• Journal of the Korean Society of Combustion
• /
• v.13 no.1
• /
• pp.31-43
• /
• 2008

Oxy-fuel flame has a significantly different structure from that of air-fuel flame because of its high temperature. This study is aimed to find out the difference of the oxy-fuel flame structure in order to understand reaction mechanism closely, which is crucial to design real-scale oxy-fuel combustion system. By examining pictures of counterflow flame and LIF images, we found that oxy-fuel flame had two-zone structure: fuel decomposition region and distributed CO oxidation region. In the oxy-fuel flame, OH radical was distributed intensely through the whole flame due to its higher flame temperature than crossover temperature. For showing those features of the oxy-fuel flame, 1 MW scale IFRF oxy-natural gas burner was simulated by conditional moment closure(CMC) model. Calculation results were compared with experimental data, and showed agreements in trend. In the simulated distributions of fuel decomposition/CO oxidation rates, CO oxidation region was also separated from fuel decomposition zone considerably, which showed the two-zone structure in the oxy-fuel flame.

• Journal of the Korean Society of Combustion
• /
• v.20 no.4
• /
• pp.34-41
• /
• 2015

Oxy-methane nonpremixed flames diluted with $CO_2$ were investigated to clarify impact of radiation heat loss and chemical effects of additional $CO_2$ to oxidizer stream on flame extinction. Flame stability maps were presented with functional dependencies of critical diluents mole fraction upon global strain rate at several oxidizer stream temperatures in $CH_4-O_2/N_2$, $CH_4-O_2/CO_2$, and $CH_4-O_2/CO_2/N_2$ counterflow flames. The effects of radiation heat loss on the critical diluent mole fractions for flame extinction are not significant even at low strain rate in nonpremixed $CH_4-O_2/N_2$ diffusion flame, whereas those are significant at low strain rate and are negligible at high strain rate (> $200s^{-1}$) in $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ counterflow flames. Chemical effects of additional $CO_2$ to oxidizer stream on the flame extinction curves were appreciable in both $CH_4-O_2/CO_2$ and $CH_4-O_2/CO_2/N_2$ flames. A scaling analysis based on asymptotic solution of stretched flame extinction was applied. A specific radical index, which could reflect the OH population in main reaction zone via controlling the mixture composition in the oxidizer stream, was identified to quantify the chemical kinetic contribution to flame extinction. A good correlation of predicted extinction limits to those calculated numerically were obtained via the ratio between radical indices and oxidizer Lewis numbers for the target and baseline flames. This offered an effective approach to estimate extinction strain rate of nonpremixed oxy-methane flames permitting air infiltration when the baseline flame was taken to nonpremixed $CH_4-O_2/N_2$ flame.

• 한국연소학회:학술대회논문집
• /
• 2015.12a
• /
• pp.183-184
• /
• 2015

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.12 no.1
• /
• pp.72-80
• /
• 1988

Partially premixed diffusion system is analyzed using the matched asymptotic expansion technique adopting counterflow with supplying fuel and oxidizer from one side and fuel only from the other as a model problem. Results show that single-stage extinction always occurs as stretch increases, and the partially premixed diffusion flame can hardly exist. Depending on the initial mixture concentrations, either premixed or diffusion flame extinction leads to complete extinction of the system, and the diffusion flame can change its character to premixed flame such that two premixed flames can exist in the partially premixed-diffusion system.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.11 no.6
• /
• pp.991-1000
• /
• 1987

Existence of triple flames in a lean-rich concentration field is studied both experimentally and theoretically using large activation energy asymptotic technique adopting counterflow system as a model problem. Experiment shows that in triplet system of a lean and a rich premixed flame separated by a diffusion flame, either lean or rich premixed flame merges with diffusion flame as stretch is increased, such that transition boundary between 3-flame and 2-flame exists. The region in which 3-flame can exist forms an island within rich-lean concentration fields for large stretch, where as it is extends to the line of (.OMEGA.$_{0}$/.OMEGA.$_{F}$)$_{R}$=0 or (.OMEGA.$_{F/}$.OMEGA.$_{0}$)$_{L}$=0 for small stretch. Theoretical results show the qualitative agreement with experiment and the existence of limiting stretch over which 3-flame can not exist.t.t.t.t.t.t.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.32 no.5
• /
• pp.351-358
• /
• 2008

