• Title/Summary/Keyword: Corrosive

Search Result 719, Processing Time 0.027 seconds

HVOF Spray Coating of Co-alloy(T800) for the Improvement of durability of High Speed Spindle (초고속 회전체의 내구성향상을 위한 Co-alloy(T800)의 초고속 용사코팅)

  • Cho, Tong-Yul;Yoon, Jae-Hong;Kim, Kil-Su;Youn, Suk-Jo;Back, Nam-Ki;Park, Byung-Chul;Chun, Hui-Gon
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.15 no.6
    • /
    • pp.32-37
    • /
    • 2006
  • Micron size Co-alloy(T800) powder was coated on Inconel 718 by HVOF thermal spraying for the studies of the improvement of durability of high speed spindle by using Taguchi program for the parameters of spray distance, flow rates of hydrogen and oxygen and powder feed rate. The optimal coating process was determined by the studies of coating properties such as micro-structure, porosity, surface roughness and micro hardness. Friction and wear behaviors of coatings were investigated by sliding wear test at room temperature and $1000^{\circ}F(538^{\circ}C)$. At both room temperature and $538^{\circ}C$ the sliding wear debris and friction coefficients of the coating were drastically reduced compared with the surface of non-coated parent material. This shows that Co-alloy powder coating is highly recommendable for the durability improvement surface coating of high speed air-bearing spindle. At high temperature wear traces and friction coefficients of both coating and non-coating were drastically reduced compared with those of room temperature since the brittle oxides were formed easily on the surface, and the brittle oxide phases were attrited by the reciprocating sliding wear according to the complicated mixed wear mechanisms These oxide particles, partially melts and the melts play role as lubricant and reduce the wear and friction coefficient. This also shows that Co-alloy powder coating is highly recommendable far the durability improvement surface coating on the surface vulnerable to frictional heat such as high speed spindles.

Erosion-Corrosion Behavior of Power Plant Pipe Caused by Hot Feed Water (고온 급수에 의한 파워 플랜트 배관 침식-부식 거동)

  • Bang, Sung-Ho;Lee, Jin-Won;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.37 no.6
    • /
    • pp.739-745
    • /
    • 2013
  • In this study, we tried to define the erosion-corrosion behavior together with the resulting effects on a pipe that is a part of a feed water circulation system according to the pipe size and hot feed water environment. An erosioncorrosion analysis was performed through the Hayduk and Minhas model based on the chemical reaction between iron and oxygen, an essential corrosive factor. The erosion-corrosion rate against the pipe diameter and feed water temperature was then evaluated by means of finite element analysis using ABAQUS. As shown in the results, the feed water temperature was the main factor influencing the erosion-corrosion rate; in particular, it was expected that the thickness of 316 stainless steel would decrease by $2.59{\mu}m$ every year in a hot water environment at $290^{\circ}C$.

Corrosive Degradation of MgO/Al2O3-Added Si3N4 Ceramics under a Hydrothermal Condition (MgO/Al2O3가 소결조제로 첨가된 Si3N4 세라믹스의 수열 조건에서의 부식열화 거동)

  • Kim, Weon-Ju;Kang, Seok-Min;Park, Ji-Yeon
    • Korean Journal of Materials Research
    • /
    • v.17 no.7
    • /
    • pp.366-370
    • /
    • 2007
  • Silicon nitride ($Si_3N_4$) ceramics have been considered for various components of nuclear power plants such as the mechanical seal of a reactor coolant pump (RCP), the guide roller for a control rod drive mechanism (CRDM), and a seal support, etc. Corrosion behavior of $Si_3N_4$ ceramics in a high-temperature and high-pressure water must be elucidated before they can be considered as components for nuclear power plants. In this study, the corrosion behaviors of $Si_3N_4$ ceramics containing MgO and $Al_2O_3$ as sintering aids were investigated at a hydrothermal condition ($300^{\circ}C$, 9.0 MPa) in pure water and 35 ppm LiOH solution. The corrosion reactions were controlled by a diffusion of the reactive species and/or products through the corroded layer. The grain-boundary phase was preferentially corroded in pure water whereas the $Si_3N_4$ grain seemed to be corroded at a similar rate to the grain-boundary phase in LiOH solution. Flexural strengths of the $Si_3N_4$ ceramics were significantly degraded due to the corrosion reaction. Results of this study imply that a variation of the sintering aids and/or a control (e.g., crystallization) of the grain-boundary phase are necessary to increase the corrosion resistance of $Si_3N_4$ ceramics in a high-temperature water.

