• Corrosion Science and Technology
• /
• v.19 no.4
• /
• pp.189-195
• /
• 2020

Two air vents situated on a heat transport pipe in district heating system were exposed to the same environment for 10 years. However, one air vent was more corroded than the other. It also had a hole on the top of the front-end pipe. Comparative analysis was performed for these air vents to identify the cause of corrosion and establish countermeasures. Through experimental observation of the damaged part and analyses of powders sampled from air vents, it was found that corrosion was initiated at the top of the front-end pipe. It then spread to the bottom. Energy dispersive X-ray spectroscopy results showed that potassium and chlorine were measured from the corroded product in the damaged air vent derived from rainwater and insulation, respectively. The temperature of the damaged air vent was maintained at 75 ~ 120 ℃ by heating water. Rainwater-soaked insulation around the front-end pipe had been hydrolyzed. Therefore, the damaged air vent was exposed to an environment in which corrosion under insulation could be facilitated. In addition, ion chromatography and inductively coupled plasma measurements indicated that the matrix of the damaged front-end pipe contained a higher manganese content which might have promoted corrosion under insulation.

• Korean Journal of Materials Research
• /
• v.12 no.2
• /
• pp.103-111
• /
• 2002

The thermally insulated underground pipelines have been used for district heating system. The sensor wire embedded in the insulation was used for monitoring the insulating resistance between the sensor wire and the pipe. The resistance measurement system detects corrosion of steel pipe under insulation. The corrosion and stress corrosion cracking(SCC) characteristics of sensor wire in synthetic ground water were investigated using the electrochemical methods and constant load SCC tests. The polarization tests were used to study the electrochemical behavior of sensor wire. The sensor wire was passivated at temperatures ranging from 25 to $95^{\circ}C$. However, the applied sensing current larger than passive current resulted in breakdown of passive film. The constant load SCC tests were performed to investigate the effects of applied current and load on the fracture behavior. Stress-corrosion cracks initiated at pits that were produced by sensing current. The growth of the pit involves a tunnelling mechanism, which leads to ductile fracture.

• Corrosion Science and Technology
• /
• v.22 no.2
• /
• pp.115-122
• /
• 2023

This study aimed to elucidate causes of corrosion of heat transport pipes and air vents installed under a manhole of heat transport facilities and suggest effective anticorrosive measures by applying paints or adhesive tapes. It was found that air vent corrosion was attributed to corrosion under insulation caused by the inflow of water and the enrichment of chloride ions. The infiltrated water caused a hydrolysis of polyurethane foam (PUF) insulation by concentrating chloride ions at the interface between a pipe and the PUF. As insulator deteriorated, more chloride ions were eluted as confirmed by ion chromatograph (IC) analysis. As an effective method to prevent air vent corrosion, different types of paints and adhesive tapes with higher corrosion resistance on chloride ions were applied and environmental resistance tests were performed with those samples. Based on environmental test results of samples exposed to 10% HCl solution, it was revealed that a wax tape was the most adequate from a viewpoint of stability at operating condition, environmental resistance, surface treatment, and field applicability.

• Proceedings of the KSR Conference
• /
• 2009.05a
• /
• pp.1117-1124
• /
• 2009

Under frame side sill of rolling stock structure is designed for preventing corrosion in order to meet mechanical requirements. However during long operation time more than 20 years, there are corrosion in the under frame side sill caused by environmental effect, vibration and etc. So, detection and evaluation of the corrosion ill the under frame nondestructive is one of important issues to extend their life time. Most of nondestructive methods are not easy to apply for detecting corrosion in the under frame side sill, since the under frame side sill consist of there layered with different material (stainless steel - stainless steel - mild steel) and each layer is connected by spot weld and plug weld. Fortunately, pulsed eddy current method claimed that it can be measured not only thickness change but also corrosion under their insulation layers. So, in this study, we have investigated performance of pulsed eddy current testing method by measuring thickness variation of fabricate of mock-up specimens. The investigation results obtained from mock-up specimens and the corrosion evaluation results of the aged rolling stocks will be presented.

• Journal of the Korean Institute of Gas
• /
• v.20 no.6
• /
• pp.50-57
• /
• 2016

Pipeline is one of the most abundant components in petrochemical plant. It plays a critical role in transporting fluids. Some pipelines are thermally insulated by wrapping them with insulating materials to prevent the loss of energy. However, when corrosion begins under insulation, it cannot be easily seen without unwrapping the cover, and thus corrossion should be detected using a non-destructive ways such as ultrasound guided wave. In this paper, the piping where the CUI (Corrosion Under Insulation) which occurs in the insulation parts guided waves effectively the optimum condition which is theoretical for selected guided waves phase velocity dispersion curve and wave-structure. The results of this study are expected to be directly utilized for onsite inspection of pipeline's CUI in many petrochemical plants.