Extinction characteristics of hydrogen-air diffusion flames at various pressures are investigated numerically by adopting counterflow flame configuration as a model flamelet. Especially, effect of radiative heat loss on flame extinction is emphasized. Only gas-phase radiation is considered here and it is assumed that $H_2O$ is the only radiating species. Radiation term depends on flame thickness, temperature, $H_2O$ concentration, and pressure. From the calculated flame structures at various pressures, flame thickness decreases with pressure, but its gradient decreases at high pressure. Flame temperature and mole fraction of $H_2O$ increase slightly with pressure. Accordingly, as pressure increases, radiative heat loss becomes dominant. When radiative heat loss is considered, radiation-induced extinction is observed at low strain rate in addition to transport-induced extinction. As pressure increases, flammable region, where flame is sustained, shifts to the high-temperature region and then, shrunk to the point on the coordinate plane of flame temperature and strain rate. The present numerical results show that radiative heat loss can reduce the operating range of a combustor significantly.

• Journal of Advanced Marine Engineering and Technology
• /
• v.26 no.2
• /
• pp.209-218
• /
• 2002

The temperature field of a counterflow non-premixed flame is investigated using thermocouples of two sizes. A thermal balance is performed on the thermocouple in order to calculate the magnitude of the radiation corrections involved. Both the thermocouple wire and bead are separately considered to be the relevant thermal surface to which convective heat transfer takes place, and from which radiation lasses occur. The flame is also simulated by using a detailed chemical kinetic mechanism in a previously developed computer code. The local thermo-physical properties of the gas mixture, required to calculate the corrections, are determined both from the simulation, and by approximating the properties of the mixture as those of molecular nitrogen at the measured temperatures. It is concluded that the thermocouple wire is the appropriate thermal surface to which radiation corrections apply, in the absence of information about the gas mixture, its properties can be reasonably approximated by those of nitrogen rm ($N_2$), and the radiation corrections are very sensitive to misalignments in the temperature and velocity fields.

• Fire Science and Engineering
• /
• v.28 no.3
• /
• pp.20-28
• /
• 2014

Effect of radiation models on the suppression limits in counterflow $CH_4$/air diffusion flame was numerically investigated with fundamental experiments for the numerical validation. $N_2$ and $CO_2$ were considered as extinguishing agents. The differences in extinguishing concentration between OTM and SNB radiation models which have different accuracy levels were examined. As a result, there is no considerable difference in extinguishing concentration for the $N_2$ dilution as the radiation models with different accuracy levels were used. As the $CO_2$ having strong radiative effect was diluted in the low strain flames, however, the radiation model with high predictive accuracy such as SNB should be used. In particular, the $CO_2$ dilution in fuel stream leads to the significant difference in extinguishing concentration between OTM and SNB models. Therefore, it is necessary that the radiation model should be reasonably chosen with the consideration of numerical accuracy and computational time for the prediction of extinguishing concentration.

• Journal of the Korean Institute of Gas
• /
• v.23 no.6
• /
• pp.8-16
• /
• 2019

One of the methods for low-pollution combustion, flue gas recirculation(FGR) is effective to reduce nitrogen oxides and it was applied in CH₄/air premixed counterflow flames to identify the change of flame characteristics and NOx mechanisms. Considering that the mole fraction of the products varied depending on the strain rates, the major products: CO₂, H₂O, O₂ and N₂ were recirculated as a diluent to reflect the actual combustion system. With the application of the FGR technique, a turning point of maximum flame temperature under certain strain rate condition was found. Furthermore as the recirculation ratio increased, the tendency of NO was changed before and after the turning point and the analysis on thermal NO and Fenimore NO production was conducted.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.21 no.9
• /
• pp.1218-1229
• /
• 1997

The diffusional-thermal instability of diffusion flames in the premixed-flame regime is studied in a constant-density two-dimensional counterflow diffusion-flame configuration, to investigate the instability mechanism by which periodic wrinkling, travelling or pulsating of the reaction sheet can occur. Attention is focused on flames with small departures of the Lewis number from unity and with small values of the stoichiometric mixture fraction, so that the premixed-flame regime can be employed for activation-energy asymptotics. Cellular patterns will occur near quasisteady extinction when the Lewis number of the more completely consumed reactant is less than a critical value( ~ =0.7). Parametric studies for the instability onset conditions show that flames with smaller values of the Lewis number and stoichiometric mixture fraction and with larger values of the Zel'dovich number tend to be more unstable. For Lewis number greater than unity, near-extinction flame are found to exhibit either travelling instability or pulsating instability.