• Title/Summary/Keyword: Cr Loading

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Development of Metal Loaded Activated Carbon Fiber for Eliminating Targeted VOCs Originated from Solvent (특정용제 Target 형 활성금속첨착 활성탄소섬유의 개발)

  • Choi, Kang-Yong;Kim, Kwang-Su;Kim, Tae-Won;Jun, Min-Kee;Park, Hea-Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.31-37
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    • 2013
  • To acquire enhanced adsorption capacity for especially targeted VOCs, activated carbon fiber of which surface area was $1,100m^2/g$ was selected and active metals were loaded. After screening study, Cr and Cu were selected as a base metal for improving adsorption capacity of activated carbon fiber. For acquiring better performance, metal loading, loading temperature, loading hours and kinds of loaded metals were changed as preparing variables. Properties measurement and adsorption capacity evaluation were performed. We found that the best conditions for metal loading were 5 hours loading at $100^{\circ}C$ and the adsorption capacity was enhanced almost double. Also we confirmed that more than 0.5 seconds contact time is needed for best adsorbate diffusion and adsorption over activated carbon fiber.

A Study of mechanical properties of oxide layer removed Co-Cr-Mo abutments

  • Ryu, Jae-ho;Huh, Jung-Bo;Ro, Jung-Hoon;Yun, Mi-Jung;Jeong, Chang-Mo
    • The Journal of the Korean dental association
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    • v.53 no.11
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    • pp.804-816
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    • 2015
  • PURPOSE: The aim of this study was to evaluate the influence of the oxide layer removal process in the Co-Cr-Mo (CCM) abutment after casting procedure on the prosthesis settlement and screw stability. MATERIALS AND METHODS: CCM abutments of four different interface conditions (CCM-M; machined, CCM-O; oxide layer formed, CCM-B; blasted, CCM-P; polished after blasted) and gold abutment (Gold-C; Cast with type III Gold alloy) were used. The initial settling values of abutments were evaluated according to the difference of implant-abutment length when the tightening torques were applied at 5 Ncm and 30 Ncm, and the settling values of abutments caused by loading were evaluated according to the difference of implant-abutment length before and after loading with 250 N, 100000 cycle. The loss ratios of removal torque for abutment screws were evaluated according to the difference in value of removal torques under 30 Ncm tightening torque applied before and after cyclic loading. RESULTS: The CCM-P and CCM-B group showed a higher initial settling value compared with the Gold-C group (P<.05), while the Gold-C group showed the highest settling values caused by loading (P<.05) and no significant differences were observed for between CCM groups (P>.05). The loss ratio of removal torque values for the CCM-B, CCM-P groups did not differ significantly from that of the Gold-C group (P>.05). CONCLUSION: Even though the oxide layer was removed by different methods, CCM abutment with internal conical connection structure showed lower abutment settling and similar screw loosening after cyclic loading compared with gold abutment.

Comparison of the fracture resistances of glass fiber mesh- and metal mesh-reinforced maxillary complete denture under dynamic fatigue loading

  • Im, So-Min;Huh, Yoon-Hyuk;Cho, Lee-Ra;Park, Chan-Jin
    • The Journal of Advanced Prosthodontics
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    • v.9 no.1
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    • pp.22-30
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    • 2017
  • PURPOSE. The aim of this study was to investigate the effect of reinforcing materials on the fracture resistances of glass fiber mesh- and Cr-Co metal mesh-reinforced maxillary complete dentures under fatigue loading. MATERIALS AND METHODS. Glass fiber mesh- and Cr-Co mesh-reinforced maxillary complete dentures were fabricated using silicone molds and acrylic resin. A control group was prepared with no reinforcement (n = 15 per group). After fatigue loading was applied using a chewing simulator, fracture resistance was measured by a universal testing machine. The fracture patterns were analyzed and the fractured surfaces were observed by scanning electron microscopy. RESULTS. After cyclic loading, none of the dentures showed cracks or fractures. During fracture resistance testing, all unreinforced dentures experienced complete fracture. The mesh-reinforced dentures primarily showed posterior framework fracture. Deformation of the all-metal framework caused the metal mesh-reinforced denture to exhibit the highest fracture resistance, followed by the glass fiber mesh-reinforced denture (P<.05) and the control group (P<.05). The glass fiber mesh-reinforced denture primarily maintained its original shape with unbroken fibers. River line pattern of the control group, dimples and interdendritic fractures of the metal mesh group, and radial fracture lines of the glass fiber group were observed on the fractured surfaces. CONCLUSION. The glass fiber mesh-reinforced denture exhibits a fracture resistance higher than that of the unreinforced denture, but lower than that of the metal mesh-reinforced denture because of the deformation of the metal mesh. The glass fiber mesh-reinforced denture maintains its shape even after fracture, indicating the possibility of easier repair.