Formation of Optical Fiber Preform Using Octamethylcyclotetrasiloxane (Octamethylcyclotetrasiloxane를 이용한 광섬유 클래드 프리폼 형성)

  • Choi, Jinseok;Lee, Tae Kyun;Park, Seong Gyu;Lee, Ga Hyoung;Jun, Gu Sik;An, Sung Jin
    • Korean Journal of Materials Research
    • /
    • v.28 no.1
    • /
    • pp.6-11
    • /
    • 2018
  • There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

Characteristics of LDPE resin film depending on RP contents (적인 함유량에 따른 LDPE 수지 film의 특성연구)

  • JO, Dong-Soo;Noh, Young-Tai;Park, Byung-Sun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.16 no.10
    • /
    • pp.6655-6665
    • /
    • 2015
  • Due to tightened environmental regulations on halogen type flame retardants, the portions of those based on phosphorous compounds that are non-halogen type is rising. When producing functional film, the physical and thermal properties become distinctly different depending on the amount of Red-phosphorus(RP) addition which causes flame resistance. The physical properties of resin fall in big scale when too much flame retardants are added, and it is hard to be applied to functional films such as shrink or anticorrosive film. The purpose of this research is to study the effects on mechanical, physical, and other properties of RP-LDPE films by changing the RP-MB contents. The LDPE film used for this study was produced through blow-type injection molding. The flame resistance was VTM-0, and the tear resistance showed inverse trends of MD and TD. Contraction percentage showed no relationship with the amount of RP content, but the anti-corrosive property showed 0.05 % better result than the national anti-corrosion shrink film reliability standard.

Changes in Corrosion Progress and Ultimate load of Tendon Under 20% and 40% of Ultimate Loading Conditions (파괴하중의 20% 및 40% 인장조건에서 텐던 부식 진행 및 파괴하중 변화)

  • Ryu, Hwa-Sung;An, Gi Hong;Hwang, Chul-Sung;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.21 no.4
    • /
    • pp.47-52
    • /
    • 2017
  • PSC (Prestressed Concrete) structures have been used widely for its engineering advantage with using total concrete area as effective compressive section. However tendon inside is exposed to such a high tensile stress that and more attentions should be paid for corrosion control. This work is for changing corrosion current and ultimate strength in tendon with increasing prestressing force in a constant corrosive condition. With increasing prestressing force, corrosion current, corrosion amount, and ultimate load are changed linearly. When prestressing force increases from 20.0 % to 40.0 %, corrosion current increases to 124.4 % and 168.0 % and ultimate load decreases to 87.8 % and 78.4 %, respectively. With inducing constant electrical potential, increasing corrosion current and reduction of strength are evaluated to be linearly related with increasing prestressing load.

A Safety Evaluation on the Ring Deflection of Buried GRP Pipes (지중매설 유리섬유복합관의 관변형에 관한 안전성 평가)

  • Park, Joon-Seok;Kim, Sun-Hee;Kim, Eung-Ho;Yoon, Soon-Jong
    • Journal of the Korean Society for Advanced Composite Structures
    • /
    • v.2 no.2
    • /
    • pp.26-33
    • /
    • 2011
  • Recently, the use of buried glass fiber reinforced plastic (GRP) pipes is widespread and ever increasing trend in the industry. GRP pipes are attractive for use in harsh environments, such as for the collection and transmission of liquids which are abrasive and/or corrosive. The structural behavior of a GRP pipes buried under the ground is different from that of a rigid one made of concrete or clay, for example. A GRP pipe buried under the ground is deflected circumferentially by several percent and the stresses in the pipe are mainly compressive stresses. A GRP pipes has been introduced by a number of manufacturers for selection and used by underground pipeline designers. In all cases, the modified Spangler's equation is recommended by these manufacturers for predicting the ring deflection of these pipes under dead and live loads. In this paper, the ring deflection of buried GRP pipe is evaluated and discussed based on the result of analytical investigation.

Development of Retinal Prosthesis Module for Fully Implantable Retinal Prosthesis (완전삽입형 인공망막 구현을 위한 인공망막모듈 개발)

  • Lee, Kang-Wook;Kaiho, Yoshiyuki;Fukushima, Takafumi;Tanaka, Tetsu;Koyanagi, Mitsumasa
    • Journal of Biomedical Engineering Research
    • /
    • v.31 no.4
    • /
    • pp.292-301
    • /
    • 2010
  • To restore visual sensation of blind patients, we have proposed a fully implantable retinal prosthesis comprising an three dimensionally (3D) stacked retinal chip for transforming optical signal to electrical signal, a flexible cable with stimulus electrode array for stimulating retina cells, and coupling coils for power transmission. The 3D stacked retinal chip is consisted of several LSI chips such as photodetector, signal processing circuit, and stimulus current generator. They are vertically stacked and electrically connected using 3D integration technology. Our retinal prosthesis has a small size and lightweight with high resolution, therefore it could increase the patients` quality of life (QOL). For realizing the fully implantable retinal prosthesis, we developed a retinal prosthesis module comprising a retinal prosthesis chip and a flexible cable with stimulus electrode array for generating optimal stimulus current. In this study, we used a 2D retinal chip as a prototype retinal prosthesis chip. We fabricated the polymide-based flexible cable of $20{\mu}m$ thickness where 16 channels Pt stimulus electrode array was formed in the cable. Pt electrode has an impedance of $9.9k{\Omega}$ at 400Hz frequency. The retinal prosthesis chip was mounted on the flexible cable by an epoxy and electrically connected by Au wire. The retinal prosthesis chip was cappted by a silicone to pretect from corrosive environments in an eyeball. Then, the fabricated retinal prosthesis module was implanted into an eyeball of a rabbit. We successfully recorded electrically evoked potential (EEP) elicited from the rabbit brain by the current stimulation supplied from the implanted retinal prosthesis module. EEP amplitude was increased linearly with illumination intensity and irradiation time of incident light. The retinal prosthesis chip was well functioned after implanting into the eyeball of the rabbit.

