• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.1
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• pp.124-129
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• 2010

When a phenolic resin is carbonized by the leakage current flowing along its surface, the carbonization pattern is one of the most important factors to determine its carbonization characteristics. However, the typical carbonization pattern of a phenolic resin is too complicated to be analyzed by conventional Euclidean geometry. In most cases, such a complicated shape shows a fractal structure. It is possible, therefore, to examine the characteristics of the carbonization pattern regarding a given phenolic resin. In order to quantitatively investigate the carbonization pattern of the phenolic resin carbonized by a leakage current, in this paper, the fractal dimension of the carbonization pattern has been calculated as a function of the magnitude of a leakage current and the distance between two electrodes. For reliability of calculation, the correlation function as well as the box counting method has been used to calculate the fractal dimension. According to the result of calculation, the fractal dimension increases as the current increases at the constant electrode gap distance. However, there is no significant relation between the fractal dimension and the electrode gap distance at a constant current.

• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4671-4678
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• 2022

The purpose of this comprehensive research is to observe the impact of scintillator crystal type on entire detection process. For this aim, MCNPX (version 2.6.0) is used for designing of a physical plastic scintillation detector available in our laboratory. The modelled detector structure is validated using previous studies in the literature. Next, different types of plastic scintillation crystals were assessed in the same geometry. Several fundamental detector properties are determined for six different plastic scintillation crystals. Additionally, the deposited energy quantities were computed using the MCNPX code. Although six scintillation crystals have comparable compositions, the findings clearly indicate that the crystal composed of PVT 80% + PPO 20% has superior counting and detecting characteristics when compared to the other crystals investigated. Moreover, it is observed that the highest deposited energy amount, which is a result of the highest collision number in the crystal volume, corresponds to a PVT 80% + PPO 20% crystal. Despite the fact that plastic detector crystals have similar chemical structures, this study found that performing advanced Monte Carlo simulations on the detection discrepancies within the structures can aid in the development of the most effective spectroscopy procedures by ensuring maximum efficiency prior to and during use.

• Analytical Science and Technology
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• v.16 no.5
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• pp.391-398
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• 2003

Basic research for the determination of boron content in biological sample has been carried out using the PGAA facility of the 24MW research reactor(HANARO). For investigation of characteristics for the measurement condition, neutron flux and its homogeneity were measured at irradiating geometry. The size of thermal neutron beam collimated from beam guide is $2{\times}2cm^2$ at the sample position. The neutron flux measured was the range of $1.0{\sim}6.5{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$, and flux distribution from center within the radius of 4.5 mm and 9.0 mm was $5.77{\pm}0.71{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$ and $4.68{\pm}1.64{\times}10^7n{\cdot}cm^{-2}{\cdot}s^{-1}$, respectively. Accordingly, sample size is adjusted within 10 mm for a homogeneous irradiation of high quality. Measurement system is designed to reduce the background source by Compton scattering and to improve the analytical sensitivity. To investigate the energy calibration and Compton suppression effect of gamma-ray counting system, the background conditions on both of Compton and single-mode were measured using NaCl standard. On the other hand, degree of spectral interference for sodium 472 keV peak as a matrix effect in the sample is established for an accurate boron analysis, and then boron content in three certified reference materials (NIST SRM 1570a, 1547, 1573a) was measured by using two modes and the results were compared with each other.

• Bulletin of the Korean Chemical Society
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• v.16 no.11
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• pp.1067-1074
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• 1995

Reaction of arachno-S2B7H8- with either THF or 1,2-dimethoxyethane upon refluxing condition results in the formation of the previously known compound hypho-S2B7H10-. Protonation of hypho-S2B7H10- with HCl/Et2O generates hypho-2,5-S2B7H11 in good yield. This hypho-S2B7H10- anion has been employed to generate a series of new nido-, arachno-, and hypho-metalladithiaborane clusters. Reaction of the anion with Cp(CO)2FeCl results in direct metal insertion and the formation of a complex containing the general formula (η5-C5H5)FeS2B7H8. Spectroscopic studies of nido-6-CpFe-7,9-S2B7H8 Ⅰ demonstrated that compound Ⅰ was shown to have an nido-type cage geometry derived from an octadecahedron missing one vertex, with the iron atom occupying the three-coordinate 6-position in the cage and the two sulfurs occupying positions on the open face of the cage. Reaction of hypho-S2B7H10- with CoCl2/Li+[C5H5]- gave the previously known complex arachno-7-CpCo-6,8-S2B6H8 Ⅱ. Also, the reaction of the anion with [Cp*RhCl2]2 gave the complex arachno-7-Cp*Rh-6,8-S2B6H8 Ⅲ, the structure of which was shown to be that of complex Ⅱ. The similarity of the NMR spectra of Ⅱ and Ⅲ suggest that Ⅲ adopts cage structure similar to that previously confirmed for Ⅱ. A series of 9-vertex hypho clusters in which the sulfur atoms are bridged by different species isoelectronic with a BH3 unit, such as HMn(CO)4 or SiR2 have been prepared. Compounds Ⅳ,Ⅴ and Ⅵ are each 2n+4 skeletal electron systems and would be expected according to skeletal electron counting theory to adopt hypho-type polyhedral structures derived from an icosahedron missing three vertices. The complex hypho-1-(CO)4Mn-2,5-S2B6H9 Ⅳ was obtained by the reaction of the anion with (CO)5MnBr and has been shown from spectroscopic data to consist of a (CO)4Mn fragment bound to the two sulfur atoms S2 and S5 of hypho-S2B7H10-. Also, similar hypho-type complexes hypho-1-R2Si-2,5-S2B6H8 (R=CH3 Ⅴ, R=C6H5 Ⅵ) have been prepared from the reaction of hypho-S2B7H10- with R2SiHCl.