Adhesive Behaviors of the Aluminum Alloy-Based CrN and TiN Coating Films for Ocean Plant

  • Murakami, Ri-Ichi;Yahya, Syed Qamma Bin
    • International Journal of Ocean System Engineering
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    • v.2 no.2
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    • pp.106-115
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    • 2012
  • In the present study, TiN and CrN films were coated by arc ion plating equipment onto aluminum alloy substrate, A2024. The film thickness was about 4.65 ${\mu}m$. TiN and CrN films were analyzed by X-ray diffraction and energy dispersive X-ray equipments. The Young's modulus and the micro-Vickers hardness of aluminum substrate were modified by the ceramic film coatings. The difference in Young's modulus between substrate and coating film would affect on the wear resistance. The critical load, Lc, was 75.8 N for TiN and 85.5 N for CrN. It indicated from the observation of optical micrographs for TiN and CrN films that lots of cracks widely propagated toward the both sides of scratch track in the early stage of MODE I. TiN film began to delaminate completely at MODE II stage. The substrate was finally glittered at MODE III stage. For CrN film, a few crack can be observed at MODE I stage. The delamination of film was not still occurred at MODE II and then was happened at MODE III. This agrees with critical load measurement which the adhesive strength was greater for CrN film than for TiN film. Consequently, it was difficult for CrN to delaminate because the adhesive strength was excellent against Al substrate. The wear process, which the film adheres and the ball transfers, could be enhanced because of the increase in loading. The wear weight of ball was less for CrN than for TiN. This means that the wear damage of ball was greater for TiN than for CrN film. It is also obvious that it was difficult to delaminate because the CrN coating film has high toughness. The coefficient of friction was less for CrN coating film than for TiN film.

Spherical Indentation Testing to Evaluate Mechanical Properties In 1Cr-1Mo-0.25V Steel (Spherical Indentation Testing에 의한 1Cr-1Mo-0.25V 강의 기계적 물성 평가)

  • Lee, J.M.;Nam, Y.H.;Nham, S.H.;Lee, S.S.;Lee, O.S.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.266-271
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    • 2001
  • Spherical indentation technique was developed to evaluate the flow properties of metallic materials in carbon steel, stainless steel and alloys, etc. Through the spherical indentation test, differently degraded 1Cr-1Mo-0.25V steel's mechanical properties were observed and compared with conventional standard test data. The flow properties of 1Cr-1Mo-0.25V steels were estimated by analyzing the indentation load-depth curve. To characterize the flow property, we used material yield slope and constraint factor index rather than strain-hardening exponent because the variation of strain-hardening exponent was very little and the data showed irregularly. And the constraint factor's effect was small when the material yield slope was taken into account.

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A study on VFAs recovery from food waste for exterior carbon source of denitrification (탈질화의 외부 탄소원 제공을 위한 음식폐기물의 유기산발효)

  • 장성호;조한진;손영일
    • Journal of environmental and Sanitary engineering
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    • v.15 no.3
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    • pp.15-23
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    • 2000
  • This study's purpose is the investigating the created liquid post-acid fermentation of usability of denitrification as exterior carbon sources by loading capacity of Organic matters. The time of acid fermentation of food waste, the slower loading capacity of organic matter, the faster decomposition fate, but the density of generation $VFA_S$ was weak and, $SBOD_5$ : ST-N rate and $SBOD_5/SCOD_{Cr}$ rate was low. Between TS and VS, VS was decreased to 6th day rast, and then was decreased slowly. Two days after stating the experiments, $SCOD_{Cr}$, $SBOD_5$, STOC and $VFA_S$ was decreased or increased slowly, and then increased fast. And after showing the highest density, it was tended to decreased fast. About 5 days after, because about 5 days later $CH_4$ bacteria activity due to the accumulation of $VFA_S$ was limited, $CH_4$ density was weak. When highest density in the acquisition of VFA, $R_1$ was $10,120mg/{\ell}$, $R_2$ was $11,380mg/{\ell}$, $R_3$was $13,720mg/{\ell}$. So $R_3$ only cut was highest generation. At the time of $SBOD_5$ with the highest density, at $SBOD_5$ : ST-N ratio, $R_1$ was 243:1, $R_2$ was 278:1, $R_3$ was 293:1. All of these were high $SBOD_5$ : ST-N ratios. And $R_3$ was the highest. After studying $SBOD_5$ : ST-N ratio and $SBCD_5/SCOD_{Cr}$ ratio, as a carbon source of biological denitrification it was profitable composition ratio.

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Evaluation of J$_lc$ and T$_mat$ of aged 1Cr-1Mo-0.25V steel at elevated temperature (시효열화시킨 1Cr-1Mo-0.25V 강의 고온에서의 J$_lc$ 및 T$_mat$ 의 평가)

  • 윤기봉;윤석호;서창민;남승훈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.11
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    • pp.2860-2870
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    • 1994
  • When crack are detected in aged turbine rotors of power plants, information on fracture resistance of the aged material at operating temperature is needed for determination of critical loading condition and residual life of the turbine. In this study, fracture toughness (J$_lc$) and tearing modulus(T$_mat$) of virgin and thermally degraded 1Cr-1Mo-0.25V steel, which is one of the most widely used rotor steels, were measured at 538.deg. C according to ASTM E813 and ASTM E1152, respectively. Five kinds of specimen with different degradation levels were prepared by isothermal aging heat treatment at $630^{\circ}C.$ It was observed that J$_lc$ and T$_mat$ value decreased as the degradation level increased. Analysis of microstructures using a scanning electron microscope showed that the decrement of J$_lc$ is related to segregation of impurities at grain boundaries. It was also verified that the DC electric potential drop method is accurate and reliable for crack length monitoring at elevated temperature.