Pain Control for Hydrofluoric Acid Chemical Burn Using EMLA® creams (EMLA® 연고를 이용한 불산 화학 화상의 통증 조절)

  • Choi, Hwan Jun;Song, Jin Woo;Choi, Chang Yong
    • Archives of Plastic Surgery
    • /
    • v.36 no.1
    • /
    • pp.113-117
    • /
    • 2009
  • Purpose: Although Hydrofluoric acid(HF) is not a strong acid when compared to other hydrogen halides, it is a feared corrosive and is particularly dangerous at higher concentrations. HF burns are characterized by symptoms, often delayed and localized with diluted HF solutions, to include erythema, edema and severe pain. Pain, a well known symptom following exposure to calcium binding. And, EMLA$^{(R)}$ cream is a topical formulation based upon the eutectic mixture of lidocaine and prilocaine and is used in clinical settings to provide pain relief undergoing superficial surgical procedures. The aim of this study is to evaluate effects of EMLA$^{(R)}$ cream, pain - control dressing on the treatment for HF injury wound. Methods: From June 2007 to June 2008, this study was carried out with 10 patients who had HF partial thickness burns. We were applied topically EMLA$^{(R)}$ cream to injured wound with vaseline gauze and 10% calcium gluconate wet gauze dressings. As a principle, in the emergency treatment, partial or complete removal of the bullae along with copious washing with normal saline was done, depending on the degree of HF invasion of the distal digital extremities. The effect of dressing was investigated by visual analogue pain scale. Results: We therefore reviewed 10 cases of HF - induced pain and pain relief treatment principle. The 10 cases who came to the hospital nearly immediately after the injury healed completely without sequelae and EMLA$^{(R)}$ related complications. Conclusion: Proper initial treatment of HF burns are important, if not promptly recognized and properly treated, for produce serious injury. Topical EMLA$^{(R)}$ cream remain a powerful, new advancement for minimizing HF - related pain during dressing procedures. When used appropriately, topical EMLA$^{(R)}$ cream can provide a safe and effective alternative to other forms of HF - pain control treatment.

The Effect of Corrosion of Rolling Bearing Ceramics in Alkalic Solution on the Rolling Wear and Hardness (알카리용액에서 구름베어링용 세라믹스의 부식이 구름마모 및 경도에 미치는 영향)

  • 최인혁;김상근;박창남;윤대현;신동우
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
    • /
    • 1999.11a
    • /
    • pp.154-159
    • /
    • 1999
  • Silicon nitride ceramic has been verified as an excellent rolling bearing material because of its high strength and outstanding rolling fatigue life properties. However under some corrosive circumstances it showed drawbacks such as hardness reduction and severe wear caused by corrosion. In this work, the variations of the rolling wear and hardness of three kinds of ceramics were studied for the specimen aged 15 days in alkali water (90$\pm$2$^{\circ}C$, 25 wt% NaOH). All of the specimens, \circled1Si$_3$N$_4$, \circled23Y-TZP and \circled33Y-TZP alloyed with 5 wt% CeO$_2$, were sintered and post-Hipped, and then polished up to 0.02 ${\mu}{\textrm}{m}$Ra of surface roughness. Rolling wear tests were conducted by MJ type rolling fatigue life tester under the initial theoretical maximum contact stress or 3.76 Gra and the spindle speed of 1,000 rpm. Spindle oil was used as a lubricant. The specimens were not worn before aging. For the specimen aged in alkali water, Si$_3$N$_4$and 3Y-TZP were worn by rolling wear tests, and hardness was decreased. While aging the specimens, the phase was transformed from tetragonal to monoclinic in 3Y-TZP and the microstructure change occurred in Si$_3$N$_4$. 3Y-TZP alloyed with 5 wt% CeO$_2$specimens were not worn after aging and no phase transformation occurred while aging.

  • PDF