• Title/Summary/Keyword: Crystal phase

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Study on the crystallization of quartz glass crucibles for preparation of single crystal silicon (단결정 실리콘 제조용 석영유리도가니의 결정화에 대한 연구)

  • Lim, Jong Won;Kim, Tae Huei;Park, Kyung Bong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.99-105
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    • 2018
  • In order to avoid un-uniform crystallization on the surface of a quartz glass crucible that is known to affect the production yield of the single crystal silicon, Ba (barium) was selected as a crystallization promotor and the inner surface of the crucible was coated using Ba (barium hydroxide octahydrate)-solution by the spray pyrolysis method. For un-coated crucible, it was found that the crystallization of its surface started at $1350^{\circ}C$, and at $1450^{\circ}C$ the surface was uniformly crystallized with ${\beta}$-cristobalite phase. It was found that the crucible coated with Ba began to be crystallized from $1000^{\circ}C$ and was uniformly crystallized on the crucible surface at $1300^{\circ}C$. In this case, ${\alpha}$-cristobalite and needle-shaped $BaSi_2O_5$ phase were created and disappeared as a crystal phase, and the ${\beta}$-cristobalite phase was eventually evenly distributed over the Ba-coated crucible surface.

Phase change of calcium carbonate crystals by adding additives (첨가제 첨가에 의한 탄산칼슘 결정의 상변화)

  • Han, Hyun-Kak;Kwon, Chil-Sun;Jeon, Je-Sung;Choi, Im-Jeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.10
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    • pp.4069-4074
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    • 2010
  • Phase change of calcium carbontae crystals in crystallization of precipitated calcium carbonate was researched by adding additives such as ethylenediaminetetraacetic acid(EDTA), diethylenetriaminepentaacetic acid(DTPA), citric acid(CIT) and pyromellitic amid(PMA). At low temperature $20^{\circ}C$, calcite crystal was made. At high temperature $80^{\circ}C$, aragonite crystal was made without additives. At middle temperature $40^{\circ}C$ and $60^{\circ}C$, Aragonite crystal also made by adding EDTA, DTPA. The crystal growth of Aragonite was retarded by the presence of CIT, PMA and the single phase of calcite was made. It was found that additives were important factors to make the single phase of calcium carbonate.

Preparation and characterization of silanized-hydroxypropyl methylcellulose/phase transformed calcium phosphate composite bone cements (실란처리된 하이드록시프로필 메틸셀룰로오스/상전이된 칼슘포스페이트 복합체 골시멘트의 제조 및 특성평가)

  • Jeong, Nahyun;Kim, Dong-Hyun;Cho, Hoon-Sang;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.6
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    • pp.243-251
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    • 2016
  • Silanized-hydroxypropyl methylcellulose (Si-HPMC)/phase transformed calcium phosphate (PTCP) composites are prepared to purpose application of injectable bone cements with enhanced biocompatibility. The crystal structure and chemical state of the synthesized PTCP and Si-HPMC as solid and liquid phase of the composite cements were measured by XRD and FT-IR. The handling and mechanical properties of cements were measured by injectability tests and three-point bending tests. The in-vitro mechanical properties, XRD, and SEM results of bone cements were showed that enhanced hardening behavior was an inherent function of bone cements after in-vitro test. The cytotoxicity result of bone cements also was showed enhanced biocompatibility. Therefore, these injectable cements had potential be used as calcium phosphate cements for biomedical applications.

Phase transition of indium hydroxide to indium oxide at low temperatures (저온에서의 indium hydroxide에서 indium oxide로의 상전이)

  • Choi, Eun-Kyoung;Lee, Won-Jun;Han, Kyu-Sung;Kim, Ung-Soo;Kim, Jin-Ho;Hwang, wang-Teak;Hwang, Hae-Jin;Shim, Kwang-Bo;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.2
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    • pp.91-97
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    • 2018
  • Indium hydroxide powder was prepared by precipitation method. The reaction temperature ($150{\sim}250^{\circ}C$) and the holding time at each reaction temperature (1~72 h) were used as experimental variables. The particle size, microstructure and crystal phase of each prepared powder were observed through X-ray diffraction (XRD), Transmission electron microscope (FE-TEM) and BET. In this study, we investigated the phase and microstructural change induced by heat treatment of indium hydroxide nanoparticles at various temperatures for different holding times.

Characteristics of Free-Standing GaN Substrates grown by Hydride Vapor Phase Epitaxy (Hydride Vapor Phase Epitaxy 법으로 성장된 Free-Standing GaN 기판의 특성에 관한 연구)

  • Kim, Hwa-Mok;Choe, Jun-Seong;O, Jae-Eung;Yu, Tae-Gyeong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.3
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    • pp.14-19
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    • 2000
  • Free-standing GaN single crystal substrates have been obtained by growing thick GaN epitaxial layers on (0001) sapphire substrates using hydride vapor phase epitaxy (HVPE) method. After growing the GaN thick film of 200 ${\mu}{\textrm}{m}$, a free-standing GaN with a size of 10 mm $\times$10 mm were obtained by mechanical polishing process to remove sapphire substrate. Crack-free GaN substrates have been obtained by GaCl pre-treatment prior to the growth of GaN epitaxial layers. Properties of free-standing GaN substrates have been compared with those of lateral epitaxial overgrowth (LEO) GaN films by double-crystal x-ray diffraction (DC-XRD), cathodoluminescence (CL) and photoluminescence (PL) measurements.

