• Title/Summary/Keyword: Cr 도금

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Application of Cr-electroplating Technology for preventing Fuel-Cladding Chemical Interaction (금속연료-피복관 상호반응 방지를 위한 Cr 도금 기술의 적용)

  • Kim, Jun-Hwan;Cheon, Jin-Sik;Kim, Gi-Hwan;Kim, Seong-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.331-331
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    • 2015
  • 차세대 원자로 핵연료의 성능을 제한하는 금속연료-피복관 상호반응 현상(FCCI)을 방지하기 위한 방안으로 Cr 도금기술의 적용성을 연구하였다. 도금 성능을 평가하기 위한 예비 시험 결과 Cr 도금층은 핵연료와 피복관의 상호반응을 억제함이 확인되었다. 도금층 성질을 개선하기 위한 연구와 함께 Cr층을 피복관 내면에 도금하는 연구를 수행하였다.

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The Study on the Corrosion Characteristics of Cr Plating in Marine Environment (해양환경 중에서 Cr도금의 부식 특성에 관한 연구)

  • 임우조;곽남인;윤병두
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.39 no.3
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    • pp.211-217
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    • 2003
  • Recently, with rapid development in marine and shipbuilding industries such as marine structures, ships and chemical plants for ship, there occurs much interest in the study on corrosion characteristics played an important role in mechanical design. This paper was studies on the corrosion characteristics of chromium plating in the marine environment. Under the various specific resistance, the electrochemical polarization test of chromium plating was carried out. And thus corrosion potential, polarization resistance, corrosion current density, control efficiency of corrosion and polarization control behavior of chromium plating are investigated. The main results are as the followed : 1. The polarization resistance of Cr plating and Ni become higher than that of base metal, also and these material become low with decrease of the specific resistance. 2. As the specific resistance decreases, the corrosion current density of Cr and Ni plating is lower than that of base metal. 3. The corrosion reaction of Cr plating, Ni plating and base metal vs. specific resistance is cathodic control.

Membrane에 의한 도금폐수 중 크롬이온의 분리에 관한 연구

  • 이선주;이효숙;정헌생;김동운;주창업
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.04a
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    • pp.59-60
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    • 1994
  • 도금공업은 주로 금속, 플라스틱 등을 소재로 하는 각종 제품의 표면을 전기적 또는 화학적 방법에 따라 석출된 비철금속질로 피복가공하여 제품의 내식, 장식적 효과 내마모성, 전기특성, 광택성, 열특성등 많은 기능을 부가하는 것을 의미한다. 이러한 도금산업은 각종 유해한 화학물질을 취급하는 관계로 도금폐수도 역시 많은 유독한 화학약품이 포함되어 있어 엄격한 규제가 요구되고 있다. 현재의 도금폐수처리는 대부분 위탁업자에 의해 이루어 지고 있으며, 위탁업자는 웅집침전법에 의한 슬러지화(함수율 80% 이하) 하여 매립되고 있는 실정이다. 이 매립물은 침출수를 방출하여 환경에 새로운 문제를 야기시키고 있다. 이러한 도금폐수 중 유가금속(Zn, Cr, Ni, Cu등)을 membrane을 이용하여 회수하고, 생성되는 물을 도금공정에 다시 투입하므로서 공해가 없는 무공해공정을 설계하는 기초자료를 얻는데 본 연구의 목적이 있다. 본 실험에서는 유가금속 중 Cr을 회수하기 위하여 Cr도금 모델폐수를 이용하여 Cr의 농도, 압력, pH등을 변화시키면서 membrane과 Cr의 상관성을 살펴보았다.

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Effects of Heat Treatment Conditions on the Interfacial Reactions and Crack Propagation Behaviors in Electroless Ni/electroplated Cr Coatings (열처리 조건에 따른 무전해 Ni/전해 Cr 이중도금의 계면반응 및 균열성장거동 분석)

  • Son, Kirak;Choi, Myung-Hee;Lee, Kyu Hawn;Byon, Eungsun;Rhee, Byong-Ho;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.69-75
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    • 2016
  • This study investigated the effect of heat treatment conditions not only on the Cr surface crack propagation behaviors but also on the Ni/Cr interfacial reaction characteristics in electroless Ni/electroplated Cr double coating layers on Cu substrate. Clear band layer of Ni-Cr solid solutions were developed at Ni/Cr interface after heat treatment at $750^{\circ}C$ for 6 h. Channeling cracks formed in Cr layer after 1 step heat treatment, that is, heat treatment after Ni/Cr plating, while little channeling cracks formed after 2 step heat treatment, that is, same heat treatments after Ni and Cr plating, respectively, due to residual stress relaxation due to crystallization of Ni layer before Cr plating.

