• Title/Summary/Keyword: Cross effects

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Dual Substituent Effects on Pyridinolysis of Bis(aryl) Chlorothiophosphates in Acetonitrile

  • Barai, Hasi Rani;Lee, Hai Whang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1754-1758
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    • 2014
  • The nucleophilic substitution reactions of bis(Y-aryl) chlorothiophosphates (1) with X-pyridines are investigated kinetically in acetonitrile at $35.0^{\circ}C$. The free energy relationships with both X and Y are biphasic concave upwards with a break point at X = 3-Ph and Y = H, respectively. The sign of cross-interaction constants (CICs; ${\rho}_{XY}$) is positive with all X and Y. Proposed mechanism is a stepwise process with a rate-limiting leaving group departure from the intermediate with all X and Y. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). In the case of Y = electron-withdrawing groups, the cross-interaction between Y and Y, due to additional substituent Y, is significant enough to change the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1, indicative of the change of mechanism from a rate-limiting bond formation to bond breaking.

Effects of Rib Cross Section Shapes on Heat Transfer of a Rib-Roughened Duct (터빈 기익 내부관 열전달 증대를 위해 설치된 요철의 형상 효과)

  • Wu, Seong Je;Kwon, Hyuk Jin;Cho, Hyung Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.1
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    • pp.149-157
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    • 1999
  • Heat transfer in a duct is augmented remarkably by rib turbulators. However, increasing friction loss is accompanied due to ribs disturbing flows. Hence, pressure drops and heat transfer are considered simultaneously to decide heat/mass transfer performance in a rib-roughened duct. In the present study, the effects of rib cross section shape on pressure drop through a duct are investigated as well as those on heat transfer characteristics. The results show that the characteristics of heat/mass transfer and friction loss in the duct roughened with triangular ribs are similar to those with square ribs, while significantly different from those with semicircular ribs. The best performance in the duct is obtained by using semicircular shaped ribs among three types of ribs for the large rib angles of ${\alpha}{\geq}63^{\circ}$.

Flapwise Bending Vibration Analysis of Rotating Cross-ply Composite Beams (전단 및 단면 관성효과를 고려한 Cross-ply 복합재 회전 외팔보의 면외방향 굽힘 진동해석)

  • 이승현;신상하;유홍희
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.994-999
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    • 2003
  • A modeling method for the modal analysis of a rotating cross-ply composite beam based on Timoshenko beam theory is presented. To analyze the composite beam exactly, the effects of shear deformation and rotary inertia are included. Linear differential equations of motion are derived using the assumed mode method. For the modeling, hybrid deformation variables are employed and approximated to derive the equations of motion. The effects of the dimensionless angular velocity and the slenderness ratio parameter on the variations of modal characteristics are investigated

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Free Vibrations of Stepped Horizontally Curved Beams with Variable Curvature (불연속 변화단면 변화곡률 수평 곡선보의 자유진동)

  • 이태은;안대순;이병구;김권식
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.858-863
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    • 2003
  • In the practical engineering fields, the horizontally curved beams are frequently erected as the major/minor structural components. The effects of both variable curvature and variable cross-section on structural behavior are very important and therefore these effects should be included in structural analyses. From this viewpoint, this paper deals with the free vibrations of horizontally curved beams with variable curvature and variable cross-section. In this study, the parabola as the curvilinear shape and stepped beam as the variable cross-section are considered. The ordinary differential equation governing free vibrations of such beams are derived. For calculating the natural frequencies, the governing equations are solved by numerical methods. The Runge-Kutta and Determinant search Methods are used for integrating the differential equations and for calculating the natural frequencies, respectively. With regard to numerical results, the relationships between frequency parameters and various beam parameters are presented in the forms of Table and Figures.

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Effects of Skin Rehabilitation Massage Therapy on Pruritus, Skin Status, and Depression in Burn Survivors

  • Roh, Young-Sook;Cho, Hee;Oh, Jung-Ok;Yoon, Cheon-Jae
    • Journal of Korean Academy of Nursing
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    • v.37 no.2
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    • pp.221-226
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    • 2007
  • Purpose. Hypertrophic scarring and depression are the principal problems of bum rehabilitation. This study was done to verify the effects of skin rehabilitation massage therapy (SRMT) on pruritus, skin status, and depression for Korean bum survivors. Methods. A pretest - posttest design using a nonequivalent control group was applied to examine the effects of SRMT for 3 months in a group of 18 bum survivors. The major dependent variables - including pruritus, objective and subjective scar status, and depression - were measured at the beginning and at the end of the therapy to examine the effects of SRMT. Results. Bum survivors receiving SRMT showed reduced pruritus, improved skin status, and depression. The remaining scar also showed improvement in skin pigmentation, pliability, vascularity, and height (compared to the surrounding skin) as measured on the Vancouver Scar Scale (VSS). Conclusions. The findings demonstrate that SRMT for bum survivors may improve their scars both objectively and subjectively, and also reduce pruritus and depression.

