• Title/Summary/Keyword: Crystal field parameter

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Temperature Dependence of Mn2+ Paramagnetic Ion in a Stoichiometric LiNbO3 Single Crystal

  • Yeom, Tae Ho;Lee, Soo Hyung
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.221-224
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    • 2013
  • Electron paramagnetic resonance (EPR) spectra of $Mn^{2+}$ impurity ion in Stoichiometric $LiNbO_3$ single crystal (SLN) was investigated with an X-band EPR spectrometer in the temperature range of 3 K~296 K. The intensity of EPR spectrum of $Mn^{2+}$ ion was increased to 20 K and decreased again below 20 K as the temperature decreases. The zero-field splitting parameter D decreased as the temperature increases. It was suggested that $Mn^{2+}$ ion substitute for $Nb^{5+}$ ion instead of $Li^+$ ion. No changes for hyperfine interaction of $Mn^{2+}$ ion was obtained in the temperature range of 3 K~296 K.

Optical absorption of $Mg_{0.15}Zn_{0.85}Te$ and $Mg_{0.15}Zn_{0.85}Te:Co^{2+}$ single crystal ($Mg_{0.15}Zn_{0.85}Te$$Mg_{0.15}Zn_{0.85}Te:Co^{2+}$ 단결정의 광흡수 특성)

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    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.2
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    • pp.180-184
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    • 1999
  • The single crystals of $Mg_{0.15}Zn_{0.85}Te$ and $Mg_{0.15}Zn_{0.85}Te:Co^{2+}$(0.001%) were grown by vertical Bridgman method. Optical absorption properties of this compound were studied. As a result of the optical absorption spectra of $Mg_{0.15}Zn_{0.85}Te$, absorption peaks were related to exciton and the exciton level redshifts with increasing temperature, and temperature coefficient given to the value of $-5.8{\times}10^{-4}\;eV/K$ for the temperature range above 100 K. in the $Mg_{0.15}Zn_{0.85}Te:Co^{2+}$(0.001%) single crystal, the intracenter transitions due to $Co^{2+}$ ions were detected for $A-band:^4A_2(^4F) {\to}^4T_1(^4F),\; B-band:\; ^4A_2(^4F){\to}^4T_1(^4P)$, and the charge transfer transition near the absorption edge was observed in the wavelength range of 500 to 800 nm. According to the crystal field theory and Lucovsky formula, the crystal field parameter, Racah parameter and charge transfer energy were determined.

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Electron Paramagnetic Resonance Study of impurity Fe3+ ion in LiTaO3 single crystal (Fe3+ 불순물이 첨가된 LiTaO3 단결정에서의 전자 상자성 공명 연구)

  • Min, S.G.;Yeon, T.H.;Lee, S.H.;Lee, M.K.;Shin, H.K.;Yu, Y.M.;Kim, T.H.;Yu, S.C.
    • Journal of the Korean Magnetics Society
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    • v.13 no.4
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    • pp.171-175
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    • 2003
  • Electron paramagnetic resonance (EPR) of Fe$^{3+}$ in LiTaO$_3$ single crystal, grown by Czochralski method, has been studied by employing an X-band spectrometer. Resonance spectra of Fe$^{3+}$ ion on the crystallographic principal axes were obtained with 9.447 ㎓ at room temperature. The spectroscopic splitting parameter g and zero-field splitting (ZFS) parameter D (= 3 B$_{2}$sup 0/) are calculated with effective spin Hamiltonian. Fe$^{3+}$ center in stoichometric single crystal turns out to be different with that in congruent single crystal reported previously. From the analysis of temperature dependence of resonance fields for Fe$^{3+}$ ion, there is no any phase transition at the temperature range (from -160 $^{\circ}C$ to 20 $^{\circ}C$).

Characterization of the biodegradable behavior for biphasic calcium phosphates using X-ray diffraction and lattice parameter (X-선 회절 및 격자 매개변수를 이용한 biphasic calcium phosphate 분말의 생분 해성 특성평가)

  • Kim, Dong-Hyun;Song, Chang-Weon;Kim, Tae-Wan;Jin, Heoyng-Ho;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.4
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    • pp.169-174
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    • 2011
  • Nanoscale-biodegradable behaviors of synthesized biphasic calcium phosphates (BCP) powders were characterized using X-ray diffraction (XRD), lattice parameter, and field emission microscopy (FE-SEM). The calcined BCP powders in vitro tested in Hank's balanced salt solution (pH = 7.4, $36.5^{\circ}C$) for 3 weeks. The calculated unit cell parameters for BCP have shown lattice distortion and expansion as irregular changes in the a and c-axis after in vitro.

Measurement of High Electric Field Using Linear Electric-Optic Effect of Crystalline SiO$_2$ (SiO$_2$의 전기 광학 효과를 이용한 고전계 측정)

  • 김요희;이대영
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.17 no.2
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    • pp.142-152
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    • 1992
  • This paper presentes a new method to measure high electric field (or high voltage) by using crystalline SiO2 which has very high half wave voltage. There are many difficulties in measuring high electric field using other crystals which have generally low half wave voltage.By applying Stokes parameter and Mueller matrix. We derive optical modulation equation in the sensor which is composed of a polarizer, and Mueller matrix, we derive optical modulation equation in the sensor which is composed of a polarizer, a Pokels material, and an analyzer, We theoretically analyzed electro-optic effect, and calculated the phase retardation and half wave volt age of the birefringent material. The designed optical valtage sensor has very excellent linearity up to 20KV without divided volt-age. The maximum error was measured within 3%. Before annealing of Sio2 crystal, the maximum variation of the output voltage is 7.5% with varying temperature from \ulcorner20˚c to 60˚c. But, after annealing of SiO2 crystal, the output voltage variation is improved within 1%error.

