• 분석과학
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• 제8권2호
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• pp.205-213
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• 1995

알루미나에 흡착된 coronene이 tetra-phenylporpine에 의해 탈착되어 역확산되는 과정을 분광광도법을 이용하여 조사하였다. 액상에서 진행되는 흡착되는 물질과 탈착되는 물질의 역확산과정을, 교차하는 물질의 확산량이 같다는 가정 아래 Fritz 2 성분 흡착등온식을 적용한 역확산 모델로 모사하였다. Tetra-phenylporphine에 의해 탈착되는 과정에서 결정된 coronene 의 역확산계수는 ${\sim}10^{-15}m^2/sec$였으며, 흡착되는 과정에서 결정된 tetra-phenylporphine의 역확산계수는 ${\sim}10^{-11}m^2/sec$였다. 탈착되는 과정에서 결정된 coronenne의 역확산계수가 단일 성분의 흡착과정에서 결정된 확산계수에 비해 $10^5$배 정도로 적게 결정되는 이유는, 확산 교차에 의한 효과뿐 아니라 탈착과정에서 세공내 coronene의 농도 구배가 커진 데 기인하는 것으로 설명되었다.

• 공업화학
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• 제10권4호
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• pp.608-614
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• 1999

촉매 담체로 사용되는 알루미나와 실리카-알루미나에 흡착된 tetra-phenylprophine과 coronene이 아세톤의 주입에 의해 탈착되는 역확산 과정과, coronene이 tetra-phenylporphine 용액에 의한 역확산 과정을 조사하였다. 이상흡착용액 이론을 적용한 역확산 모델을 이용하여 역확산 과정을 해석하고 모사한 결과로부터 역확산 계수를 결정하였다. 과량의 아세톤 주입에 의한 탈착에서 tetra-phenylporphine과 coronene의 역확산 계수는 ${\sim}10^{-15}m^2/sec$ 범위로 얻어졌다. 흡착용액과 비슷한 농도를 갖는 tetra-phenylprophine 용액에 의한 역확산의 경우 탈착되는 coronene의 역확산 계수의 값도 ${\sim}10^{-15}m^2/sec$ 범위에 있으며, 세공내로 들어가는 tetra-phenylporphine의 확산 계수는 ${\sim}10^{-11}m^2/sec$ 이었다. 흡착제 밖으로 탈착되어 나오는 coronene의 역확산 계수는 아세톤이나 tetra-phenylporphine 용액의 주입에 의한 흡착-탈착의 경우 탈착제는 종류와 양에 관계없이 모두 비슷한 범위의 값을 보여 주었다. 역확산계수는 비어 있는 세공내로의 확산에 대한 유효확산계수에 비해 현저히 감소하였다. 이러한 현상은 역확산 과정에 나타나는 확산 흐름의 교차에 기인하는 것으로 설명되었다.

• Korean Membrane Journal
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• 제3권1호
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• pp.39-50
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• 2001

The counter-diffusion of two gaseous substances permeating a polymeric membrane has been investigated both experimentally and theoretically. The aim of the study was to find mutual effects, if any, that could influence the permeability and diffusivity data. The experimental data were obtained with an isostatic permeameter operating at ambient pressure and 303 K: helium, nitrogen, carbon dioxide methane were used as permeating gas at different partial pressure; helium or nitrogen as equilibrating or carrier gas. No evident mutual effect of the counter-diffusing gas was observed. The theoretical analysis gave some insight into the phenomena and it was concluded that at near-atmospheric pressures, and in the absence of swelling phenomena no mutual interaction exists. On a theoretical basis any mutual interaction between diffusing and counter-diffusing gases could only occur: i) at high pressures , when the free movement of permeating gas molecules within the polymer is hindered by the counter-diffusing gas; ii) when a large part of the free volume fraction is occupied by the counter--diffusing gas; iii) swelling phenomena modify the structure and free volume fraction of the polymer.

• 한국응용과학기술학회지
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• 제26권4호
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• pp.451-456
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• 2009

We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.

• 한국응용과학기술학회지
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• 제27권2호
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• pp.202-207
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• 2010

We investigated the electrochemical properties for Langmuir-Blodgett(LB) films mixed with l-bromotetradecane(Cl4), l-bromohexadecane(Cl6), and l-bromooctadecane(Cl8). The alkyl bromides mixture was deposited by using the Langmuir-Blodgett method on the ITO glass. The electrochemical properties measured by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, 1.5 and 2.0 N) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 m V, continuously oxidized to 1650 mV. The scan rate was 100 mV/s. As a result, LB films of Cl4, Cl6, and Cl8 mixture monolayers appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl bromides amount.