Effect of Slowly Forced Expiration on Abdominal Muscle Activity During Cross Knee Curl-Up Exercise

  • Yoon, Tae-Lim;Kim, Ki-Song
    • Physical Therapy Korea
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    • v.21 no.1
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    • pp.63-69
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    • 2014
  • Cross knee curl-up is an ideal variation of abdominal curl up exercise to strengthen abdominal musculature without excessive lumbar flexion which can increase the loads on the disc and ligaments. In addition, slowly forced expiration can facilitate the activation of the abdominal musculature. The purpose of this study was to determine the effects of slowly forced expiration on activity of abdominal muscles, such as rectus abdominis (RA), external oblique (EO), and transverse abdominis/internal oblique (TrA/IO), while cross knee curl-up. Eleven young and healthy subjects (6 males and 5 females) participated. All subjects performed the cross knee curl-up slowly forced expiration and natural breathing. Paired t-test was performed in normalized electromyogram (EMG) muscle activity of the bilateral RA, EO, and TrA/IO to compare the differences between the cross curl-up with slowly forced expiration and natural breathing. Statistical significance was set at .05. There were no significant differences in normalized EMG muscle activity of the bilateral RA, EO, and TrA/IO between the cross curl-up with slowly forced expiration and natural breathing. The finding of this study designates that slowly forced expiration does not induce increasing activity of abdominal muscle in cross knee curl-up; hence, learning step of breathing control might not be necessary to strengthen abdominal muscle in cross knee curl-up.

Wigner-Ville Distribution Applying the Rotating Window and Its Characteristics (회전 창문함수를 적용한 위그너-빌 분포함수와 그 특성)

  • 박연규;김양한
    • Journal of KSNVE
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    • v.7 no.5
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    • pp.747-756
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    • 1997
  • Wigner-Ville distribution which is a time-frequency analysis has a fatal drawback, when the signal has multiple components. This is the cross-talk and often causes a neagative value in the distribution. Wingner-Ville distriution is an expression of power, therefore the cross-talk must be avoided. Smoothing the Wigner-Ville distribution by convoluting it with a window, is most commonly used to reduce the cross-talk. There can be infinite number of distributions depending on the windows. But, the smoothing reduces resolution in time-frequency plane; this motives to design a more effective window in reducing cross-talk while remaining resolution. The domain in which the cross-talk and legitimate components can be easily distinguished, is the ambiguity function. In the ambiguity function domain, the legitimate components appear as linear lines passing through the orgine. But, the cross-talk is widely distributes in the ambiguity function plane. Based on the relative distributions of cross-talk and legitimate components, rotating window can be designed to minimize cross-talk. Applying the rotating window to the ambiguity function corresponds to smoothing the Wigner-Ville distribution. Therefore, the effects of rotating window is estimated in terms of the bias error due to smooting the Wigner-Ville distribution. By applying the rotating window, not only the Wigner-Ville distribution but also its properties are changed. The properties of the new distribution are checked, in order to complete analyzing the rotating window.

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A Study on the Lightweight Design of a Cross Beam for Railway Passenger Coach (철도객차용 크로스 빔의 경량화 설계에 관한 연구)

  • Jang, Deuk-Yul;Jeon, Hyung-Yong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.5
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    • pp.126-133
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    • 2017
  • This report investigates the stress distribution according to the location and shape change of the circular hole for the lightweight design of the cross beam of a railway passenger car and studies the lightweight design. To design a lightweight cross beam with a circular hole, we selected the non-circular crossbeam as a basic model, examined the stress distribution and displacement by position and determined the location, shape, size and quantity of the hole for light weight. We analyzed the effects of the position and shape of the hole on the maximum equivalent stress and displacement. The influencing factors were set as the design parameters, and the stress value was examined according to the variation of each variable. By considering the stress value according to the change of each variable and selecting the design parameter with the narrowest scattering value of the stress at each position of the hollow cross beam with various hole positions and shapes, we studied a cross beam with a circle hole under identical load condition to have an equal stress distribution to that of a non-circular cross beam.