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Single Crystal 133Cs NMR Study of Cs+(15-Crown-5)2I-

  • Lee, Kang-Yeol;Kim, Tae-Ho;Shin, Yong-Woon;Kim, Jin-Eun
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.529-532
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    • 2004
  • Cesium-133 NMR spectra of a single crystal of tetragonal $Cs^+ (15-crown-5)_2I^-$ were obtained as a function of crystal orientation in an applied magnetic field of 9.40T and analyzed to provide the magnitudes and orientations of the $^{133}Cs$ chemical shift and quadrupolar tensors for two magnetically nonequivalent and symmetry related sites. Chemical shift tensor components and parameters of quadrupolar interactions are obtained as ${\delta}_{11}=46(1),\;{\delta}_{22}=60(1),\;{\delta}_{33}=-30(1)$ ppm, quadrupole coupling constant QCC = 581(1) kHz, and asymmetry parameter ${\eta}$ = 0.481(1), respectively. The nonaxially symmetric NMR parameters imply that the local environment of the cesium nuclei is nonaxially symmetric. The DANTE experiment burned holes in the $^{133}Cs$ NMR line of the title compound. The hole burning of the single crystal and powder $^{133}Cs$ NMR lines showed that the NMR lines are not homogeneously broadened.

Optical Properties of $CdAl_2S_4 : Co_{2+}$ Single Crystal ($CdAl_2S_4 : Co_{2+}$ 단결정의 광학적 특성)

  • Kim, Hyung-Gon;Kim, Nam-Oh;Son, Kyeong-Choon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.7
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    • pp.382-387
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    • 2000
  • The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals were grown by the chemical transport reaction method using iodine as a transport agent. The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$single crystals were crystallized into a defect chalcopyrite structure. The optical energy gap of the $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals was found to be 3.377 eV and 2.924 eV, respectively, at 300 K. Blue emission with peaks in 456nm~466nm at 280K was observed in the $CdAl_2S_4$ single crystal. Optical absorption and emission peaks due to impurities in the $CdAl_2S_4 Co^{2+}$ single crystal were observed and described as originating from the electron transition between energy levels of the $Co^{2+} ion sited at the Td symmetry point.

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Effect of Sputtering Parameter on the Deposition Behavior of TiO2 Thin Film (TiO2 박막의 증착거동에 미치는 스퍼터링 공정변수의 영향)

  • Kim, Eul-Soo;Lee, Gun-Hwan;Kwon, Sik-Chol;Ahn, Hyo-Jun
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.1
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    • pp.8-16
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    • 2003
  • $TiO_2$ thin films were deposited by DC reactive magnetron sputtering with variations in sputtering parameter such as Ar and $O_2$ flow rate, DC power, substrate temperature and magnetic field. Deposition rate, crystal structure, chemical bond of $TiO_2$ films on the deposition conditions were investigated by Alpha-step, X-ray Diffractometer(XRD), X-ray Photoelectron Spectroscopy(XPS). When the DC power was applied at 500watt, deposition rate of $TiO_2$ film was about 480A/min. $TiO_2$ films coated under the deposition condition of 15sccm Ar and 7~10sccm $O_2$ flow rate was only observed anatase phase. With increasing substrate temperature from RT to $300^{\circ}C$, crystal orientation of $TiO_2$ films variously became.

Magnet applications of HTS wires

  • Oh, Sang-Soo
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.27-34
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    • 2000
  • HTS wires processed by PIT method are now available for magnet applications. But, those wires can not be used over 40 K due to weak link. This leads to necessity of development of coated conductor which can retain high $J_c$ at high field in liquid nitrogen. In this paper, various technical issues and the R&D status for both PIT wires and coated conductor were discussed. The difference of coated conductor's processes were also investigated and summarized. Various requirements for a design of HTS magnets were discussed. Anisostropic $J_c$ property with respect to magnetic field was considered to determine the coil's critical current. Low n value is a critical parameter to degrade a field stability with respect to time for a persistent mode HTS magnet. The relation between the margin of operation current and n value was investigated. Prototype HTS magnets with PIT wires are being developed for various applications such as crystal growth, MRI, magnetic separator and etc. HTS magnets will come into wide use in various fields of industries if the HTS wires with a low performance cost is developed.

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Prediction of Customer Failure Rate Using Data Mining in the LCD Industry (LCD 디스플레이 산업에서 데이터마이닝 알고리즘을 이용한 고객 불량률 예측)

  • You, Hwa Youn;Kim, Seoung Bum
    • Journal of Korean Institute of Industrial Engineers
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    • v.42 no.5
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    • pp.327-336
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    • 2016
  • Prediction of customer failure rates plays an important role for establishing appropriate management policies and improving the profitability for industries. For these reasons, many LCD (Liquid crystal display) manufacturing industries have attempted to construct prediction models for customer failure rates. However, most traditional models are based on the parametric approaches requiring the assumption that the data follow a certain probability distribution. To address the limitation posed by the distributional assumption underpinning traditional models, we propose using parameter-free data mining models for predicting customer failure rates. In addition, we use various information associated with product attributes and field return for more comprehensive analysis. The effectiveness and applicability of the proposed method were demonstrated with a real dataset from one of the leading LCD companies in South Korea.