• Journal of the Korean institute of surface engineering
• /
• v.40 no.6
• /
• pp.279-282
• /
• 2007

Cr-Mo-Si-C-N coatings were deposited on steel and Si wafer by a hybrid system of AIP and sputtering techniques using Cr, Mo and Si target in $Ar/N_2/CH_4$ gaseous mixture. Instrumental analyses of XRD and XPS revealed that the Cr-Mo-Si-C-N coatings must be a composite consisting of fine(Cr, Mo and Si)(C and N) crystallites and amorphous $Si_3N_4$ and SiC. The hardness value of Cr-Mo-Si-C-N coatings significantly increased from 41 GPa of Cr-Mo-C-N coatings to about 53 GPa with Si content of 9.3 at.% due to the refinement of (Cr, Mo and Si)(C and N) crystallites and the composite microstructure characteristics. A systematic investigation of the microstructures and mechanical properties of Cr-Mo-Si-C-N coatings prepared with various Si contents is reported in this paper.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2009.05a
• /
• pp.205-207
• /
• 2009

아크이온플래이팅 기술과 스퍼터링 기술이 결합된 하이브리드 코팅 시스템을 이용하여 STS 304와 Si 기판에 4성분계 Cr-Al-Mo-N 코팅을 증착하였다. $N_2$/Ar 혼합가스 분위기하에 아크 타겟은 Cr을 사용하였고 스퍼터링 타겟은 Al과 Mo를 사용하였으며 합성된 Cr-Al-Mo-N 코팅은 주로 치환고용된 (Cr, Al, Mo)N으로 구성되었다. 최고 경도값은 Mo 함량이 24.2 at.%일 때 35 GPa을 나타냈으며 마찰계수는 Mo의 함량이 0에서 33.2 at.%로 증가함에 따라 0.9에서 0.48로 감소하였다. 이는 $MoO_3$가 코팅면과 스틸볼 계면에서 고체 윤활제로 작용한 것으로 사료된다. 그러나 Cr-Al-Mo-N 코팅은 MoN의 낮은 내산화온도로 인하여 Cr-Al-N에 비하여 더 낮은 온도에서 산화되었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2009.05a
• /
• pp.184-185
• /
• 2009

하이브리드 코팅 시스템을 이용하여 CrN 을 기초로 3성분계 코팅을 합성한다. 이번 연구는 C를 첨가한 음이온 고용경화와 Mo를 첨가한 양이온 고용경화의 영향이 미세구조와 기계적 성질에 미치는 영향을 알아보는 것이다. Cr-C-N 과 Cr-Mo-N 코팅은 23, 43GPa의 최대 경도 값을 가진다. 이 경도강화는 고용강화로 설명할 수 있다.

• Journal of the Korean institute of surface engineering
• /
• v.44 no.6
• /
• pp.269-276
• /
• 2011

Phase evolution and tribological behavior of Cr-Mo-N multi compositional films with different interlayer were investigated. The films were deposited by hybrid PVD (Physical Vapor Deposition) system consisted of dc unbalanced magnetron (UBM) sputtering and arc ion plating (AIP) sources. A pure molybdenum (Mo) was used as sputtering target and also a pure Cr was used as AIP target to form the Cr-Mo-N films. Various growth planes were found, no textured surface, in all of the multi composition films. Maximum value of microhardness was measured in Cr-Mo-N film with Mo interlayer as 29 GPa. Composition film was mainly showed the aspect of the adhesive wear than CrN film. The friction coefficient was decreased from 0.6 for pure CrN coating to 0.35 for Cr-Mo-N film with Mo interlayer. This result may come from the formation of metal oxide tribo-layer which is known as solid lubricant during the wear test.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2008.11a
• /
• pp.86-87
• /
• 2008

4성분계 Cr-MO-Si-N코팅은 하이브리드 시스템에 아르곤, 질소 가스를 주입하여 스테인리스 기판과 실리콘 웨이퍼에 증착시킨다. XRD, XPS, HRTEM을 이용해 Cr-MO-Si-N코팅의 성분을 분석하고 Si의 함량이 12.1at.%일때 50GPa의 강도가 나오고 이것은 33GPa의 강도Cr-MO-N코팅보다 크게 향상된 것이다.