A clinical study on the effects of myocardial protection during open heart surgery (개심술에서 술중 심근보호효과에 관한 임상적연구)

  • 김근호
    • Journal of Chest Surgery
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    • v.20 no.2
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    • pp.230-240
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    • 1987
  • Cardioplegia and myocardial protection were performed under cardiopulmonary bypass during open-heart surgery with the use of cold St. Thomas Hospital cardioplegic solution [4=C] for the coronary artery perfusion and normal saline solution [4- C] for the topical cardiac cooling. To maintain the state of myocardial protection, coronary artery reperfusion was carried out using St. Thomas Hospital cardioplegic solution at the interval of 30 minutes. A total number of patients studied were 57 cases, including 37 cases of correction for congenital cardiac anomalies and 20 cases for acquired heart valvular diseases. Cardiopulmonary bypass time during the surgery was observed to be average of 87.89*47.55 hours, aortic cross-clamping time to be average of 76.68~44.27 hours raging from 30 to 191 minutes. In order to evaluate the effects of myocardial protection in the surgery, serum enzyme levels were determined. To observe the relationship between aortic cross-clamping time and myocardial protection effects, patients studied were divided into the following 3 groups. I group: aortic cross-clamping time, 60 minutes, II group: aortic cross-clamping time, 90 minutes, III group: aortic cross-clamping time, over 91 minutes. 1. Changes in serum enzyme levels in postoperative period. [1] SCOT; The postoperative value [increased over 200 units] for ischemic myocardial injury during operation was observed in 11 cases [19.3% of the total] of the total patients studied, of which 4 cases [13.3%] in I group, 1 case [10.0%] in II group, and 6 cases [35.3%] in III group. [2] LDH; The positive value [increased over 900 units] for ischemic myocardial injury during operation was observed in 9 cases [15.7% of the total] of the total patients studied, of which 2 cases [6.6%] in I group, 1 case [10.0%] in II group, and 6 cases [35.3%] in III group. [3] CPK; The positive value [increased over 800 units] for ischemic myocardial injury during operation was observed in 10 cases [17. 5% of the total] of the total patients studied, including 4 cases [13. 3%] in I group, 1 case [10.0%] in II group, and 5 cases [29.4%] in III group. 2. The myocardial protection method used in the present study was demonstrated to be effective for the myocardial protection in the surgery with aortic cross-clamping time of up to 90 minutes. A few ischemic myocardial injury were observed in the surgery with aortic cross-clamping time over 91 minutes, but no significant cardiac dysfunction was noted. The surgery with aortic cross-clamping time of up to 191 minutes did not appear to give rise any significant interference with postoperative recovery.

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Genetic Variation in Growth and Body Dimensions of Jersey and Limousin Cross Cattle. 2. Post-Weaning Dry and Wet Season Performance

  • Afolayan, R.A.;Pitchford, W.S.;Weatherly, A.W.;Bottema, C.D.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.10
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    • pp.1378-1385
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    • 2002
  • The importance of direct genetic, maternal, heterosis and epistatic effects were examined on post-weaning weight, height, length, girth, fat depth and muscle (ratio of stifle to hip width) with dry and wet season gains in these traits. The breeds used were two pure breeds (Jersey and Limousin), the Limousin${\times}$Jersey $F_1$, and two backcrosses ($F_1{\times}$Jersey dams and $F_1{\times}$Limousin dams). Direct genetic effects were large (p<0.001) for all traits except for length. Jersey maternal effects were large for weight, girth, fat depth and muscle in the post-weaning wet season gains which is an evidence of the impact of Jersey dam on progeny beyond weaning. There were large heterosis effects on fat depth and muscle relative to other traits. Epistatic effects were observed for post-weaning performance in weight, girth, fat depth and muscle. There are indications that there were different genetic effects for post-weaning compared to preweaning growth traits. Thus, it could be hypothesized from this study that different quantitative trait loci (QTL) affect early and late growth in Jersey and Limousin cross cattle breeds. The follow up work will examine the different chromosomal gene effects on pre- and post-weaning growth.