• Korean Journal of Materials Research
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• v.15 no.8
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• pp.528-535
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• 2005

It is inclined to increase that use of hazardous substances such as lead(Pb), mercury (Hg), cadmium(Cd) etc. are prohibited in the electronics according to environmental friendly policies of an advanced nation for protecting environment of earth. As this reasons, many researches for ensuring the reliability were proceeding in Pb free soldering process. n the flux remains on the PCB(printed circuit board) in the soldering process or the electronics exposed to corrosive environment, it becomes the reasons of breakdown or malfunction of the electronics caused by corrosion. Therefore in this studies we researched the polarization and Tafel properties of Sn40Pb and SnCu system solders based on the electrochemical theory. The experimental polarization curves were measured in distilled ionized water and 1 mole $3.5 wt\%$ NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrodes, respectively. To observe the electrochemical reaction, polarization test was conducted from -250mV to +250mV. From the polarization curves composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density((cow). In these results, we compared the corrosion rate of SnPb and SnCu solders.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.105-105
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• 2016

Recently, high power impulse magnetron sputtering (HIPIMS) has attracted considerable attentions due to its high potential for industrial applications. By pulsing the sputtering target with high power density and short duration pulses, a high plasma density and high ionization of the sputtered species can be obtained. HIPIMS has exhibited several merits such as increased coating density, good adhesion, microparticle-free and smooth surface, which make the HIPIMS technique desirable for synthesizing hard coatings. However, hard coatings present intrinsic defects (columnar structures, pinholes, pores, discontinuities) which can affect the corrosion behavior, especially when substrates are active alloys like steel or in a wear-corrosion process. Atomic layer deposition (ALD), a CVD derived method with a broad spectrum of applications, has shown great potential for corrosion protection of high-precision metallic parts or systems. In ALD deposition, the growth proceeds through cyclic repetition of self-limiting surface reactions, which leads to the thin films possess high quality, low defect density, uniformity, low-temperature processing and exquisite thickness control. These merits make ALD an ideal candidate for the fabrication of excellent oxide barrier layer which can block the pinhole and other defects left in the coating structure to improve the corrosion protection of hard coatings. In this work, CrN/Al2O3/CrN multilayered coatings were synthesized by a hybrid process of HIPIMS and ALD techniques, aiming to improve the CrN hard coating properties. The influence of the Al2O3 interlayer addition, the thickness and intercalation position of the Al2O3 layer in the coatings on the microstructure, surface roughness, mechanical properties and corrosion behaviors were investigated. The results indicated that the dense Al2O3 interlayer addition by ALD lead to a significant decrease of the average grain size and surface roughness and greatly improved the mechanical properties and corrosion resistance of the CrN coatings. The thickness increase of the Al2O3 layer and intercalation position change to near the coating surface resulted in improved mechanical properties and corrosion resistance. The mechanism can be explained by that the dense Al2O3 interlayer acted as an excellent barrier for dislocation motion and diffusion of the corrosive substance.

• Journal of the Korean Chemical Society
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• v.46 no.5
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• pp.444-456
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• 2002

To protect the occurrence of the oxidation of car body, we developed antioxidizing device made with sacrificial anode. Because car body is made of iron and iron-alloy and oxidation potential of Mg, Al and Zn is higher than that of iron, sacrificial anodes were made with Mg, Al and Zn. Accordingly, Mg, Al and Zn are better oxidizing than car body, iron and iron-alloy can be protected from oxidizing. We have made an antioxidizing device and evaluated their anti-corrosive effect for iron piece in the solution of hydrochloric, nitric and sulfuric acid using balance, SEM and XPS. When iron pieces were connected with antioxidizing device of car body, weight loss by oxidation was remarkably reduced and surface corrosion of iron piece was protected. It was shown that the surface of iron pieces which is not con-nected to the device was changed to iron(Ⅲ) oxide, Fe$_2$O$_3$. Therefore, if this device is attached to car body, corrosion and oxidation of car body will be reduced, considerably.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.49-52
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• 2008

The tensile and bond performance of GFRP rebar are different from those of conventional steel reinforcement. It requires some studies on concrete members reinforced with GFRP reinforcing bars to apply it to concrete structures. GFRP has some advantages such as high specific strength, low weight, non-corrosive nature, and disadvantage of larger deflection due to the lower modulus of elasticity than that of steel. Bridge deck is a preferred structure to apply FRP rebars due to the increase of flexural capacity by arching action. This paper focuses on the behavior of concrete bridge deck reinforced with newly developed GFRP rebar. A total of three real size bridge deck specimens were made and tested. Main variable was reinforcement ratio of GFRP rebar. Static test was performed with the load of DB-24 level until failure. Test results were compared and analyzed with ultimate load, deflection behavior.