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Growth and structural properties of ZnO co-doped Er :$ LiNbO_3$ thin films by liquid phase epitaxy method (LPE법에 의한 ZnO co-doped Er :$ LiNbO_3$, 박막의 성장 및 구조적 특성)

  • 심장보;전원남;윤석규;윤대호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.27-30
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    • 2002
  • ZnO co-doped Er:$LiNbO_3$ single crystal thin films have been grown on $LiNbO_3$ (001) substrate by liquid phase epitaxy (LPE) method. The melts of ZnO co-doped Er:$LiNbO_3$ was fixed $Er_2O_3$, concentration (1 mol%) and different ZnO concentrations 3 and 5 mol%. The crystallinity of ZnO co-doped Er :$LiNbO_3$ films became better than the $LiNbO_3$ substrate. At ZnO 5 mol% concentration, the surface of ZnO co-doped Er:$LiNbO_3$ film is affected by compressive stress along both the perpendicular and the parallel direction. Also the surface of ZnO 3 mol% co-doped Er:$LiNbO_3$film is smoother than the original $LiNbO_3$ substrate surface.

A Design of Beam Steeringn-phase OPTO-ULSI Processor for IIPS (IIPS를위한 광선 제어용n-위상 OPTO-ULSI 프로세서의 디자인)

  • Lee, Chang-Ki;Im, Hyung-Kyu
    • Journal of the Korea Computer Industry Society
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    • v.5 no.2
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    • pp.261-268
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    • 2004
  • This study to design an optimum phase implementing a 256 phase Opto-ULSI processor for multi-function capable optical networks. The design of an 8 phase processor is already in construction and will provide the Initial base for experimentation and characterisation. The challenge is to be able to compensate for the non-linearity of the liquid crystal, find an optimum phase, and implement a larger scale Opto-ULSI processor. This research is oriented around the initial development of an 8 phase Opto-ULSI processor that implements a Beam Steering (BS) Opto-ULSI processor (OUP) for integrated intelligent photonic system (IIPS), while investigating the optimal phase characteristics and developing compensation for the non-linearity of liquid crystal.

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THE STABILITY OF ALL-TRANS-RETINOL IN NOVEL LIQUID CRYSTALLINE OW EMULSION

  • Kang, H.H.;Cho, J.C.;Lee, J.H.;Lee, O.S.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.111-115
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    • 1998
  • We investigated the stability of all-trans-retinol on the liquid crystalline O/W emulsion composed of mainly alkyl polyglycerine, alkyl polyglucose and glycerine, and compared the activity of all-trans-retinol in the various forms of liquid crystal. Under certain conditions, novel liquid crystalline gel was formed around oil droplets, and layers of this liquid crystalline gel were very wide and rigid. (SWLC; Super Wide Liquid Crystal) SWLC was very helpful to stabilize retinol in O/W emulsion. After storage at 45 C for 4 weeks, all-trans-retinol in O/W emulsion composed of SWLC retained above 85% of the activity upon HPLC analysis, whereas those within no liquid crystalline emulsion gave 47% and normal liquid crystalline emulsion composed of fatty alcohols gave 40 60%. Retinol in oil phase is nealy insoluble in pure water, but in cosmetic emulsion systems can be slightly solubilized into water because emulsifiers and polyols in emulsion systems function as solubilizers. In this case, water in outer phase acts as a media for oxygen transporation$.$and thus destabilizes retinol. As a result, retinol in O/W emulsion has a tendency to become unstable. SWLC surrounding oil droplet which contains retinol is wide and rigid, therefore reduces contact between inner phase and outer phase To make SWLC, properties of emulsifiers are very important phase transition temperature should be high, and the structure of surfactants should be bulky, and their ratio should be suitable to make rigid and wide liquid crystalline gel layer in order to reduce contact between retinol in inner phase and water in outer phase.

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Design of Beam Steering n-phase OPTO-ULSI Processor for IIPS (IIPS를 위한 빔 조향 n위상 광 ULSI 프로세서 디자인)

  • Lee, Chang-Ki;Lim, Hyung-Kyu
    • The Journal of the Korea institute of electronic communication sciences
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    • v.3 no.3
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    • pp.158-164
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    • 2008
  • This project investigates an optimum phase design implementing a 256 phase Opto-ULSI processor for multi-function capable optical networks. The design of an 8 phase processor is already in construction and will provide the initial base for experimentation and characterization. The challenge is to be able to compensate for the non-linearity of the liquid crystal, find an optimum phase, and implement a larger scale Opto-ULSI processor. This research is oriented around the initial development of an 8 phase Opto-ULSI processor that implements a Beam Steering(BS) Opto-ULSI processor(OUP) for integrated intelligent photonic system(IIPS), while investigating the optimal phase characteristics and developing compensation for the non-linearity of liquid crystal.

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