A Study on Evaluation of High Temperature Creep Properties of 9Cr1MoVNb Steel by Small Punch-Creep test (소형펀치-크리프 시험에 의한 9Cr1MoVNb강의 고온 크리프 특성 평가 연구)

  • Yu, Hyo-Sun;Na, Sung-Hoon;Baek, Seung-Se;Kwon, Il-Hyun;Ahn, Byung-Guk;Na, Eui-Gyun
    • Proceedings of the KSME Conference
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    • 2000.11a
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    • pp.99-104
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    • 2000
  • This paper describes the high temperature creep characteristics for virgin material of 9Cr1MoVNb steel using small punch creep(SP-Creep) test technique which is developing recently. In addition, the several results of SP-Creep test are compared with that of 2.25Cr- 1Mo steel which is widely used as boiler materials and that of conventional uniaxial creep test. The obtained SP-Creep curves show the creep behaviors of three regimes like that obtained from conventional uniaxial creep test, and SP-Creep properties are definitely depended on applied load and test temperature. The correlation of SP-Creep rate and creep rupture life with applied load has been determined like the correlation between creep rate/rupture life and stress in uniaxial creep test, and also is satisfied with Power law. The creep rupture times of newly 9Cr1MoVNb steel are higher than those of 2.25Cr1Mo steel at the same creep temperature and applied loading condition, and the decrease extent of creep rupture life with loads is very lower compared with 2.25Cr1Mo steel.

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Ni Nanoparticle-Graphene Oxide Composites for Speedy and Efficient Removal of Cr(VI) from Wastewater

  • Wang, Wan-Xia;Zhao, Dong-Lin;Wu, Chang-Nian;Chen, Yan;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.31 no.6
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    • pp.345-352
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    • 2021
  • In this study, Ni nanoparticle supported by graphene oxide (GO) (Ni-GO) is successfully synthesized through hydrothermal synthesis and calcination, and Cr(VI) is extracted from aqueous solution. The morphology and structure of Ni-GO composites are characterized by scanning electron microscopy (SEM), trans mission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). High-resolution transmission electron microscopy (HRTEM) and XRD confirms the high dispersion of Ni nanoparticle after support by GO. Loading Ni on GO can obviously enhance the stability of Ni-GO composites. It can be calculated from TGA that the mass percentage of Ni is about 60.67 %. The effects of initial pH and reaction time on Cr(VI) removal ability of Ni-GO are investigated. The results indicate that the removal efficiency of Cr(VI) is greater than that of bared GO. Ni-GO shows fast removal capacity for Cr(VI) (<25 min) with high removal efficiency. Dynamic experiments show that the removal process conforms to the quasi-second order model of adsorption, which indicates that the rate control step of the removal process is chemical adsorption. The removal capacity increases with the increase of temperature, indicating that the reaction of Cr(VI) on Ni-GO composites is endothermic and spontaneous. Combined with tests and characterization, the mechanism of Cr(VI) removal by rapidly adsorption on the surface of Ni-GO and reduction by Ni nanoparticle is investigated. The above results show that Ni-GO can be used as a potential remediation agent for Cr(VI)-contaminated groundwater.

A Study of Comparison of outflow characteristics of pollutants by rainfall event of forest area near Juam lake basin (주암호 유역의 강우사상에 따른 오염물질의 유출특성)

  • Kim, Nam-Joung;Shin, Dae-Yewn
    • Journal of environmental and Sanitary engineering
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    • v.22 no.4
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    • pp.87-104
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    • 2007
  • The objective of this study is to estimate the load of pollutants caused from the forest area among non-point pollutants within the Juam lake. The surveyed forest area was classified into broad-leaved, conifer, mixed and herbage area by forest tree type. Water quality and flux were investigated under rainfall and non-rainfall, respectively. Then, pollutant loading was evaluated by using the values of unit pollutant loading factor of each point and area of forest zone. Water quality analysis results of runoff by forest tree types were as follows. - Annual BOD, $COD_{Mn}\;and\;COD_{Cr}$ concentration of runoff in conifer area was high, and particle and biological recalcitrant compounds were flowed highly. - SS, T-N and T-P concentration was high in runoff from broad-leaved area, and biological degradable compounds was flowed. - Water quality of water from valley was maintained good under non-rainfall and could be utilized as fresh drinking water. Through water quality standard investigation, a countermeasure establishment was necessary to secure a good quality of drinking water - BOD, $COD_{Mn},\;and\;COD_{Cr}$ concentration of Bo-sung river was higher 1.5 times than other 2 streams, and because of high T-N, and T-P concentration in Songgwang stream, the management for this was necessary.