;Kun Chul Shin;Keun Ho Auh;Kyo Seon Kim
    • 한국결정성장학회지
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    • 제9권5호
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    • pp.475-479
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    • 1999
  • Langasite ($La_{3}Ga_{5}SiO_{14}$) was found to have wide application as a promising piezoelectric material. It has high thermal stability of the frequency and large electromechanical coupling factor. For the further development of new compounds with langasite type structure, powders in the La-Al-Si-O system were synthesized by a modified Pechini process. The evolution of the crystalline phase during calcination was studied using TG-DTA, XRD and TEM for the precursor powders. Decomposition proceeded via dehydration and removal of excess solvents at low temperatures ($T<500^{\circ}C$), followed by the crystallization of lanthanum aluminum silicate ($T>800^{\circ}C$) and phase transformation to $LaAlO_{3}$ phase ($T>1200^{\circ}C$). Transmission electron microscopy (TEM) of the calcined powders showed diffuse hollow rings corresponding to an amorphous phase at $800^{\circ}C$ and clear diffraction patterns corresponding to a crystalline phase from the P321 space group ($T<1200^{\circ}C$) and the R3m ($T<1200^{\circ}C$).

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압전 수정 결정 미량 천평[PZ QCM] 바이오센서의 원리와 응용 (The Theory and Application or Piezoelectric Quartz Crystal Microbalance[PZ QCM] for Biosensor)

  • 김의락
    • KSBB Journal
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    • 제18권2호
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    • pp.79-89
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    • 2003
  • This article contains an overview of acoustic wave devices, the theory and application of piezoelectric quartz crystal microbalances(PZ QCM), clinical analysis, gas phase detection, DNA biosensors, drug analysis, food microbial analysis and environmental analysis.

랜덤 위상 마스크를 이용한 광 메모리에서의 암호화 특성 (Characteristics of encryption in optical memory using random phase mask)

  • 최진산;양병춘;이병호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
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    • pp.1128-1130
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    • 1999
  • Optical encoding method of images using random-phase encoding in both input and Fourier Planes was proposed by Javidi and his group, and the method was realized experimentally by Singh and his group with use of a photorefractive crystal and a phase conjugate wave.[1-2] Recently various techniques have been proposed theorically and experimentally. These include the method using one random-phase mask in the Fourier plane or two random-phase masks in the input and the Fresnel planes.[3] We demonstrate the difference and the problem of the methods using one or two random-phase masks in the Fourier or Fresnel plane. We perform the encoding and decoding in $LiNbO_3$ crystal using degenerate four-wave mixing.

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