• 통합자연과학논문집
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• 제9권1호
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• pp.28-34
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• 2016

A number of chiral selectors have been developed and applied for enantiomer separation of a variety of chiral compounds. Among these chiral selectors are chiral crown ethers, a class of synthetic host polyether molecules that bind protonated chiral primary amines with high selectivity and affinity. In this paper, two important chiral crown ethers as chiral selectors of bis-(1,1'-binaphthyl)-22-crown-6 and (18-crown-6)-2,3,11,12-tetracarboxylic acid (18-C-6-TA) are focused. They have been widely used to resolve the enantiomers of chiral compounds containing a primary amino moiety using chiral stationary phases (CSPs) or chiral selectors by high-performance liquid chromatography (HPLC), capillary electrophoresis (CE) and so on in chirotechnology. Also, it was described that the commercially available covalent type HPLC CSPs derived from (+)- and (-)-18-C-6-TA have been developed and successfully applied for the resolution of various primary amino compounds including amino acids.

• Bulletin of the Korean Chemical Society
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• 제13권3호
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• pp.274-279
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• 1992

Immobilization method of lariat azacrown ethers, containing hydroxyl group in the side arm of crown ring, on the polymer matrix and the phase-transfer catalytic activity of thus obtained immobilized lariat azacrown ethers were studied. Polystyrene resins with crown ether structures and hydroxyl groups adjacent to the macrorings were prepared by the reaction of crosslinked polystyrene resins containing epoxy groups with monoaza-15-crown-5 or monoaza-18-crown-6. Microporous crosslinked polystyrene resins containing epoxy group for the syntheses of these immobilized lariat crown catalysts were prepared by suspension polymerization of styrene, divinylbenzene (DVB 2%) and vinylbenzylglycidyl ether. The immobilized lariat catalysts with 10-20% ring substitution exhibited maximal activity for the halogen exchange reactions of 1-bromooctane with aqueous KI or NaI under triphase heterogeneous conditions. Immobilized catalyst exhibited higher activity than corresponding catalyst without the hydroxyl group and this result was suggested that the active site have a structure in which the $K^+$ ion was bound by the cooperative coordination of the crown ring donors and the hydroxyl group in the side arm.

• Imaging Science in Dentistry
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• 제43권4호
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• pp.295-301
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• 2013

The author experienced 8 cases of pericoronal radiolucency involving an incomplete tooth crown that had not developed to form the cemento-enamel junction, and the underdeveloped crown sometimes appeared to be floating within the radiolucency radiographically. The first impression was that these cystic lesions had odontogenic keratocysts, but half of them turned out to be dentigerous cysts histopathologically. There has been no report concerning odontogenic cysts involving an incompletely developed crown. The purpose of this paper is to report that dentigerous cysts may develop before the completion of the cemento-enamel junction of a developing crown.

• 한국산림과학회지
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• 제99권3호
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• pp.391-396
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• 2010

수관화 위험성 평가에 필요한 소나무 수관층 연료특성을 분석하기 위해 수관 부위별로 연료량을 추정할 수 있는 상대생장식을 개발하고, 수관연료밀도를 분석하였다. 이를 위해 대구 팔공산의 소나무 임분을 대상으로 10본의 소나무를 벌채하고, 수간, 가지, 잎 부분의 고사여부와 가지의 굵기 별로 구분하여 무게를 측정하였다. 상대생장식은 흉고직경(D) 또는 흉고직경과 수고(H)를 이용하는 회귀식을 이용하여 추정하였다. 평균적으로 추정식 lnWt=${\alpha}+{\beta}lnD+{\gamma}lnH$의 결정계수가 가장 높고(${R^2}_{adj}$=0.835-0.996) 표준추정오차가 가장 낮았지만(SEE=0.074-0.638), 잎과 작은 가지 항목에서는 추정식들간 결정계수 및 표준추정오차의 차이가 미미하였다. 각 부위별 연료량을 수관체적으로 나눈 수관연료 밀도는 잎만을 고려했을 때 0.067 kg/$m^3$, 잎과 직경이 0.5 cm 이하인 가지까지 포함했을 때 0.097 kg/$m^3$로 나타났다. 흉고직경이 증가함에도 잎과 잔가지 부위의 수관연료밀도 증가폭은 미미하였다.

• 대한소아치과학회지
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• 제29권3호
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• pp.382-388
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• 2002

전라북도 전주시 유치원 어린이 650명을 대상으로 구강내 검사 실시하여 평균 연령 4.5세 어린이 100명(남아 50명, 여아 50명)의 유치열 석고모형을 계측하여 다음과 같은 결과를 얻었다. 1. 유치의 계측자내 오차는 제1유구치에서 다소 크고, 총평균치는 0.255mm이었다. 2. 유치의 근원심 및 순(협)설측 치관 직경은 전체 유치에서 남아가 여아보다 컸다. 3. 변동계수(coefficient variation)는 남 여아 모두 유전치부위가 유구치부위에 비해 다소 큰 경향을 보였고, 근원심 및 순(협)설측 치관 직경 모두 제2유구치에서 크기변화가 가장 적게 나타났다. 4. 좌, 우측 동명치 사이의 차이를 나타내는 비대칭성에서는 상악 근원심 크기 측정을 제외하고는 근원심 및 협설측 치관 크기 측정 모두에서 제2유구치가 제1유구치보다 보다 덜 비대칭적이었다. 5. Crown index는 상악의 경우 여아보다 남아에서 큰 반면, 하악의 경우에는 유견치를 제외하고는 여아에서 컸다. Crown module은 여아보다 남아에서 컸고, 일반적인 치아크기가 유중절치에서부터 제2유구치까지 점차 증가하였다. Crown area도 여아보다 남아에서 컸으며 하악 유중절치가 가장 적은 면적을 나타냈고, 상악 제2유구치가 가장 큰 면적을 나타냈다.