• Journal of Environmental Science International
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• v.19 no.6
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• pp.665-670
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• 2010

Pollutants from urban pavement consists various kinds of substances which are originated from dry deposition, a grind out tire, corrosive action of rain to pavement and facilities and raw materials of the road etc.. These are major pollutants of urban NPS (Non-point source) during rainfall period. However there is not enough information to control such pollutants for appropriate management of natural water quality. In this study of transportation areas, three monitoring stations were set up at trunk road, urban highway and national road in Gyeongnam province. Runoff flow rate was measured at every 15minutes by automatic flow meters installed at the end of storm sewer pipe within the road catchment area for water quality analysis. Data was collected every 15 minutes for initial two hours of rainfall. Additional samples were collected 1-4 hours interval till the end of rainfall. The monitoring parameters were $COD_{Mn}$, SS, T-N & T-P and heavy metals. The average EMCs of TSS and $COD_{Mn}$ were 62.0 mg/L and 24.2 mg/L on the city trunk road, which were higher than those of urban highway and national road, indicating higher pollutant loads due to activities in the city downtown area beside the vehicle. On the other hand, the average EMC of T-N and T-P were in the range of 2.67-3.23 mg/L and 0.19-3.21 mg/L for all the sampling sites. Heavy metals from the roads were mainly Fe, Zn, Cu and Mn, showing variable EMCs by the type of road. From the TSS wash-off analysis in terms of FF(first flush) index, first flush phenomenon was clearly observed in the trunk road(FF : 0.89-1.43). However, such mass delivery behavior was not apparently shown in urban highway(FF : 0.90-1.11) and national road(FF : 0.81-1.41).

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.529-532
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• 2008

Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. In severe cases, scaling can result in dislodgement of coarse aggregate. This research estimates that pH and test of specific pollutants, dynamic modulus of elasticity for freeze-thaw test of concrete were higher than those NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w), also weight losses for scaling test of concrete were much lower than those of NaCl, $CaCl_2$, and NaCl+$CaCl_2$(7:3, w/w).

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.561-564
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• 2008

Concrete scaling is the progressive surface deterioration of susceptible subjected to freeze-thaw cycling in the presence of moisture. Particularly, it has been recognized that chlorides present in deicing agents can significantly increase concrete surface scaling. Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Use of deicing chemicals has been and will continue to be a major part of highway snow and ice control methods. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. Extensive use of chloride deicers is, however, not only the source of substantial cost penalties due to their corrosive action and ability to deterioration roadway surface materials but also the source of environmental damages. In this study, Use of (40, 27, 21MPa) pavement concrete analyze freeze-thaw test and scaling on the chlorides present.

• Journal of Navigation and Port Research
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• v.30 no.4
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• pp.291-294
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• 2006

Corrosion is never avoided in the use rf materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic Protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. This thesis is about the ICCP control and monitoring system, which brings protection against the corrosion of the ship's hull in the sea environments. The test system for ICCP is composed of a power supply, anode, reference electrode and controller. The test system is composed power supply, anode, ref electrode, shunt and etc. The protection current is sent to the protection area though anode. Reference electrode senses whether or not the detected potential is within a range of protection of test equipment and then it is automatically controlled to increase or decrease the amount of protective current to be sent to the anode by controller. The monitoring system with LabView is also detected in order to check the normal state of the system at operation period, because an operator does not always watch over this system and thus the system cannot operate well because rf his or her negligent management. This paper was studied the variation of potential and current density with environment factors, velocity and time, and the experimental results will be explained Also, It is suggested that this system can accommodate a ship's automation for SCMS(Ship Control and Management System) and will be very useful.

• Corrosion Science and Technology
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• v.6 no.2
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• pp.37-43
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• 2007

Iodine sulfur (IS) process is one of the promising processes for a hydrogen production by using a high temperature heat generated by a very high temperature gas cooled reactor(VHTR) in the nuclear power industries. Even though the IS process is very efficient for a hydrogen production and it is not accompanied by a carbon dioxide evolution, the highly corrosive environment of the process limits its application in the industry. Corrosion tests of selected materials were performed in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Fe-Cr alloys, Fe-Ni-Cr alloys, Fe-Si alloys, Ni base alloys, Ta, Ti, Zr, SiC, Fe-Si, etc. The test environments were 50 wt% sulfuric acid at $120^{\circ}C$ and 98 wt% at $320^{\circ}C$. Corrosion rates were measured by using a weight change after an immersion. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. Corrosion behaviors of the materials were discussed in terms of the chemical composition of the materials, a weight loss, the corrosion morphology, the precipitates in the microstructure and the surface layer composition.

• Corrosion Science and Technology
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• v.15 no.6
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• pp.303-310
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• 2016

The tap water used in Seoul was found to be corrosive. Its corrosivity was effectively reduced by that the additions of alkali agent such as NaOH, $Ca(OH)_2$ and corrosion inhibitor such as $H_3PO_4$. For the corrosion test, carbon steel pipe 50 m long was exposed to the drinking water produced by a pilot plant at $36.5^{\circ}C$, similar to the existing process where it takes about 20 minutes to reduce the initial chlorine content of 0.5 mg/L to 0.05 mg/L. $CO_2$ and $Ca(OH)_2$ was added not only to control the Langelier index (LI) above -1.0 and but also, to increase the duration time of residual chlorine by about 6 times. The persistence effect of residual chlorine was in the order of $H_3PO_4$ > $Ca(OH)_2$ > NaOH. Measurements of weight loss showed that corrosion inhibition was effective in order of $Ca(OH)_2$ > $H_3PO_4$ > NaOH > no addition, where the concentrations of $Ca(OH)_2$ and phosphate were 5 ~ 10 mg/L (as $Ca^{2+}$) and 1 mg/L (as $PO{_4}^{3-}$), respectively.