• 대한기계학회논문집B
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• 제41권10호
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• pp.667-673
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• 2017

공개소스 전산유체 해석 라이브러리인 OpenFOAM을 이용하여 음극 지지체형 고체산화물 연료전지의 온도균일성에 관한 연구를 수행하였다. 3가지 유형의 유동흐름(병행류, 대향류, 직교류)에 대하여 수치해석이 이루어졌다. 다공성 물질내에서의 기체의 흐름은 유효확산계수를 이용하여 계산하였고 분리판의 리브 영향도 고려하였다. 전기화학반응의 계산을 위하여 실험식으로부터 얻은 집중내부저항 모델이 사용되었다. 수치해석 결과 대향류가 가장 균일한 온도분포를 나타내었다.

• Bulletin of the Korean Chemical Society
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• 제4권3호
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• pp.128-132
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• 1983

The self-diffusion experiment of water was performed across two series of tactic poly(2-hydroxyethyl methacrylate), P(HEMA) membranes prepared by crosslinking with various amount of hexamethylene diisocyanate (HMDIC). The tagging material was tritium hydroxide (THO) and the efflux of THO was counted on a Liquid Scintillation Counter. The transport data of THO show that the permeability decreases as the amount of HMDIC increased from 2.5 to 10 mole % and the self-diffusions coefficient shows a parallel trend with it. The diffusivity data was discussed in terms of the change of water structural orderliness within membranes. Using the relation between viscosities and diffusivities derived from Eyring's absolute rate theory, the corresponding viscosities of water within two series of tactic P(HEMA) membranes were obtained. From this, it is seen that the viscosity of water within tactic P(HEMA) membranes may have the same values with those of supercooling water whose temperature ranges from -28 to -$36^{\circ}C.$.

• 한국응용과학기술학회지
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• 제26권4호
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• pp.400-406
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• 2009

We investigated the electrochemical properties for Langmuir-Blodgett (LB) films of functionalized polyimide. LB films of polyimide monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, and 1.5 N) of $NaClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100 and 150 mV/s, respectively. As a result, monolayer and multilayer LB films of polyimide are appeared on irreversible process caused by the oxidation current from the cyclic voltammogram.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.104-108
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• 1984

The self-diffusion experiment of THO was performed across a series of copolymer hydrogel membranes at different temperatures. Copolymer hydrogel membranes were prepared by copolymerizing 2-hydroxyethyl methacrylate (HEMA) and 2-aminoethyl methacrylate (AEMA) in the presence of the solvent and the crosslinker, ethylene glycol dimethacrylate (EGDMA). By changing the crosslinker content and the ratio of HEMA and AEMA monomer, two series of copolymer hydrogel membranes were synthesized. The tagging material was THO and efflux of THO was counted on a Liquid Sc-intillation Counter. The experimental data show that the permeability decreases as the amount of EGDMA and the mole fraction of HEMA increase, and the permeability is proportional to the temperature. The partition coefficient shows a parallel trend with permeability. Using the relationship between viscosity and diffusivity, the viscosity of water within the membrane was obtained. According to the result, the viscosity of watler within the membrane has the same value with those of supercooling water. And we obtained the activation energy of THO for transport in the membrane by using Arrhenius plotting.

• 한국응용과학기술학회지
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• 제32권2호
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• pp.275-280
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• 2015

본 연구에서는 스테인리스강을 사용하여 전형적인 3-전극 시스템의 순환전류전압법으로 트리 에탄올아민(TEA) 용액 중에서 전류-전압 곡선을 측정하였다. 스테인리스강은 작업 전극으로, Ag/AgCl 전극은 기준 전극으로, 그리고 백금 선은 상대 전극으로 각각 사용하였고, 그 결과, 트리에탄올아민 용액에서의 스테인리스강의 C-V 특성은 순환전류전압법으로부터 산화전류에 기인한 비가역 공정으로 나타났다. 부식억제제의 확산계수의 효과는 농도 증가에 따라 감소하였다. 그리고 부식억제 효과는 농도 0.5 N의 $NaClO_4$, $2.5{\times}10^{-3}M$ TEA용액에서 가장 컸으며, 1.5 N $NaClO_4$, $1.0{\times}10^{-3}M$ TEA용액에서 가장 낮았다.