• Journal of Advanced Navigation Technology
• /
• v.28 no.4
• /
• pp.532-537
• /
• 2024

In this study, wear characteristics and microstructure changes due to changes in alloy composition of Ni-Cr-Mo-V and Ni-Cr-Mo low-alloy steels used in brake discs for transportation system such as aircraft and high-speed trains. As a result of the hardness test, the hardness of C-Mo-V steel was the highest at 39.4±0.9HRc, and the hardness of Ni-Cr-Mo steel was the lowest at 32.4±0.6HRc. The friction coefficient tended to decrease as the vertical load increased. At a vertical load of 1 N, the friction coefficient of Ni-Cr-Mo steel was the highest at 0.842, and at a vertical load of 5 N, Mn-Cr-V steel was the highest at 0.696. Ni-Cr-Mo showed the largest wear scar width, depth, and wear amount, with a width of 711 ㎛, a depth of 8.24 ㎛, and a wear amount of 11 mg under a vertical load of 1 N, and a width of 1,017 ㎛, a depth of 19.17 ㎛, and a wear amount of 17 mg under a vertical load of 5 N. As a result of wear mechanism analysis, ploughing, delamination, and adhesion in all specimens, with plastic deformation being more prominently observed in Ni-Cr-Mo.

• Corrosion Science and Technology
• /
• v.2 no.2
• /
• pp.75-81
• /
• 2003

Chromium, molybdenum. and nitrogen are very important alloying elements in stainless steels and its effect was approved in pitting resistance equivalent (PRE) equations and many experimental results. However, Cr can improve the corrosion resistance, but facilitate the formation of sigma phase. Also. Mo has the same effect in stainless steels. If Cr and Mo are added at high amount to increase the corrosion resistance of stainless steel, corrosion resistance in annealed alloys can be improved, but in case of welding or aging heat treatment. its resistance will be drastically decreased. In this work, increasing Cr and N contents but decreasing Mo than the commercial alloys made the experimental alloys. Typical alloys are 25Cr-4.5Mo-0.43N alloy, 27Cr-4.7Mo-0.4N alloy, 27Cr-5.3Mo-0.25N alloy, 32Cr-2.6Mo-0.36N alloy. After annealing and aging heat treatment, microstructures, anodic polarization test, and pitting corrosion test were performed. Annealed alloys showed $100^{\circ}C$ of CPT and aged alloys showed the different tendency depending upon Cr and Mo contents(SFI)

• Nuclear Engineering and Technology
• /
• v.31 no.6
• /
• pp.561-571
• /
• 1999

Microstructure and mechanical properties of five Cr-Mo steels for nuclear industry applications have been investigated. Transmission electron microscopy, energy dispersive spectrometer, differential scanning calorimeter, hardness, tensile, and impact test were used to evaluate the Cr and W effect on the microstructure and mechanical properties. Microstructures of Cr-Mo steels after tempering are classified into three types : bainitic 2.25Cr-lMo steel, martensitic Mod.9Cr-lMo, HT9M, and HT9W steels, and dual phase HT9 steel. The majority of the precipitates were found to be M$_{23}$C$_{6}$ carbides. As minor phases, fine needle-like V(C,N), spherical NbC, fine needle-like Cr-rich Cr$_2$N, and Cr-rich M$_{7}$C$_3$were also found. Addition of 2wt.% W in Cr-Mo steels retarded the formation of subgrain and dissolution of Cr$_2$N precipitates. Hardness and ultimate tensile strength increased with increasing Cr content. Though Cr content of HT9W steel was lower than that of HT9 steel, the hardness of HT9W was higher due to the higher W content. W added HT9W steel had the highest ultimate tensile strength above $600^{\circ}C$. But impact toughness of W added steel (HT9W) and high Cr steel (HT9) was low.w.w.

• Journal of the Korean institute of surface engineering
• /
• v.39 no.2
• /
• pp.70-75
• /
• 2006

As technology advances, there is a demand for development of hard, solid lubricant coating. (Ti,Cr)N-$MoS_2$, films were deposited on SKD 11 tool steel substrate by co-deposition of $MoS_2$, with (Ti,Cr)N using a D.C. magnetron sputtering process. The influence of the $N_2/Ar$ gas ratio, the deposition temperature, the amount of $MoS_2$ in the films, and the bias voltage on the mechanical and the structural properties of the films were investigated. Wear tests were performed on the films deposited in various conditions.

• Elastomers and Composites
• /
• v.40 no.3
• /
• pp.174-180
• /
• 2005

Sonochemical synthesis of fullerene oxides $[C_{70}O_n](n=1{\sim}2)$ by fullerene$[C_{70}]$ and metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) took place under air atmosphere. The reactivity of fullerene$[C_{70}]$ and several metal hexacarbonyl complexes $M(CO)_6$(M=Cr, Mo, W) under same ultrasonic condition increased in the order of $Mo(CO)_6$ > $W(CO)_6$ > $Cr(CO)_6$. The MALDI-TOF-MS, UV-visible spectra, and HPLC analysis confirmed that the products of sonochemical reaction were $[C_{70}O_n](n=1{\sim}2)$.