• Title/Summary/Keyword: Corrosion rate

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Experimental Study on Corrosion Rate in Concrete

  • Jang, BongSeok;Oh, ByungHwan
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.34-38
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    • 2004
  • The corrosion of reinforcement is a very important factor on the serviceability and safety of reinforced concrete structures. The corrosion rate influences directly the cover failure time of reinforced concrete structures because the corrosion rate is used to estimate the amount of corrosion and thus expansive pressure due to corrosion. In this study, several series of experiments are performed considering the chloride concentration in artificial pore solution. The potentials are measured according to the applied current density and then corrosion current densities are obtained from the Tafel plot for various chloride concentrations. The measured corrosion rates show good correlation with those of other researchers.

Effect of Flow Rate on Erosion Corrosion Damage and Damage Mechanism of Al5083-H321 Aluminum Alloy in Seawater Environment (해수 환경에서 Al5083-H321 알루미늄 합금의 침식부식 손상에 미치는 유속의 영향과 손상 메카니즘)

  • Kim, Young-Bok;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.3
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    • pp.115-121
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    • 2020
  • In this study, erosion tests and erosion-corrosion tests of Al5083-H321 aluminum alloy were conducted at various flow rates in seawater. The erosion tests were conducted at a flow rate of 0 to 20 m/s, and erosion-corrosion tests were performed by potentiodynamic polarization method at the same flow rate. Characteristic evaluation after the erosion test was conducted by surface analysis. Characteristic evaluation after the erosion-corrosion test was performed by Tafel extrapolation and surface analysis. The results of the surface analysis after the erosion test showed that surface damage tended to increase as the flow rate increased. In particular, intermetallic particles were separated due to the breakdown of the oxide film at 10 m/s or more. In the erosion-corrosion test, the corrosion current density increased as the flow rate increased. Additionally, the surface analysis showed that surface damage occurred in a vortex shape and the width of the surface damage tended to increase as the flow rate increased. Moreover, damage at 0 m/s, proceeded in a depth direction due to the growth of pitting corrosion, and the damaged area tended to increase due to acceleration of the intermetallic particle loss by the fluid impact.

Corrosion Characteristics of Diffusion Barrier in Copper CMP (구리 CMP시 확산방지막의 부식특성)

  • Lee, Do-Won;Kim, Nam-Hoon;Lim, Jong-Heun;Kim, Sang-Yong;Lee, Chul-In;Chang, Eui-Gu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.162-165
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    • 2003
  • The corrosion characteristics of diffusion barrier in Copper CMP has been investigated. Key experimental variables that has been investigated are the corrosion rate by different agents containing slurry of Cu CMP. Whenever Cu and Ta films were corroded adding each oxidizer, the corrosion rate of Ta was much lower than that of Cu. That is, the difference in the corrosion rates of Ta by oxidizer was not larger as compared with Cu. As corroded by complexing agents, the corrosion rate of Ta was close to O. The corrosion rate of Ta increased as added $HNO_3$ and $CH_3COOH$ compared with the reference slurry; on the other hand, it decreased with addition of HF. In addition, resulting corrosion rate went up with lower pH of agent. The corrosion rates by agents were however significant small; hence, it doesn't affect on the removal rate of Cu CMP practically. Consequently, this can be explained by assuming that the mechanical effect dominates than the chemical effect on the polishing rate of Ta(TaN).

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Probabilistic estimates of corrosion rate of fuel tank structures of aging bulk carriers

  • Ivosevic, Spiro;Mestrovic, Romeo;Kovac, Natasa
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.1
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    • pp.165-177
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    • 2019
  • This paper considers corrosion wastage of two ship hull structure members as a part of investigated fuel oil tanks of 25 aging bulk carriers. Taking into account that many factors which influence corrosion wastage of ship hull structures are of uncertain nature, the related corrosion rate ($c_1$) is considered here as a real-valued continuous distribution, assuming that the corrosion wastage starts after 5, 6 or 7 years. In all considered cases, by using available data and applying three basic statistical tests, it is established that between two-parameter continuous distributions, normal, Weibull and logistic distributions are best fitted distributions for the mentioned corrosion rate ($c_1$). Note that the presented statistical, numerical and graphical results concerning two mentioned ship hull structure members allow to compare and discuss the corresponding probabilistic estimates for the corrosion rate ($c_1$).

Dynamic Boric Acid Corrosion of Low Alloy Steel for Reactor Pressure Vessel of PWR using Mockup Test (가압형 경수로 압력용기 재료인 저합금강의 동적 붕산 부식 실증 연구)

  • Kim, Sung-Woo;Kim, Hong-Pyo;Hwang, Seong-Sik
    • Corrosion Science and Technology
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    • v.12 no.2
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    • pp.85-92
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    • 2013
  • This work is concerned with an evaluation of dynamic boric acid corrosion (BAC) of low alloy steel for reactor pressure vessel of a pressurized water reactor (PWR). Mockup test method was newly established to investigate dynamic BAC of the low alloy steel under various conditions simulating a primary water leakage incident. The average corrosion rate was measured from the weight loss of the low alloy steel specimen, and the maximum corrosion rate was obtained by the surface profilometry after the mockup test. The corrosion rates increased with the rise of the leakage rate of the primary water containing boric acid, and the presence of oxygen dissolved in the primary water also accelerated the corrosion. From the specimen surface analysis, it was found that typical flow-accelerated corrosion and jet-impingement occurred under two-phase fluid of water droplet and steam environment. The maximum corrosion rate was determined as 5.97 mm/year at the leakage rate of 20 cc/min of the primary water with a saturated content of oxygen within the range of experimental condition of this work.

A study on the tensile property and corrosion resistance of austenitic stainless base and weld metal (오스테나이트계 스테인리스강 모재 및 용접부의 인장특성과 내식성에 관한 연구)

  • 정호신;김조권;엄동석
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.71-78
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    • 1996
  • The effect of chemical composition on mechanical properry and corrosion resistance of austenitic stainless steel was investigated. The main results obtained were as follows : 1. There was a linear relationship between the tensile strength of stainless steel and the $Cr_{eq}/Ni_{eq}$. The larger the $Cr_{eq}/Ni_{eq}$ was the higher the tensile strength of stainless steel. 2. There was a good correlationship between $Cr_{eq}/Ni_{eq}$ and intergranular, gerneral corrsion rate. 3. Intergranular corrosion rate decreased linearly with increasing Cr content. 4. General corrosion rate decreased linearly with increasing Ni content. 5. Logarithm corrosion rate of intergranular and general corrosion has a linear relationship with all of the factor of $Cr_{eq}/Ni_{eq}$, Cr and Ni content.

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The Corrosion Inhibition Characteristics of Sodium Nitrite Using an On-line Corrosion Rate Measurement System (온라인 부식속도 측정 시스템을 이용한 아질산 나트륨의 금속 부식억제 특성 연구)

  • Park, Mal-Yong;Moon, Jeon-Soo;Kang, Dae-Jin
    • Corrosion Science and Technology
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    • v.14 no.2
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    • pp.85-92
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    • 2015
  • An on-line corrosion rate measurement system was developed using a personal computer, a data acquisition board and program, and a 2-electrode corrosion probe. Reliability of the developed system was confirmed with through comparison test. With this system, the effect of sodium nitrite ($NaNO_2$) as a corrosion inhibitor were studied on iron and aluminum brass that were immersed in sodium chloride (NaCl) solution. Corrosion rate was measured based on the linear polarization resistance method. The corrosion rates of aluminum brass and iron in 1% NaCl solutions were measured to be 0.290 mm per year (mmpy) and 0.2134 mmpy, respectively. With the addition of 200 ppm of $NO{_2}^-$, the corrosion rates decreased to 0.0470 mmpy and 0.0254 mmpy. The addition of $NO{_2}^-$ caused a decrease in corrosion rates of both aluminum brass and iron, yet the $NO{_2}^-$ acted as a more effective corrosion inhibitor for iron. than aluminum brass.

Galvanic Corrosion between Carbon Steel 1018 and Alloy 600 in Crevice with Boric Acid Solution

  • Kim, Dong Jin;Macdonald, Digby D.;Kim, Hong Pyo;Kim, Joung Soo
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.75-80
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    • 2005
  • This work dealt with the evaluation of galvanic corrosion rate in a corrosion cell having annular gap of 0.5 mm between carbon steel 1018 and alloy 600 as a function of temperature and boron concentration. Temperature and boron concentration were ranged from 110 to 300 $^{\circ}C$ and 2000~10000 ppm, respectively. After the operating temperature of the corrosion cell where the electrolyte was injected was attained at setting temperature, galvanic coupling was made and at the same time galvanic current was measured. The galvanic corrosion rate decreased with time, which was described by corrosion product such as protective film as well as boric acid deposit formed on the carbon steel with time. From the galvanic current obtained as a function of temperature and boron concentration, it was found that the galvanic corrosion rate decreased with temperaturewhilethe corrosionrate increasedwith boronconcentration. The experimental resultsobtained from galvanic corrosion measurement were explained by adhesive property of corrosion product such as protective film, boric acid deposit formed on the carbon steel wall and dehydration of boric acid to be slightlysolubleboric acid phase.Moreoverthe galvaniccorrosionrate calculatedusing initialgalvaniccoupling current instead of steady state coupling current was remarked, which could give us relatively closer galvanic corrosion rate to real pressurized water reactor.

Investigation on Electrochemical Corrosion and Stress Corrosion Cracking Characteristics of Anodized 5083-H321 Alloy in Natural Seawater (양극산화된 5083-H321 합금의 천연해수 내 전기화학적 부식 및 응력부식균열 특성에 관한 연구)

  • Hwang, Hyun-kyu;Shin, Dong-Ho;Jung, Kwang-Hu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.19 no.5
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    • pp.259-264
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    • 2020
  • Many studies have been conducted to improve the corrosion resistance and durability of various aluminum alloys through the anodizing technique. It is already used as a unique technique for enhancing the properties of aluminum alloys in various industries. This paper investigated the electrochemical corrosion and stress corrosion cracking characteristics of anodized aluminum 5083-H321 alloy in natural seawater. The corrosion characteristics were assessed by the electrochemical technique and potentiodynamic polarization test. The stress corrosion cracking characteristic was evaluated with a slow strain rate tensile test under 0.005 mm/min rate, which showed that the hard anodizing film had a thickness of about 16.8 ㎛. Although no significant characteristics of stress corrosion cracking were observed in the slow strain rate test, the anodized specimen presented excellent corrosion resistance. The corrosion current density was measured to be approximately 4.2 times lower than that of the base material, and no surface damage was observed in the anodic polarization test.

Corrosion Behaviour of Water Pipes (수도관의 부기거동에 관한 연구)

  • 김원만;박영식
    • Journal of environmental and Sanitary engineering
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    • v.7 no.1
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    • pp.1-16
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    • 1992
  • Corrosion of pipes Is one of the most serious problems in the maintenance of water worlds. Corrosion is promoted not only by physical factors such as temperature, but also by electrochemical factors including concentration of soluble metal ions, chlorine ion, pH, DO and microorganisms. Corrosion products also affect corrosion rate. In this research, study results are summarized as follows ; 1) Corrosion test was performed for 4 weeks at $70^{\circ}C$, pH 7.0 with specimens of 4 types of metal materials used as service pipes. Corrosion rate and S.E.M were analyzed. The results were showed that corrosion 1.ate of carbon steel pipe was 4.10~5.22 $mg/\textrm{cm}^2$ . week, galvanized steel pipe 0.98~1.34$mg/\textrm{cm}^2$. week, Copper pipe 0.02~0.04$mg/\textrm{cm}^2$. week, stainless steel pipe 0.05~ 0.10$mg/\textrm{cm}^2$ . week. 2) When corrosion rate was tested for tile types of pipes at pH 7 and both $25^{\circ}C$ and $75^{\circ}C$, avaerage corrosion rate for 6 weeks at $25^{\circ}C$ Ivas 2.26$mg/\textrm{cm}^2$ . week in carbon steel pipe, 1.99$mg/\textrm{cm}^2$. week in galvanized steel pipe, 0.26 $mg/\textrm{cm}^2$. week in stainless steel pipe. At $87^{\circ}C$, average corrosion rate for 4 weeks u.3s 4.56 $mg/\textrm{cm}^2$. week in carbon steel pipe,

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