• 한국전기화학회:학술대회논문집
• /
• 1998.10a
• /
• pp.51-51
• /
• 1998

• Journal of Advanced Marine Engineering and Technology
• /
• v.27 no.3
• /
• pp.447-452
• /
• 2003

Crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. Such stagnant micro environments tend to occur in crevices (shielded areas) such as those formed under gaskets washers insulation material. fastener heads. surface deposits. disbonded coatings. threads. lap joints and clamps. Crevice corrosion is initiated by changes in located electrochemical reaction within the crevice such as a) depletion of inhibitor in the crevice b) depletion of oxygen in the crevice c) a shift to acid conditions in the crevice and d) build-up of aggressive ion species (e.g chloride) in the crevice. In this study. the mechanism of crevice corrosion for Type 430 stainless steel is investigated undercondition that the size of specimen is $15{\times}20\{times}3mm$, in 1N $H_2SO_4$ + 0.05N NaCl solution. and the artificial crevice gap size of 3 x 0.2 x 15 mm. Crevice corrosion is measured under applied potential -300mV(SCE) to the external surface. The obtained result of this study showed that 1) the induced time for initiation of crevice is 750 seconds. 2) potential of the crevice was about from -320mV to -399mV. which is lower than that of external surface potential of -300mV It is considered that potential drop in the crevice is one of mechanisms for the crevice corrosion

• Corrosion Science and Technology
• /
• v.19 no.4
• /
• pp.196-202
• /
• 2020

The air vent connected to a heat supply pipeline in the district heating system has been used to eliminate the existing air in the pipe, which has a detrimental effect on corrosion durability and heat efficiency. Recently, the air vent installed under a manhole for 22 years was corroded and several pinholes were detected in the front-end of the air vent. To identify the cause of the failure, thickness reduction, corrosion products, and water quality were examined. The corrosion damage was significant at the outside of the front-end of the air vent where the insulator was covered. While a thin oxide layer was formed in the interior of the tube, the coarse and porous corrosion products consisting of magnetite and hematite were found externally. Water flowing into the thermal insulator was absorbed by the insulator following hydrolysis. The hydrolyzed insulator ejected the corrosion factors such as Cl^-, SO₄^2-, and NH₄⁺. The findings suggest that the corrosion under insulation due to rain water is the main cause of the underlying failure in the air vent.

• Corrosion Science and Technology
• /
• v.6 no.6
• /
• pp.308-310
• /
• 2007

The owner of underground metallic structures (gas pipeline, oil pipeline, water pipeline, etc) has a burden of responsibility for the corrosion protection in order to prevent big accidents like gas explosion, soil pollution, leakage and so on. So far, Cathodic Protection(CP) technology have been implemented for protection of underground systems. The stray current from DC subway system in Korea has affected the cathodic protection (CP) design of the buried pipelines adjacent to the railroads. In this aspect, KERI has developed a various mitigation method, drainage system through steel bar under the rail, a stray current gathering mesh system, insulation method between yard and main line, distributed ICCP(Impressed Current Cathodic System), High speed response rectifier, restrictive drainage system, Boding ICCP system. We installed the mitigation system at the real field and test of its efficiency in Busan and Seoul, Korea. In this paper, the results of field test, especially, distributed ICCP are described.

• Journal of Energy Engineering
• /
• v.27 no.2
• /
• pp.1-13
• /
• 2018

The proportion of natural gas-fueled power generation is expanding due to the change of domestic energy policy pursuing reduction of dust and increasing clean energy consumption. Natural gas fuels used for the combined-cycle power plants and the district-heating power plants are operated at high temperature and high pressure in the fuel supply system. Accidents due to leakage of the gas such as fire and explosion should be prevented by applying risk management techniques. In this study, risk assessment was performed on the natural gas fuel supply system of a combined power plant based on the API RP 581 RBI code. For the application of the API RBI code, lines and segments of the evaluation target system were identified. Operational data and input information were analyzed for the calculations of probability of failure and consequence of failure. The results of the risk assessment were analyzed over time from the initial installation time. In the code-based evaluation, the gas fuel supply system was mainly affected by thinning, external damage, and mechanical fatigue damage mechanisms. As the operating time passes, the risk is expected to increase due to the external damage caused by the CUI(Corrosion Under Insulation).