• 한국해안해양공학회지
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• 제16권4
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• pp.206-212
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• 2004

본 연구에서는 폭이 좁은 1열 및 다열 잠제 대한 파랑 차단 성능을 폭이 넓은 1열 및 2열 잠제의 파랑 차단 성능과 비교$.$연구하였다. 파동장은 선형포텐셜 이론으로 모형화 하였으며 유한요소법을 적용하여 수치해석 하였다. 수치해석 결과, 1열 잠제에서는 폭이 좁은 잠제가 폭이 넓은 잠제보다 파랑 차단 성능이 다소 떨어지나 어느 정도 효과적인 파랑 차단 성능을 보여주고 있으며, 폭이 좁은 잠제를 2열 또는 3열로 배치하였을 때에는 폭이 넓은 1열 또는 2열 잠제보다 훨씬 뛰어난 파랑 차단 성능을 보이고 있다.

• KSBB Journal
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• 제27권4호
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• pp.199-206
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• 2012

Chiral crown ethers are synthetic macrocyclic polyethers that bind protonated chiral primary amines with high selectivity and affinity. They have been widely used to separate or distinguish the enantiomers of chiral compounds containing a primary amino moiety by high-performance liquid chromatography, capillary electrophoresis, and NMR spectroscopy. In this paper, two important chiral crown ethers including chiral binaphthyl unit and (18-crown-6)-2,3,11,12-tetracarboxylic acid as chiral selectors are focused. And several chiral resolution techniques and their applications in chirotechnology using these chiral crown ethers with related chiral recognition mechanism studies are reviewed. Especially, it was shown that the commercially available HPLC columns based on (18-crown-6)-2,3,11,12-tetracarboxylic acid have been developed and successfully applied for the resolution of various primary amino compounds including amino acids.

• 한국작물학회지
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• 제44권4호
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• pp.309-315
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• 1999

Rice seedling test was conducted to check the loging tolerance at ripening stage through evaluating the root characters. Thirteen Korean and foreign rice cultivars with direct seeding adaptable or high quality characteristics were grown in a cell pot and under submerged paddy. The root characters and pushing resistance of rice hill were determined at seedling and ripening stage, respectively. The diameter of crown root at the 7th and 8th leaf stages was thicker in lodging tolerance cultivars than those of others and showed significant-positive correlation with both pushing resistance and crown root diameter of mature plants. Also, the tensile strength of crown root at the 7th and 8th leaf stage showed highly positive correlation with the tensile strength of crown root of mature plants. The number of crown root at 7th leaf stage was significant-positively correlated with that of mature plant. The diameter of seminal root was not significantly correlated with the diameter of crown root throughout the whole growth stage. These results indicate that the diameter, tensile strength and number of crown root associated with root lodging tolerance can be detected with the seedling at about 7th or 8th leaf stage, and the seedling test using the cell pot is an useful and practical method to select lodging tolerant cultivars or lines of rice based on root characters, especially diameter of crown root.

• The Korean Journal of Ecology
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• 제2권1호
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• pp.15-20
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• 1978

Pathological and anatomical studies on the cause of the crown gall like symptoms associated with the chestnut nurse grafts were undertaken. The crown gall bacterium, Agrobacterium tumefaciens, was isolated from the gall tissues of chestnut nurese grafts by using selective media developed by S초개소 et al. and kado and Heskett. Typical crown gall symptoms appeared on tomato, castor bean and geranium plants 10~21 days following inoculation with the bacterium isolated from the gall tissues of chestnut nurse grafts. Agrobacterium tumefaciens was reisolated from crown gall tissues of tomato, castor bean and geranium. Anatomical studies on the origin, growth and differentiation of the gall tissues of the chestnut nurse grafts confirmed that the gall tissues are of crown gall origin. Masses of Agrobacterium tumefaciens were observed from gall tissues of chestnut nurse grafts, so it could be confirmed that the crown gall symptoms prevalent on chestnut nurse grafts are caused by the crown gall bacterium, Agrobacterium tumefaciens.

• 대한치과보철학회지
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• 제25권1호
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• pp.341-353
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• 1987

The purpose of this study was to investigate the gingival response to the location of the crown margin and the gingival response to the period of crown placement. Twenty one patients were selected for this study. The patients fitted into the research condition. The crown margins of anterior teeth were located at crest and supragingivally. The crown margins of posterior teeth were located at crest, subgingivally and supragingivally. Plaque index and gingival index were measured before tooth preparation and 1 week,4 weeks, 6 weeks after crown placement. The results were as follows: 1. There was no significance in the gingival response to the location of crown margin in short term period. 2. As the period of crown placement was extended, plaque index and gingival index were gradually increased. 3. Plaque index and gingival index of tooth surfaces were increased in the order of the interproximal surfaces, lingual surfaces and buccal or labial surfaces.