Thermal Cycle Reliabilties and Cracking Characteristics of Electroplated Cr/Ni-P Coatings (전해 Cr/Ni-P 도금막의 열 사이클 신뢰성 및 균열거동 분석)

  • Lee, Jina;Son, Kirak;Lee, Kyu Hwan;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.4
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    • pp.133-140
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    • 2019
  • The effects of thermal cycle conditions on the bonding strength and crack propagation behaviors in electroplated Cr/electroplated Ni-P coatings were systematically evaluated. 1st heat treatment was performed at 500℃ for 3 hours after electroplating Ni-P, and then, 2nd heat treatment was performed at 750℃ for 6 hours after electroplating Cr. The measured bonding strength by ASTM C633 were around 25.6 MPa before thermal cycling, while it increased to 47.6 MPa, after 1,000 cycles. Increasing thermal cycles led to dominant fail mode with cohesive failure inside adhesive, which seemed to be closely related to the increasing bonding strength possibly not only due to higher Cr surface roughness, but also to penetrated channeling crack density. Also, increasing density of penetrated channeling cracks in electroplating Cr layer led to slightly stronger bonding strength due to mechanical interlocking effects of adhesive inside channeling cracks.

Development of Ni/Cr Plating Process for LRE Thrust Chamber (액체로켓엔진 연소기용 니켈/크롬 코팅의 공정 개발)

  • Cho, Hwang-Rae;Bang, Jeong-Suk;Rhee, Byung-Ho;Lee, Kwang-Jin;Lim, Byoung-Jik;Han, Yeoung-Min;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.603-607
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    • 2009
  • A Ni/Cr plating process has been developed for applying to inner wall of liquid rocket engine(LRE) thrust chamber. Ni plating conditions were selected through thermal shock test and endurance verification of the plating layers was performed through hot firing test of a subscale thrust chamber with Ni/Cr plating. Test results showed that a crack or separation of the plating layers was not found. Judging from the results, Ni/Cr plating could be applied to LRE thrust chamber as a substitute of air plasma sprayed ceramic coating which is presently being used.

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Study on Ni-Cr Electro Plating Process for Staged Combustion Cycle Engine (다단연소사이클 엔진 적용을 위한 Ni-Cr 코팅에 관한 연구)

  • Bae, Byung-Hyun;Hwang, Yang-Jin;Lee, Kyu-Hwan;Rhee, Byong-ho;Han, Yeoung-Min;Kim, Young-June;Noh, Yong-Oh;Cho, Hwang-Rae;Hyun, Seong-Yoon;Bang, Jeong-Suk
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.857-863
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    • 2017
  • In this paper, the process of electro Ni and electro Cr plating is studied for the purpose of thermal barrier to protect the inner wall combustion chamber. The chamber is under the environment of very high temperature and high pressure when propellants burn in there. As one of the thermal barrier coatings, Zr-based thermal spray coating has been applied to the chamber. However, peeling of coating layer can occur under such a hard condition because of the difference of thermal expansion coefficients between the ceramic and the metallic wall. We study the characteristics of Ni-Cr coating and establish its process. It is found that the thickness of over $100{\mu}m$ of Ni and Cr coating layers with the uniformity of ${\pm}10%$ can be obtained with the used of as-developed plating bath.

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Zn-Cr Alloy Plating from Acidic Chloride Bath: Effect of Temperature and Current Densities on Composition of Electrodeposits (산성염화욕에서의 Zn-Cr합금도금 : 합금화에 미치는 전류밀도와 온도의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
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    • v.9 no.11
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    • pp.285-290
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    • 2018
  • The steel has been used in modern industry, car maker and electric appliance. The steel have some problem, specially corrosion problem. To solve corrosion problem, Zn electrodeposit on steel have been adapted. Recently, The modern industry asks to increase corrosion resistance. Naturally, Increasing corrosion resistance increases the thickness of Zn electrodeposit. But increasing thickness of Zn electrodeposit has some problems. In making part, There are some crack. This crack cause to decrease corrosion resistance. To solve this problem, it is interested in Zn Based alloy electrodeposit such as Zn-Cr. Here, the influence of the electrolytic conditions on the composition of the alloy plating in the chloride bath was investigated. The results are explained by the cathode overvoltage curve of Cr and Zn. As the current density of the cathode increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase. As the temperature of the electrolyte increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase.